Structure, Thermal Behavior and Characterization of a New Hybrid Iron Fluoride FeF4(2,2'-bipyridine)(H2O)2

doi:10.1007/s40242-015-4171-x

高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (1): 16-20.doi: 10.1007/s40242-015-4171-x

Structure, Thermal Behavior and Characterization of a New Hybrid Iron Fluoride FeF₄(2,2'-bipyridine)(H₂O)₂

Mouna SMIDA^1,2, Hager LITAIEM¹, Mohamed DAMMAK¹, Santiago GARCIA-GRANDA²

1. Laboratoire de Chimie Inorganique, Faculté des Sciences de Sfax, Université de Sfax, 3000Sfax, Tunisie;
2. Département de Chimie, Physique Analytique, Faculté de Chimie, Université d'Oviedo-CINN, 33006 Oviedo, Spain

收稿日期:2014-05-05 修回日期:2014-05-30 出版日期:2015-02-01 发布日期:2015-01-21
通讯作者: Mouna SMIDA, E-mail:mouna.smida@yahoo.fr E-mail:mouna.smida@yahoo.fr
基金资助:
Supported by the Project from the Ministry of Superior Education and the Research of Tunisia and Spanish MINECO (No. MAT2006-150AM).

Structure, Thermal Behavior and Characterization of a New Hybrid Iron Fluoride FeF₄(2,2'-bipyridine)(H₂O)₂

Mouna SMIDA^1,2, Hager LITAIEM¹, Mohamed DAMMAK¹, Santiago GARCIA-GRANDA²

1. Laboratoire de Chimie Inorganique, Faculté des Sciences de Sfax, Université de Sfax, 3000Sfax, Tunisie;
2. Département de Chimie, Physique Analytique, Faculté de Chimie, Université d'Oviedo-CINN, 33006 Oviedo, Spain

Received:2014-05-05 Revised:2014-05-30 Online:2015-02-01 Published:2015-01-21
Contact: Mouna SMIDA, E-mail:mouna.smida@yahoo.fr E-mail:mouna.smida@yahoo.fr
Supported by:
Supported by the Project from the Ministry of Superior Education and the Research of Tunisia and Spanish MINECO (No. MAT2006-150AM).

摘要/Abstract

摘要：

New crystal of FeF₄(2,2'-bipyridine)(H₂O)₂ was prepared by hydrothermal synthesis. Crystalline structure determination is performed from single crystal X-ray diffraction data. The unit cell is monoclinic space group P2₁/n, with cell parameters a=0.9046(5) nm, b=0.7502(5) nm, c=1.9539(5) nm, β=93.307(5)°, V=1.3238(12) nm³ and Z=4. The structure of FeF₄(2,2'-bipyridine)(H₂O)₂ is built up from FeF₄N₂ octahedra coordinated by two nitrogen atoms of the 2,2'-bipyridine molecules, and four fluorine atoms as well as uncoordinated H₂O molecules. Thermal analysis of the title compound showed that the decomposition introduced four steps. IR spectra confirmed the presence of 2,2'-bipyridine molecules. The optical absorption was measured at the corresponding l_max using UV-Vis diffuse reflectance spectrum.

关键词: Hydrothermal synthesis, Hybrid, Iron fluoride

Abstract:

Key words: Hydrothermal synthesis, Hybrid, Iron fluoride

Mouna SMIDA, Hager LITAIEM, Mohamed DAMMAK, Santiago GARCIA-GRANDA. Structure, Thermal Behavior and Characterization of a New Hybrid Iron Fluoride FeF₄(2,2'-bipyridine)(H₂O)₂[J]. 高等学校化学研究, 2015, 31(1): 16-20.

0
/ / 推荐 2O)₂”的文章，特向您推荐。请打开下面的网址：https://crcu.jlu.edu.cn/CN/abstract/abstract3736.shtml' name="neirong"> 2O)₂'>

导出引用管理器 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

链接本文: https://crcu.jlu.edu.cn/CN/10.1007/s40242-015-4171-x

https://crcu.jlu.edu.cn/CN/Y2015/V31/I1/16

参考文献

[1] Touret J., Bourdon X., Leblanc M., Retoux R., Renaudin J., Maisonneuve V., J. Fluorine Chem., 2001, 110, 133
[2] Smida M., Lhoste J., Pimenta V., Hémon-Ribaud A., Jouffret L., Leblanc M., Dammak M., Grenèche J. M., Maisonneuve V., Dalton Trans., 2013, 42, 15748
[3] Liu J. Q., Wang Y. Y., Zhang Y. N., Liu P., Shi Q. Z., Battern R., Eur. J. Inorg. Chem., 2009, 1, 147
[4] Su Z., Fan J., Okamura T., Sun Y. W., Ueyama N., Cryst. Growth. Des., 2010, 10, 3515
[5] Sanchez C., Ribot F., New J. Chem., 1994, 18, 1007
[6] Férey G., L'actualité Chimique, 2007, 304, 3
[7] Adil K., Leblanc M., Maisonneuve V., Lightfoot P., Dalton Trans., 2010, 39, 5983
[8] Collins D. J., Zhou H. C., J. Mater. Chem., 2007, 17, 3154
[9] Gandara F., Gomez-Lor B., Gutierrez-Puebla Iglesias E., Monge M. A., Proserpio D. M., Snejko N., Chem. Mater., 2008, 20, 72
[10] Halper S. R., Do L., Stork J. R., Cohen S. M., J. Am. Chem. Soc., 2006, 128, 15255
[11] Ye Q., Fu D. W., Tian H., Xiong R. G., Chan P. W. H., Huang S. P. D., Inorg. Chem., 2008, 47, 772
[12] Zhang J. P., Lin Y. Y., Huang X. C., Chen X. M., J. Am. Chem. Soc., 2005, 127, 5495
[13] Férey G., Millange F., Morcrette M., Serre C., Doublet M., Grenéche J. M., Tarascon J. M., Angew. Chem., 2007, 46, 3259
[14] Sheldrick G. M., SHELXS 97, Program for the Solution of Crystal Structures, University of GÖttingen, GÖttingen, 1997
[15] Sheldrick G. M., SHELXL 97, Program for the Solution of Crystal Structures, University of GÖttingen, GÖttingen, 1997
[16] Farrugia L. J., J. Appl. Cryst., 1999, 32, 837
[17] Brandenburg K., Berndt M., Crystal Impact, Diamond, Version 2.1.b, GbR., Bonn, 1999
[18] Vargas W. E., J. Opt. A: Pure Appl. Opt., 2002, 4, 452
[19] Kubelka P., Part I, J., Opt. Soc. Am., 1948, 38, 448
[20] Liu H. X., Acta Cryst., 2009, E65, 1093
[21] Czakis-Sulikowska D., Katuzna-Czapliñska J., J. Ther. Ana. Calor., 2000, 62, 821
[22] Niven M. L., Percy G. C., Transition Met. Chem., 1978, 3, 267
[23] Strukl J. S., Walter J. L., Spectrochimica Acta, 1971, 27A, 223
[24] Cotton S. A., Coord. Chem. Rev., 1972, 8, 185
[25] Han Z., Guo J., Li W., Chem. Eng. J., 2013, 228, 36
[26] Cheetham A. K., Rao C. N. R., Feller R. K., Chem. Commun., 2006, 4780

Structure, Thermal Behavior and Characterization of a New Hybrid Iron Fluoride FeF₄(2,2'-bipyridine)(H₂O)₂

Structure, Thermal Behavior and Characterization of a New Hybrid Iron Fluoride FeF₄(2,2'-bipyridine)(H₂O)₂

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	WANG Yibin, TIAN Liang, ZHU Tianhao, MEI Jing, CHEN Zezhong, YU Deng-Guang. Electrospun Aspirin/Eudragit/Lipid Hybrid Nanofibers for Colon-targeted Delivery Using an Energy-saving Process[J]. 高等学校化学研究, 2021, 37(3): 443-449.
[2]	LIN Qingjin, LIN Chenlu, LIU Jingying, LIU Shuang, XU Haidi, CHEN Yaoqiang, DAN Yi. Optimization of Hybrid Crystal with SAPO-5/34 on Hydrothermal Stability for deNO_x Reaction by NH₃[J]. 高等学校化学研究, 2020, 36(6): 1249-1254.
[3]	LI Yujie, CHEN Jie, DONG Yuanchen, LIU Huajie, LIU Dongsheng. Construction of pH-Triggered DNA Hydrogels Based on Hybridization Chain Reactions[J]. 高等学校化学研究, 2020, 36(2): 243-246.
[4]	LI Xue, YANG Donglei, SHEN Luyao, XU Fan, WANG Pengfei. Programmable Assembly of DNA-protein Hybrid Structures[J]. 高等学校化学研究, 2020, 36(2): 211-218.
[5]	LIU Shuo, YANG Mingjie, GUO Weiwei. Programmable and Reversible Regulation of Catalytic Hemin@MOFs Activities with DNA Structures[J]. 高等学校化学研究, 2020, 36(2): 301-306.
[6]	LIU Zhenchao, WANG Peng, HU Wei, LIU Baijun. Preparation and Properties of Hybrid Silane-crosslinked Sulfonated Poly(aryl ether ketone)s as Proton Exchange Membranes[J]. 高等学校化学研究, 2019, 35(5): 937-944.
[7]	WEN Xuemei, YI Fangshun, JI Jinhai, BI Yangang, ZHANG Wenyi, WANG Wenquan. S-1805/Ag/Au Hybrid Transparent Electrodes for ITO-f ree Flexible Organic Photovoltaics[J]. 高等学校化学研究, 2019, 35(3): 509-513.
[8]	LI Xianliang, SHI Zuosen, CUI Zhanchen, ZHU Song. Silver Chloride Loaded Hollow Mesoporous Silica Particles and Their Application in the Antibacterial Coatings on Denture Base[J]. 高等学校化学研究, 2018, 34(3): 495-499.
[9]	LIU Rui, QIAO Yingjie, SONG Yingjin, SONG Kehan, LIU Chuan. Enhanced Efficiency of Dye-sensitized Solar Cells Using rGO@TiO₂ Nanotube Hybrids[J]. 高等学校化学研究, 2018, 34(2): 269-273.
[10]	ZHANG Jiaqi, WANG Shan, YUAN Long, HOU Changmin. Hydrothermal Synthesis and Magnetic Properties ofSmCr_0.5M_0.5O₃(M=Fe and Mn) Micro-plates[J]. 高等学校化学研究, 2018, 34(1): 1-7.
[11]	JIANG Yuhang, LI Yao, WANG Xuesong, PIAO Linglan, SHI Zuosen, CUI Zhanchen. Fabrication of New Transparent and Hydrophilic Hybrid Anti-fog Coating from Silane Coupler Modified by Polyethylene Glycols[J]. 高等学校化学研究, 2017, 33(1): 150-154.
[12]	YU Ye, WANG Yuxiang, FENG Chuanliang. Hybrid Hydrogels Assembled from Phenylalanine Derivatives and Agarose with Enhanced Mechanical Strength[J]. 高等学校化学研究, 2016, 32(5): 872-876.
[13]	HUANG Hongxiang, HE Wenli, MA Yueyang. Preparation, Characterization, Luminescent and Electrochemical Properties of Ru(bpy)₂-functionalized Silica Nanoparticles[J]. 高等学校化学研究, 2016, 32(4): 695-701.
[14]	ZHANG Zaichao, HU Gonghao, XU Yan. Hydrothermal Synthesis, Structure and Properties of a New Phosphomolybdate Based on Novel [Co(H₂O)₄(HP₂Mo₅O₂₃)]^8- Anions and [H₈(H₂O)₁₆]⁸⁺ Water Cluster Cations[J]. 高等学校化学研究, 2016, 32(3): 329-333.
[15]	WANG Xi, HAN Bin, GAO Yan, WANG Li, BAI Ming. HEDP-capped Terbium Orthophosphate Nanoparticles as Sensitive Luminescent Probes for the Detection of Pb²⁺ Ions[J]. 高等学校化学研究, 2016, 32(3): 325-328.