Synthesis of Pt-SnOx/TS-1@SBA-16 Composites and Their High Catalytic Performance for Propane Dehydrogenation

doi:10.1007/s40242-019-9120-7

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (5): 866-873.doi: 10.1007/s40242-019-9120-7

Synthesis of Pt-SnO_x/TS-1@SBA-16 Composites and Their High Catalytic Performance for Propane Dehydrogenation

LI Hongda¹, ZHAO Zhen^1,2, LI Jiacheng¹, LI Jianmei¹, ZHAO Linlin², SUN Jiachen¹, FAN Xiaoqiang²

1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, P. R. China;
2. Institute of Catalysis for Energy and Environment, College of Chemistry and Chemical Engineering, Shenyang Normal University, Shenyang 110034, P. R. China

收稿日期:2019-04-24 出版日期:2019-10-01 发布日期:2019-09-24
通讯作者: ZHAO Zhen E-mail:zhenzhao@cup.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21845201, 21761162016, 21603148).

Synthesis of Pt-SnO_x/TS-1@SBA-16 Composites and Their High Catalytic Performance for Propane Dehydrogenation

LI Hongda¹, ZHAO Zhen^1,2, LI Jiacheng¹, LI Jianmei¹, ZHAO Linlin², SUN Jiachen¹, FAN Xiaoqiang²

1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, P. R. China;
2. Institute of Catalysis for Energy and Environment, College of Chemistry and Chemical Engineering, Shenyang Normal University, Shenyang 110034, P. R. China

Received:2019-04-24 Online:2019-10-01 Published:2019-09-24
Contact: ZHAO Zhen E-mail:zhenzhao@cup.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21845201, 21761162016, 21603148).

摘要/Abstract

摘要： A novel composite material of TS-1@SBA-16 was synthesized by enwrapping TS-1 zeolite crystals with mesoporous SBA-16 silica. This composite was used as catalyst support for loading Pt-SnO_x in the propane dehydrogenation(PDH) reaction. Catalysts were characterized by means of N₂ adsorption-desorption, XRD, SEM, TEM, XPS, UV-Vis, and Raman spectroscopy. The effect of different contents of TS-1 on PDH was investigated, and the optimal amount of TS-1 was determined to be 10%. The catalyst with TS-1 content of 10% showed the highest PDH activity and the initial conversion of propane over it can achieve 54.5%, higher than those over TS-1 or SBA-16-supported ones. The superior catalytic performance of Pt-SnO_x/TS-1@SBA-16 is related to the synergistic effect of the excellent mass transfer performance through the hierarchical porous structure, suitable acid acidity and electronic effect of Ti species.

关键词: Catalyst, Pt-SnO_x, Propane, Dehydrogenation, TS-1 zeolite, Micro-and meso-porous material

Abstract: A novel composite material of TS-1@SBA-16 was synthesized by enwrapping TS-1 zeolite crystals with mesoporous SBA-16 silica. This composite was used as catalyst support for loading Pt-SnO_x in the propane dehydrogenation(PDH) reaction. Catalysts were characterized by means of N₂ adsorption-desorption, XRD, SEM, TEM, XPS, UV-Vis, and Raman spectroscopy. The effect of different contents of TS-1 on PDH was investigated, and the optimal amount of TS-1 was determined to be 10%. The catalyst with TS-1 content of 10% showed the highest PDH activity and the initial conversion of propane over it can achieve 54.5%, higher than those over TS-1 or SBA-16-supported ones. The superior catalytic performance of Pt-SnO_x/TS-1@SBA-16 is related to the synergistic effect of the excellent mass transfer performance through the hierarchical porous structure, suitable acid acidity and electronic effect of Ti species.

Key words: Catalyst, Pt-SnO_x, Propane, Dehydrogenation, TS-1 zeolite, Micro-and meso-porous material

LI Hongda, ZHAO Zhen, LI Jiacheng, LI Jianmei, ZHAO Linlin, SUN Jiachen, FAN Xiaoqiang. Synthesis of Pt-SnO_x/TS-1@SBA-16 Composites and Their High Catalytic Performance for Propane Dehydrogenation[J]. 高等学校化学研究, 2019, 35(5): 866-873.

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Synthesis of Pt-SnO_x/TS-1@SBA-16 Composites and Their High Catalytic Performance for Propane Dehydrogenation

Synthesis of Pt-SnO_x/TS-1@SBA-16 Composites and Their High Catalytic Performance for Propane Dehydrogenation

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