Research on Ice Crystal Growth Inside the Vitrified Vs55 with Magnetic Nanoparticles During Devitrification by Cryomicroscopy

doi:10.1007/s40242-019-8230-6

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (3): 542-548.doi: 10.1007/s40242-019-8230-6

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Research on Ice Crystal Growth Inside the Vitrified Vs55 with Magnetic Nanoparticles During Devitrification by Cryomicroscopy

LIU Ke, XU Yi, YU Hongmei

Institute of Biothermal Science & Technology, University of Shanghai for Science and Technology, Shanghai 200093, P. R. China

收稿日期:2018-07-18 修回日期:2019-03-01 出版日期:2019-06-01 发布日期:2019-05-29
通讯作者: XU Yi E-mail:xuyi@usst.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.51576132).

Research on Ice Crystal Growth Inside the Vitrified Vs55 with Magnetic Nanoparticles During Devitrification by Cryomicroscopy

LIU Ke, XU Yi, YU Hongmei

Institute of Biothermal Science & Technology, University of Shanghai for Science and Technology, Shanghai 200093, P. R. China

Received:2018-07-18 Revised:2019-03-01 Online:2019-06-01 Published:2019-05-29
Contact: XU Yi E-mail:xuyi@usst.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.51576132).

摘要/Abstract

摘要： The effect of magnetic nanoparticles(mNPs) on the devitrification crystallization of typical vitrification solution Vs55 was systematically explored by differential scanning calorimetry(DSC) and cryomicroscope system. The results show that, (i) the mNPs coated by both carboxylic acid(CA) and polyethylene glycol(PEG) had little effect on the glass transition temperature(T_g) of Vs55, but had significant effect on the devitrification transition temperature(T_d) and devitrification enthalpy(H_T_d), (ii) in the range of the devitrification area(-85- -60℃), the MNPs coated by CA can significantly accelerate the devitrification of Vs55 as the isothermal temperatures and the cooling rates increased, and the ice growth rate was 0.37 μm/s at the isothermal temperature of -85℃, and was about 2.19 μm/s at -75℃. Also, the ice growth rates rose from 1.72 μm/s to 3.54 μm/s when the cooling rates were increased from 2℃/min to 100℃/min(at the isothermal temperature of -75℃), (iii) magnetic nanoparticles coated by both PEG and CA could promote the devitrification of Vs55, for instance, without any crystal growth inside Vs55 at the isothermal temperature of -80℃, but 1.04 and 2.31 μm/s for adding magnetic nanoparticles coated by CA and PEG, respectively. Compared with the samples coated by CA, PEG promoted the devitrification of Vs55 in a much more positive way, and the ice growth rates were 0.62 and 6.25 μm/s at the isothermal temperatures of -85 and -75℃, respectively. These results indicate that the surface coating of MNPs could significantly affect the recrystallization of Vs55, and further work should be conducted in the future research.

关键词: Crystallization, Kinetics, Nanoparticle, Devitrification, Ice growth rate, Vs55

Abstract: The effect of magnetic nanoparticles(mNPs) on the devitrification crystallization of typical vitrification solution Vs55 was systematically explored by differential scanning calorimetry(DSC) and cryomicroscope system. The results show that, (i) the mNPs coated by both carboxylic acid(CA) and polyethylene glycol(PEG) had little effect on the glass transition temperature(T_g) of Vs55, but had significant effect on the devitrification transition temperature(T_d) and devitrification enthalpy(H_T_d), (ii) in the range of the devitrification area(-85- -60℃), the MNPs coated by CA can significantly accelerate the devitrification of Vs55 as the isothermal temperatures and the cooling rates increased, and the ice growth rate was 0.37 μm/s at the isothermal temperature of -85℃, and was about 2.19 μm/s at -75℃. Also, the ice growth rates rose from 1.72 μm/s to 3.54 μm/s when the cooling rates were increased from 2℃/min to 100℃/min(at the isothermal temperature of -75℃), (iii) magnetic nanoparticles coated by both PEG and CA could promote the devitrification of Vs55, for instance, without any crystal growth inside Vs55 at the isothermal temperature of -80℃, but 1.04 and 2.31 μm/s for adding magnetic nanoparticles coated by CA and PEG, respectively. Compared with the samples coated by CA, PEG promoted the devitrification of Vs55 in a much more positive way, and the ice growth rates were 0.62 and 6.25 μm/s at the isothermal temperatures of -85 and -75℃, respectively. These results indicate that the surface coating of MNPs could significantly affect the recrystallization of Vs55, and further work should be conducted in the future research.

Key words: Crystallization, Kinetics, Nanoparticle, Devitrification, Ice growth rate, Vs55

LIU Ke, XU Yi, YU Hongmei. Research on Ice Crystal Growth Inside the Vitrified Vs55 with Magnetic Nanoparticles During Devitrification by Cryomicroscopy[J]. 高等学校化学研究, 2019, 35(3): 542-548.

LIU Ke, XU Yi, YU Hongmei. Research on Ice Crystal Growth Inside the Vitrified Vs55 with Magnetic Nanoparticles During Devitrification by Cryomicroscopy[J]. Chemical Research in Chinese Universities, 2019, 35(3): 542-548.

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Research on Ice Crystal Growth Inside the Vitrified Vs55 with Magnetic Nanoparticles During Devitrification by Cryomicroscopy

Research on Ice Crystal Growth Inside the Vitrified Vs55 with Magnetic Nanoparticles During Devitrification by Cryomicroscopy

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