Reduction Removal of Cr(VI) from Wastewater by CO2·- Deriving from Formate Anion Based on Activated Carbon Catalyzed Persulfate

doi:10.1007/s40242-020-0169-0

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (5): 870-876.doi: 10.1007/s40242-020-0169-0

Reduction Removal of Cr(VI) from Wastewater by CO₂^·- Deriving from Formate Anion Based on Activated Carbon Catalyzed Persulfate

ZHOU Rui, LI Tingting, ZHANG Lijian, JIAO Xinqian

Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin Provincial Key Laboratory of Water Resource and Environment, College of New Energy and Environment, Jilin University, Changchun 130021, P. R. China

收稿日期:2020-06-05 修回日期:2020-07-06 出版日期:2020-10-01 发布日期:2020-10-01
通讯作者: JIAO Xinqian E-mail:jiaoxq@jlu.edu.cn
基金资助:
Supported by the National Nature Science Foundation of China(No.41302184), the Project of the Research on Water Environmental Protection Strategy and Management Policy in Beijing-Tianjin-Hebei Region, China(No.2018ZX07111001), the Scientific Frontier and Interdisciplinary Research Project of Jilin University, the Outstanding Youth Cultivation Plan of Jilin University, the Fund of the Key Laboratory of Groundwater Resources and Environmental of Ministry of Education(Jilin University), China, and the Project of the National and Local Joint Engineering Laboratory for Petrochemical Contaminated Site Control and Remediation Technology of China.

Reduction Removal of Cr(VI) from Wastewater by CO₂^·- Deriving from Formate Anion Based on Activated Carbon Catalyzed Persulfate

ZHOU Rui, LI Tingting, ZHANG Lijian, JIAO Xinqian

Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin Provincial Key Laboratory of Water Resource and Environment, College of New Energy and Environment, Jilin University, Changchun 130021, P. R. China

Received:2020-06-05 Revised:2020-07-06 Online:2020-10-01 Published:2020-10-01
Contact: JIAO Xinqian E-mail:jiaoxq@jlu.edu.cn
Supported by:
Supported by the National Nature Science Foundation of China(No.41302184), the Project of the Research on Water Environmental Protection Strategy and Management Policy in Beijing-Tianjin-Hebei Region, China(No.2018ZX07111001), the Scientific Frontier and Interdisciplinary Research Project of Jilin University, the Outstanding Youth Cultivation Plan of Jilin University, the Fund of the Key Laboratory of Groundwater Resources and Environmental of Ministry of Education(Jilin University), China, and the Project of the National and Local Joint Engineering Laboratory for Petrochemical Contaminated Site Control and Remediation Technology of China.

摘要/Abstract

摘要： As a strong reducing radical, carbon dioxide anion radical(CO₂^·-) can be generated by initiating sulfate radical(SO₄^·-) in the presence of formate anions(FA) for Cr(VI) reduction. Moreover, activated carbon(AC)-catalyzed persulfate(PS) oxidation is an economically justifiable, environmentally friendly, and easy-to-scale-up method to produce SO₄^·-. The complete removal of Cr(VI) was achieved within 280 min for an initial Cr(VI) concentration of 50 mg/L under the optional condition of c(AC)=1 g/L, [PS]₀=10 mmol/L, [FA]₀=10 mmol/L, T=30℃, and unadjusted pH. When the molar ratio of FA to PS was greater than or equal to 1, the system maintained a strong reduction state. The mechanism investigation confirmed that FA was converted to carboxyl anion radical(CO₂^·-) as the predominant radical for Cr(VI) reduction. This novel system may offer a potential platform technology for Cr(VI) wastewater treatment.

关键词: Cr(VI), Activated carbon, Carboxyl anion radical, Persulfate, Reduction

Abstract: As a strong reducing radical, carbon dioxide anion radical(CO₂^·-) can be generated by initiating sulfate radical(SO₄^·-) in the presence of formate anions(FA) for Cr(VI) reduction. Moreover, activated carbon(AC)-catalyzed persulfate(PS) oxidation is an economically justifiable, environmentally friendly, and easy-to-scale-up method to produce SO₄^·-. The complete removal of Cr(VI) was achieved within 280 min for an initial Cr(VI) concentration of 50 mg/L under the optional condition of c(AC)=1 g/L, [PS]₀=10 mmol/L, [FA]₀=10 mmol/L, T=30℃, and unadjusted pH. When the molar ratio of FA to PS was greater than or equal to 1, the system maintained a strong reduction state. The mechanism investigation confirmed that FA was converted to carboxyl anion radical(CO₂^·-) as the predominant radical for Cr(VI) reduction. This novel system may offer a potential platform technology for Cr(VI) wastewater treatment.

Key words: Cr(VI), Activated carbon, Carboxyl anion radical, Persulfate, Reduction

ZHOU Rui, LI Tingting, ZHANG Lijian, JIAO Xinqian. Reduction Removal of Cr(VI) from Wastewater by CO₂^·- Deriving from Formate Anion Based on Activated Carbon Catalyzed Persulfate[J]. 高等学校化学研究, 2020, 36(5): 870-876.

参考文献 52

[1]	Kobya M., Bioresour Technol., 2004, 91(3), 317
[2]	du Preez S. P., Beukes J. P., van Zyl P. G., Metallurgical and Materials Transactions B, 2014, 46(2), 1002
[3]	Nakajima A., Baba Y., Water Res., 2004, 38(12), 2859
[4]	Zhang Y. J., Ou J. L., Duan Z. K., Xing Z. J., Wang Y., Colloids & Surfaces A:Physicochemical & Engineering Aspects, 2015, 481, 108
[5]	Fang Z., Qiu X., Huang R., Qiu X., Li M., Desalination, 2011, 280(1), 224
[6]	Bansal M., Singh D., Garg V. K., J. Hazard Mater., 2009, 171(1), 83
[7]	Wang N., Zhu L., Deng K., She Y., Yu Y., Tang H., Applied Catalysis B:Environmental, 2010, 95(3/4), 400
[8]	Daulton T. L., Little B. J., Jones-Meehan J., Blom D. A., Allard L. F., Geochim Cosmochim Acta, 2007, 71(3), 556
[9]	Thomson R. C., Miller M. K., Acta Mater., 1998, 46(6), 2203
[10]	Zongo I., Leclerc J.-P., Maiga H. A., Wethe J., Lapicque F., Sep. Purif Technol., 2009, 66(1), 159
[11]	Tosco T., Papini M. P., Viggi C. C., Sethi R., Journal of Cleaner Production, 2014, 77, 10
[12]	Oh W.-D., Dong Z., Lim T.-T., Applied Catalysis B:Environmental, 2016, 194, 169
[13]	Rosso J. A., Bertolotti S. G., Braun A. M., Martire D. O., Gonzalez M. C., J. Phys. Org. Chem., 2001, 14(5), 300
[14]	Tachikawa T., Tojo S., Fujitsuka M., Majima T., Langmuir, 2004, 20(22), 9441
[15]	Schutz O., Meyerstein D., Tetrahedron Lett., 2006, 47(7), 1093
[16]	Mora V. C., Rossoa J. A., Carrillo Le Roux G., Martire D. O., Gonzalez M. C., Chemosphere, 2009, 75(10), 1405
[17]	Wu W., Liu G., Liang S., Chen Y., Shen L., Zheng H., Yuan R., Hou Y., Wu L., J. Catal., 2012, 290, 13
[18]	Berkovic A. M., Bertolotti S. G., Villata L. S., Gonzalez M. C., Pis Diez R., Martire D. O., Chemosphere, 2012, 89(10), 1189
[19]	Berkovic A. M., Gonzalez M. C., Russo N., Michelini M. D. C., Pis Diez R., Martire D. O., J. Phys. Chem. A, 2010, 114(49), 12845
[20]	Ren H., Hou Z., Han X., Zhou R., Chem. Eng. J., 2017, 309, 638
[21]	Harbour J. R., Hair M. L., Canadian Journal of Chemistry, 1979, 57(10), 1150
[22]	Wang J., Wang S., Chem. Eng. J., 2018, 334, 1502
[23]	Wang G., Chen S., Quan X., Yu H., Zhang Y., Carbon, 2017, 115, 730
[24]	Kordkandi S. A., Forouzesh M., Journal of the Taiwan Institute of Chemical Engineers, 2014, 45(5), 2597
[25]	Li J., Lin H., Zhu K., Zhang H., Chemosphere, 2017, 188, 139
[26]	Vega E., Valdes H., Microporous Mesoporous Mater., 2018, 259, 1
[27]	Lee Y. C., Lo S. L., Kuo J., Huang C. P., J. Hazard Mater., 2013, 261, 463
[28]	Yang S., Yang X., Shao X., Niu R., Wang L., J. Hazard Mater., 2011, 186(1), 659
[29]	Forouzesh M., Ebadi A., Aghaeinejad-Meybodi A., Sep. Purif Technol., 2019, 210, 145
[30]	Fierro V., Torne-Fernandez V., Celzard A., Montane D., J. Hazard Mater., 2007, 149(1), 126
[31]	Liang C., Lin Y. T., Shih W. H., Ind. Eng. Chem. Res., 2009, 48(18), 8373
[32]	Diao Z. H., Xu X. R., Jiang D., Kong L. J., Sun Y. X., Hu Y. X., Hao Q. W., Chen H., Chem. Eng. J., 2016, 302, 213
[33]	Wang N., Zhu L., Deng K., She Y., Yu Y., Tang H., Applied Catalysis B:Environmental, 2010, 95(3/4), 400
[34]	Liang C., Huang C. F., Mohanty N., Kurakalva R. M., Chemosphere, 2008, 73(9), 1540
[35]	Sun Y., Yue Q., Mao Y., Gao B., Yuan G., Huang L., J. Hazard Mater., 2014, 265(2), 191
[36]	Cheng S., Zhang L., Ma A., Xia H., Peng J., Li C., Shu J., J. Environ. Sci., 2018, 65, 92
[37]	Xu M., Gu X., Lu S., Qiu Z., Sui Q. J. I., Ind. Eng. Chem. Res., 2014, 53(3), 1056
[38]	Guedidi H., Reinert L., Lévêque J. M., Soneda Y., Duclaux L. J. C., Carbon, 2013, 54, 432
[39]	Liu W., Zhang J., Zhang C., Ren L., Chem. Eng. J., 2012, 189, 295
[40]	Gupta V. K., Shrivastava A. K., Jain N., Water. Res., 2001, 35(17), 4079
[41]	Reymond J. P., Kolenda F., Powder Technol., 1999, 103(1), 30
[42]	Mohan D., Pittman C. U. Jr., J. Hazard Mater., 2006, 137(2), 762
[43]	Powell R. M., Blowes D. W., Gillham R. W., Schultz D., Sivavec T., Puls R. W., Vogan J. L., Powell P. D., Landis R., Office of Research and Development, Office of Solid Waste and Emergency Response, USEPA, EPA/600/R-98/125, 1998
[44]	Santos A., Fernandez J., Rodriguez S., Dominguez C. M., Lominchar M. A., Lorenzo D., Romero A., Sci. Total. Environ., 2018, 615, 1070
[45]	Yang J. F., Yang L. M., Zhang S. B., Ou L. H., Liu C. B., Zheng L. Y., Yang Y. F., Ying G. G., Luo S. L., Chem. Eng. J., 2017, 321, 113
[46]	Danis U., Environ. Prog. Sustain Energy, 2011, 30(2), 177
[47]	Vega F. A., Covelo F. E., Spanish Journal of Soil Science, 2011, 1(1), 20
[48]	Lei Y., Chen C. S., Tu Y. J., Huang Y. H., Zhang H., Environ. Sci. Technol., 2015, 49(11), 6838
[49]	Liu H., Bruton T. A., Doyle F. M., Sedlak D. L., Environ. Sci. Technol., 2014, 48(17), 10330
[50]	Villamena F. A., Locigno E. J., Rockenbauer A., Hadad C. M., Zweier J. L., J. Phys. Chem. A, 2006, 110(49), 13253
[51]	Zamora P. L., Villamena F. A., J. Phys. Chem. A, 2012, 116(26), 7210
[52]	Das S., Mishra J., Das S. K., Pandey S., Rao D. S., Chakraborty A., Sudarshan M., Das N., Thatoi H., Chemosphere, 2014, 96, 112

Reduction Removal of Cr(VI) from Wastewater by CO₂^·- Deriving from Formate Anion Based on Activated Carbon Catalyzed Persulfate

Reduction Removal of Cr(VI) from Wastewater by CO₂^·- Deriving from Formate Anion Based on Activated Carbon Catalyzed Persulfate

可视化

摘要/Abstract

引用本文

使用本文

参考文献 52

相关文章 15

编辑推荐

Metrics

本文评价

[1]	XU Guangyuan, LIU Qin, YAN Huan. Recent Advances of Single-atom Catalysts for Electro-catalysis[J]. 高等学校化学研究, 2022, 38(5): 1146-1150.
[2]	BU Ran, LU Yingying, ZHANG Bing. Covalent Organic Frameworks Based Single-site Electrocatalysts for Oxygen Reduction Reaction[J]. 高等学校化学研究, 2022, 38(5): 1151-1162.
[3]	MIAO Tianchang, DI Xin, HAO Feini, ZHENG Gengfeng, HAN Qing. Polymeric Carbon Nitride-based Single Atom Photocatalysts for CO₂ Reduction to C₁ Products[J]. 高等学校化学研究, 2022, 38(5): 1197-1206.
[4]	MA Chunrong, SONG Bingyi, MA Zhentao, WANG Xiaoqian, TIAN Lin, ZHANG Haoran, CHEN Cai, ZHENG Xusheng, YANG Li-ming, WU Yuen. A Supported Palladium on Gallium-based Liquid Metal Catalyst for Enhanced Oxygen Reduction Reaction[J]. 高等学校化学研究, 2022, 38(5): 1219-1225.
[5]	QIAN Shengjie, WANG Yanggang, LI Jun. Single Iron-dimer Catalysts on MoS₂ Nanosheet for Potential Nitrogen Activation[J]. 高等学校化学研究, 2022, 38(5): 1226-1231.
[6]	SHU Chengyong, GAN Zhuofan, ZHOU Jia, WANG Zhen, TANG Wei. Highly Efficient Oxygen Reduction Reaction Fe-N-C Cathode in Long-durable Direct Glycol Fuel Cells[J]. 高等学校化学研究, 2022, 38(5): 1268-1274.
[7]	ZHENG Meng, WANG Jin. Regulating the Oxygen Affinity of Single Atom Catalysts by Dual-atom Design for Enhanced Oxygen Reduction Reaction Activity[J]. 高等学校化学研究, 2022, 38(5): 1275-1281.
[8]	GONG Yu, PAN Jing, ZHANG Lingling, WANG Xiao, SONG Shuyan, ZHANG Hongjie. Metal-Organic Frameworks-derived Indium Clusters/Carbon Nanocomposites for Efficient CO₂ Electroreduction[J]. 高等学校化学研究, 2022, 38(5): 1287-1291.
[9]	ZHENG Ruonan, ZHAI Zihui, QIU Chenxi, GAO Rui, LV Yang, SONG Yujiang. Highly Active Electrocatalyst Derived from ZIF-8 Decorated with Iron(III) and Cobalt(III) Porphyrin Toward Efficient Oxygen Reduction in Both Alkaline and Acidic Media[J]. 高等学校化学研究, 2022, 38(4): 961-967.
[10]	CHEN Yu, CHEN Yongting, LIAO Yuxiang, CHEN Shengli. A Chemical Dealloying Approach for Pt Surface-enriched Pt₃Co Alloy Nanoparticles as Oxygen Reduction Reaction Electrocatalysts[J]. 高等学校化学研究, 2022, 38(4): 991-998.
[11]	JI Yuancheng, XU Jiayun, SUN Hongcheng, and LIU Junqiu. Artificial Photosynthesis(AP): from Molecular Catalysts to Heterogeneous Materials[J]. 高等学校化学研究, 2022, 38(3): 688-697.
[12]	CHANG Shunkai, LI Cuiyan, LI Hui, ZHU Liangkui, FANG Qianrong. Stable Thiophene-sulfur Covalent Organic Frameworks for Oxygen Reduction Reaction(ORR)[J]. 高等学校化学研究, 2022, 38(2): 396-401.
[13]	ZHANG Yin, MA Shengqian. Laser-induced Synthesis of Ultrafine Gold Nanoparticles in Covalent Organic Frameworks[J]. 高等学校化学研究, 2022, 38(2): 468-471.
[14]	YU Xiaoming, MA Yunchao, LI Cuiyan, GUAN Xinyu, FANG Qianrong, QIU Shilun. A Nitrogen, Sulfur co-Doped Porphyrin-based Covalent Organic Framework as an Efficient Catalyst for Oxygen Reduction[J]. 高等学校化学研究, 2022, 38(1): 167-172.
[15]	YI Jundong, LI Qiuxia, CHI Shaoyi, HUANG Yuanbiao, CAO Rong. Boron-doped Covalent Triazine Framework for Efficient CO₂ Electroreduction[J]. 高等学校化学研究, 2022, 38(1): 141-146.