Fabrication and Properties of Graphene Oxide/Sulfonated Polyethersulfone Layer-by-layer Assembled Polyester Fiber Composite Proton Exchange Membranes

doi:10.1007/s40242-018-7313-0

高等学校化学研究 ›› 2018, Vol. 34 ›› Issue (2): 318-325.doi: 10.1007/s40242-018-7313-0

Fabrication and Properties of Graphene Oxide/Sulfonated Polyethersulfone Layer-by-layer Assembled Polyester Fiber Composite Proton Exchange Membranes

HUANG Lihua¹, HE Yao², JIN Liying¹, HOU Xiuwei³, MIAO Luyang², LÜ Changli²

1. First Hospital of Jilin University, Changchun 130021, P. R. China;
2. College of Chemistry, Northeast Normal University, Changchun 130024, P. R. China;
3. Second Hospital of Jilin University, Changchun 130021, P. R. China

收稿日期:2017-09-21 修回日期:2018-01-09 出版日期:2018-04-01 发布日期:2018-03-26
通讯作者: HUANG Lihua,E-mail:Huang18186878770@163.com;LÜ Changli,E-mail:lucl055@nenu.edu.cn E-mail:Huang18186878770@163.com;lucl055@nenu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21574017).

Fabrication and Properties of Graphene Oxide/Sulfonated Polyethersulfone Layer-by-layer Assembled Polyester Fiber Composite Proton Exchange Membranes

HUANG Lihua¹, HE Yao², JIN Liying¹, HOU Xiuwei³, MIAO Luyang², LÜ Changli²

1. First Hospital of Jilin University, Changchun 130021, P. R. China;
2. College of Chemistry, Northeast Normal University, Changchun 130024, P. R. China;
3. Second Hospital of Jilin University, Changchun 130021, P. R. China

Received:2017-09-21 Revised:2018-01-09 Online:2018-04-01 Published:2018-03-26
Contact: HUANG Lihua,E-mail:Huang18186878770@163.com;LÜ Changli,E-mail:lucl055@nenu.edu.cn E-mail:Huang18186878770@163.com;lucl055@nenu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21574017).

摘要/Abstract

摘要： Using the hydrogen-bonding interaction between graphene oxide(GO) and sulfonated polyethersulfone (SPES), we constructed the multilayer structure of GO and SPES on the polyester fiber mats via layer-by-layer self-assembly. In each self-assembled layer, sulfonic acid groups are arranged along the axis of fiber, which provides the long-range proton transmission channels, promoting the rapidly proton conduction. The performances of the composite membranes based on SPES and multilayer assembled polyester fiber mats were studied. The results show that the proton conductivity of composite membranes increases with the increasing assembly layers. At the same time, the mechanical properties and methanol-resistance of the composite membranes were obviously improved.

关键词: Composite proton exchange membrane, Graphene oxide, Sulfonated polyethersulfone, Polyester fiber, Layer-by-layer assembly, Property

Abstract: Using the hydrogen-bonding interaction between graphene oxide(GO) and sulfonated polyethersulfone (SPES), we constructed the multilayer structure of GO and SPES on the polyester fiber mats via layer-by-layer self-assembly. In each self-assembled layer, sulfonic acid groups are arranged along the axis of fiber, which provides the long-range proton transmission channels, promoting the rapidly proton conduction. The performances of the composite membranes based on SPES and multilayer assembled polyester fiber mats were studied. The results show that the proton conductivity of composite membranes increases with the increasing assembly layers. At the same time, the mechanical properties and methanol-resistance of the composite membranes were obviously improved.

Key words: Composite proton exchange membrane, Graphene oxide, Sulfonated polyethersulfone, Polyester fiber, Layer-by-layer assembly, Property

HUANG Lihua, HE Yao, JIN Liying, HOU Xiuwei, MIAO Luyang, LÜ Changli. Fabrication and Properties of Graphene Oxide/Sulfonated Polyethersulfone Layer-by-layer Assembled Polyester Fiber Composite Proton Exchange Membranes[J]. 高等学校化学研究, 2018, 34(2): 318-325.

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Fabrication and Properties of Graphene Oxide/Sulfonated Polyethersulfone Layer-by-layer Assembled Polyester Fiber Composite Proton Exchange Membranes

Fabrication and Properties of Graphene Oxide/Sulfonated Polyethersulfone Layer-by-layer Assembled Polyester Fiber Composite Proton Exchange Membranes

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