Two New Piperazine Templated Lanthanide Sulfates with 2D Corrugated Layered Crystal Structures

doi:10.1007/s40242-013-2110-2

高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (1): 10-14.doi: 10.1007/s40242-013-2110-2

Two New Piperazine Templated Lanthanide Sulfates with 2D Corrugated Layered Crystal Structures

ZHANG Deng, FAN Xin-rong, LU Yun, XU Yan

State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, P. R. China

收稿日期:2012-03-19 修回日期:2012-05-08 出版日期:2013-02-01 发布日期:2013-01-23
基金资助:
Supported by the Natural Science Foundation of Jiangsu Province of China(No.BK2012823).

Two New Piperazine Templated Lanthanide Sulfates with 2D Corrugated Layered Crystal Structures

ZHANG Deng, FAN Xin-rong, LU Yun, XU Yan

State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, P. R. China

Received:2012-03-19 Revised:2012-05-08 Online:2013-02-01 Published:2013-01-23
Supported by:
Supported by the Natural Science Foundation of Jiangsu Province of China(No.BK2012823).

摘要/Abstract

摘要：

Two new piperazine templated lanthanide sulfates (C₄N₂H₁₂)_1.5[Ln(SO₄)₃(H₂O)]·H₂O[Ln=Gd(1), Tb(2)] have been synthesized solvothermally and structurally characterized by single crystal X-ray diffraction(XRD), infrared(IR) spectroscopy, thermal analysis, fluorescent spectra and inductively coupled plasma(ICP). Single crystal X-ray diffraction reveals that both compounds 1 and 2 crystallized in the monoclinic crystal system, with space group P2₁/c and cell dimensions: a=0.64468(19) nm, b=2.9979(9) nm, c=0.9818(3) nm, β=101.271(4)°, V=1.8608(10) nm³, Z=4 for compound 1; a=0.64259(19) nm, b=3.0010(9) nm, c=0.9812(3) nm, β=101.229(4)°, V=1.8560(10) nm³, Z=4 for compound 2. Compounds 1 and 2 are isomorphous and have similar 2D corrugated inorganic frameworks fabricated via the connection of single chains and S2O₄ groups, while fully protonated piperazine cations and water molecules are located between the inorganic layers. The solid state luminescent properties of compound 2 were investigated and it displayed a typical luminescent property of Tb³⁺ with excitation wavelength at 371 nm.

关键词: Solvothermal synthesis, Lanthanide sulfate, Layered structure, Luminescence

Abstract:

Key words: Solvothermal synthesis, Lanthanide sulfate, Layered structure, Luminescence

ZHANG Deng, FAN Xin-rong, LU Yun, XU Yan. Two New Piperazine Templated Lanthanide Sulfates with 2D Corrugated Layered Crystal Structures[J]. 高等学校化学研究, 2013, 29(1): 10-14.

ZHANG Deng, FAN Xin-rong, LU Yun, XU Yan. Two New Piperazine Templated Lanthanide Sulfates with 2D Corrugated Layered Crystal Structures[J]. Chemical Research in Chinese Universities, 2013, 29(1): 10-14.

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Two New Piperazine Templated Lanthanide Sulfates with 2D Corrugated Layered Crystal Structures

Two New Piperazine Templated Lanthanide Sulfates with 2D Corrugated Layered Crystal Structures

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