Preparation, Structure and Magnetic Properties of Lithium Substituted NiO by Molten Salt Method

doi:10.1007/s40242-013-2159-y

高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (2): 210-213.doi: 10.1007/s40242-013-2159-y

Preparation, Structure and Magnetic Properties of Lithium Substituted NiO by Molten Salt Method

DU Fei¹, BIE Xiao-fei¹, BIAN Xiao-fei², HU Fang³, CHEN Gang¹, WANG Chun-zhong¹, WEI Ying-jin¹

1. Key Laboratory of Advanced Batteries Physics and Technology, Ministry of Education, College of Physics, Jilin University, Changchun 130012, P. R. China;
2. School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China;
3. School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, P. R. China

收稿日期:2012-04-23 修回日期:2012-06-25 出版日期:2013-04-01 发布日期:2013-03-20
通讯作者: WEI Ying-jin E-mail:yjwei@jlu.edu.cn
基金资助:
Supported by the Special Funds for Major National Basic Research Project of China(No.2009CB220104), the National Natural Science Foundation of China(No.11004073) and the Research Fund for the Doctoral Program of Higher Education of China(New Teacher)(No.20090061120020) and Partially Supported by the Development Program of Science and Technology of Jilin Province, China(No.201205035).

Preparation, Structure and Magnetic Properties of Lithium Substituted NiO by Molten Salt Method

DU Fei¹, BIE Xiao-fei¹, BIAN Xiao-fei², HU Fang³, CHEN Gang¹, WANG Chun-zhong¹, WEI Ying-jin¹

1. Key Laboratory of Advanced Batteries Physics and Technology, Ministry of Education, College of Physics, Jilin University, Changchun 130012, P. R. China;
2. School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China;
3. School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, P. R. China

Received:2012-04-23 Revised:2012-06-25 Online:2013-04-01 Published:2013-03-20
Supported by:
Supported by the Special Funds for Major National Basic Research Project of China(No.2009CB220104), the National Natural Science Foundation of China(No.11004073) and the Research Fund for the Doctoral Program of Higher Education of China(New Teacher)(No.20090061120020) and Partially Supported by the Development Program of Science and Technology of Jilin Province, China(No.201205035).

摘要/Abstract

摘要：

A typical Li⁺ substituted NiO compound, Li_0.29Ni_0.71O, was synthesized by molten nitrate method. The effects of Li⁺ substitution on the structure and magnetic properties of NiO were investigated. X-Ray diffraction(XRD), scanning electron microscope(SEM) and high-resolution transmission electron microscope(HRTEM) analyses confirm the cubic structure of Li_0.29Ni_0.71O, with a primary particle size of 150 nm. Analysis of the Ni X-ray photoelectron spectroscopy(XPS) shows the transformation from Ni²⁺ to Ni³⁺ induced by Li⁺ substitution. Two magnetic transitions were observed at 225 and 55 K which were assigned to the ferrimagnetic ordering and spin glass transition, respectively. The different magnetic behavior with respect to that of NiO was attributed to the break of superexchange interaction Ni²⁺-O-Ni²⁺ and the formation of different spin clusters after non-magnetic Li⁺ doping.

关键词: NiO, Magnetic property, Substitution effect

Abstract:

Key words: NiO, Magnetic property, Substitution effect

DU Fei, BIE Xiao-fei, BIAN Xiao-fei, HU Fang, CHEN Gang, WANG Chun-zhong, WEI Ying-jin. Preparation, Structure and Magnetic Properties of Lithium Substituted NiO by Molten Salt Method[J]. 高等学校化学研究, 2013, 29(2): 210-213.

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Preparation, Structure and Magnetic Properties of Lithium Substituted NiO by Molten Salt Method

Preparation, Structure and Magnetic Properties of Lithium Substituted NiO by Molten Salt Method

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