Two New Inorganic-organic Hybrid Compounds Constructed from Different Polymolybdates and Transition Metal-amine Subunits

doi:10.1007/s40242-015-4386-x

高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (3): 337-341.doi: 10.1007/s40242-015-4386-x

Two New Inorganic-organic Hybrid Compounds Constructed from Different Polymolybdates and Transition Metal-amine Subunits

WANG Xiuli, LIU Danna, HAN Na, LIN Hongyan, LUAN Jian, TIAN Aixiang

Liaoning Province Silicon Materials Engineering Technology Research Centre, Department of Chemistry, Bohai University, Jinzhou 121000, P. R. China

收稿日期:2014-10-14 修回日期:2015-01-26 出版日期:2015-06-01 发布日期:2015-02-02
通讯作者: WANG Xiuli E-mail:wangxiuli@bhu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21171025, 21471021), the Fund for the New Century Excellent Talents in Universities of China(No.NCET-09-0853) and the Program of Innovative Research Team in Universities of Liaoning Province, China(No.LT2012020).

Two New Inorganic-organic Hybrid Compounds Constructed from Different Polymolybdates and Transition Metal-amine Subunits

WANG Xiuli, LIU Danna, HAN Na, LIN Hongyan, LUAN Jian, TIAN Aixiang

Liaoning Province Silicon Materials Engineering Technology Research Centre, Department of Chemistry, Bohai University, Jinzhou 121000, P. R. China

Received:2014-10-14 Revised:2015-01-26 Online:2015-06-01 Published:2015-02-02
Contact: WANG Xiuli E-mail:wangxiuli@bhu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21171025, 21471021), the Fund for the New Century Excellent Talents in Universities of China(No.NCET-09-0853) and the Program of Innovative Research Team in Universities of Liaoning Province, China(No.LT2012020).

摘要/Abstract

摘要：

Two new polyoxometalate(POM)-based hybrid compounds, [Cu(en)][H₄Mo₄O₁₆]_0.5(1)(en=ethylene- diamine) and [Ag(3-C₅H₆N₂)₂][H₂PMo₁₂O₄₀](2)(3-C₅H₆N₂=3-aminopyridine), containing different transition metal-amine subunits were hydrothermally synthesized and characterized by elemental analyses, infrared spectroscopy and single-crystal X^-ray diffraction. For compound 1, each [H₄Mo₄O₁₆]^4-(Mo₄O₁₆) cluster was linked to four neighboring Mo₄O₁₆ clusters through four [Cu(en)]²⁺ subunits to yield a (2,4)-connected 2D layer, which was further extended to a 3D supramolecular network via hydrogen bonding interactions. For compound 2, the adjacent [H₂PMo₁₂O₄₀]^- clusters were bridged by [Ag(3-C₅H₆N₂)₂]⁺ subunits to generate a 1D chain. The electrochemical behaviors and the photocatalytic activities of compounds 1 and 2 were studied in detail.

关键词: Polyoxometalate, Metal-amine unit, Crystal structure, Electrochemical property, Photocatalysis

Abstract:

Key words: Polyoxometalate, Metal-amine unit, Crystal structure, Electrochemical property, Photocatalysis

WANG Xiuli, LIU Danna, HAN Na, LIN Hongyan, LUAN Jian, TIAN Aixiang. Two New Inorganic-organic Hybrid Compounds Constructed from Different Polymolybdates and Transition Metal-amine Subunits[J]. 高等学校化学研究, 2015, 31(3): 337-341.

参考文献

[1] Gao G. G., Li F. Y., Xu L., Liu X. Z., Yang Y. Y., J. Am. Chem. Soc., 2008, 130, 10838
[2] Zhao J. W., Song Y. P., Ma P. T., Wang J. P., Niu J. Y., J. Solid State Chem., 2009, 182, 1798
[3] Wu Q., Li Y. G., Wang Y. H., Wang E. B., Zhang Z. M., Clerac R., Inorg. Chem., 2009, 48, 606
[4] Park J., Li J. R., Chen Y. P., Yu J. M., Yakovenko A. A., Wang Z. U., Sun L. B., Balbuena P. B., Zhou H. C., Chem. Commun., 2012, 48, 9995
[5] Lin R. B., Chen D., Lin Y. Y., Zhang J. P., Chen X. M., Inorg. Chem., 2012, 51, 9950
[6] Bi Y. F., Wang X. T., Liao W. P., Wang X. F., Wang X. W., Zhang H. J., Gao S., J. Am. Chem. Soc., 2009, 131, 11650
[7] Wang X. L., Bi Y. F., Chen B. K., Lin H. Y., Liu G. C., Inorg. Chem., 2008, 47, 2442
[8] Dolbecq A., Mialane P., Lisnard L., Marrot J., Sécheresse F., Chem. Eur. J., 2003, 9, 2914
[9] Lu C. Z., Wu C. D., Zhuang H. H., Huang J. S., Chem. Mater., 2002, 14, 2649
[10] Wang X. L., Wang Y. F., Liu G. C., Tian A. X., Zhang J. W., Lin H. Y., Dalton Trans., 2011, 40, 9299
[11] Zhang X., Liu S. X., Li S. J., Wang X. N., Jin H. Y., Cui J. L., Liu Y. W., Liu C. Z., Chem. J. Chinese Universities, 2013, 34(9), 2046
[12] Mirzaei M., Eshtiagh-Hosseini H., Alipour M., Fronter A., Coord. Chem. Rev., 2014, 275, 1
[13] Wu X. Y., Dong P., Yu R. M., Zhang Q. K., Kuang X. F., Chen S. C., Lin Q. P., Lu C. Z., Cryst. Eng. Comm., 2011, 13, 3686
[14] Gil-García R., Zichner R., Díez-Gómez V., Donnadieu B., Madariaga G., Insausti M., Lezama L., Vitoria P., Pedrosa M. R., García-Tojal J., Eur. J. Inorg. Chem., 2010, 28, 4513
[15] Chen L. J., Xia C. K., Zhang Q. Z., Yang W. B., Lu C. Z., Inorg. Chem. Commun., 2005, 8, 858
[16] Gong Y., Wu T., Jiang P. G., Lin J. H., Yang Y. X., Inorg. Chem., 2013, 52, 777
[17] Rarig R. S., Zubieta J., Polyhedron, 2003, 22, 177
[18] Chen Y. Q., Li G. R., Qu Y. K., Zhang Y. H., He K. H., Gao Q., Bu X. H., Cryst. Growth Des., 2013, 13, 901
[19] Lin H. Y., Xu C., Wang X. L., Chang Z. H., Tian A. X., Liu G. C., Zhang J. W., Inorg. Chem. Commun., 2013, 36, 81
[20] Luo L., Lin H. S., Li L., Smirnova T. I., Maggard P. A., Inorg. Chem., 2014, 53, 3464
[21] Guo G. L., Xu Y. Q., Chen B. K., Hu C. W., J. Coord. Chem., 2011, 64, 1032
[22] Zhang C. L., Shen X. M., Lü S. Z., Peng Z. S., Zhu W., Cai T. J., J. Mol. Struct., 2012, 1016, 155
[23] Sheldrick G. M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, 64, 112
[24] Sheldrick G. M., SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Göttingen, 1997
[25] Wang X. L., Li N., Tian A. X., Ying J., Liu G. C., Lin H. Y., Zhang J. W., Yang Y., Dalton Trans., 2013, 42, 14856
[26] Tian A. X., Ying J., Peng J., Sha J. Q., Su Z. M., Pang H. J., Zhang P. P., Chen Y., Zhu M., Shen Y., Cryst. Growth Des., 2010, 10, 1104
[27] Gu J., Jiang X. E., Su Z. H., Zhao Z. F., Zhou B. B., Inorg. Chim. Acta, 2013, 400, 210
[28] Han Q. X., Ma P. T., Zhao J. W., Wang Z. L., Yang W. H., Guo P. H., Wang J. P., Niu J. Y., Cryst. Growth Des., 2011, 11, 436
[29] Qi M. L., Yu K., Su Z. H., Wang C. X., Wang C. M., Zhou B. B., Zhu C. C., Inorg. Chim. Acta, 2013, 400, 59
[30] Deng Q., Huang Y. L., Peng Z. S., Dai Z. J., Lin M. R., Cai T. J., J. Solid State Chem., 2013, 200, 60
[31] Wang X. L., Wang E. B., Lan Y., Hu C. W., Electroanalysis, 2002, 14, 1116
[32] Du X. D., Li C. H., Zhang Y., Liu S., Ma Y., You X. Z., Cryst. Eng. Comm., 2011, 13, 2350
[33] Liu H. Y., Bo L., Yang J., Liu Y. Y., Ma J. F., Wu H., Dalton Trans., 2011, 40, 9782
[34] Wang X. L., Li N., Tian A. X., Ying J., Li T. J., Lin X. L., Luan J., Yang Y., Inorg. Chem., 2014, 53, 7118

Two New Inorganic-organic Hybrid Compounds Constructed from Different Polymolybdates and Transition Metal-amine Subunits

Two New Inorganic-organic Hybrid Compounds Constructed from Different Polymolybdates and Transition Metal-amine Subunits

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