Hydrothermal Synthesis and Structural Characterization of a Novel Mixed-Valence Sodium Vanadium(Ⅳ,Ⅴ) Phosphate Na3.6H1.4P2V5O18·11H2O

高等学校化学研究 ›› 1998, Vol. 14 ›› Issue (4): 351-355.

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Hydrothermal Synthesis and Structural Characterization of a Novel Mixed-Valence Sodium Vanadium(Ⅳ,Ⅴ) Phosphate Na_3.6H_1.4P₂V₅O₁₈·11H₂O

PANG Guang-sheng, FENG Shou-hua, XU Ru-ren

Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130023

收稿日期:1997-10-09 出版日期:1998-12-24 发布日期:2011-08-17
通讯作者: FENG Shou-hua
基金资助:
Supported by the NSFC through a National Outstanding Youth Science Fund,the State Education Commission through an Excellent Talent Plan(S.F.).

Hydrothermal Synthesis and Structural Characterization of a Novel Mixed-Valence Sodium Vanadium(Ⅳ,Ⅴ) Phosphate Na_3.6H_1.4P₂V₅O₁₈·11H₂O

PANG Guang-sheng, FENG Shou-hua, XU Ru-ren

Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Department of Chemistry, Jilin University, Changchun 130023

Received:1997-10-09 Online:1998-12-24 Published:2011-08-17

摘要/Abstract

摘要： A novel mixed-valance vanadium phosphate Na_3.6H_1.4P₂V₅O₁₈·11H₂O was synthesized by a hydrothermal method and its structure was characterized by X-ray diffraction, infrared spectroscopy, differential thermal analysis, and thermogravimetric analysis. Na_3.6H_1.4P₂V₅O₁₈·11H₂O crystallizes in the cubic system with the cell parameter a =1.601(8) nm. The ratio of V( Ⅳ)/ V(Ⅴ) in the compound is 3.55.

关键词: Mixed valence vanadium phosphate, Hydrothermal synthesis, Crystallization

Abstract: A novel mixed-valance vanadium phosphate Na_3.6H_1.4P₂V₅O₁₈·11H₂O was synthesized by a hydrothermal method and its structure was characterized by X-ray diffraction, infrared spectroscopy, differential thermal analysis, and thermogravimetric analysis. Na_3.6H_1.4P₂V₅O₁₈·11H₂O crystallizes in the cubic system with the cell parameter a =1.601(8) nm. The ratio of V( Ⅳ)/ V(Ⅴ) in the compound is 3.55.

Key words: Mixed-valence vanadium phosphate, Hydrothermal synthesis, Crystallization

PANG Guang-sheng, FENG Shou-hua, XU Ru-ren . Hydrothermal Synthesis and Structural Characterization of a Novel Mixed-Valence Sodium Vanadium(Ⅳ,Ⅴ) Phosphate Na_3.6H_1.4P₂V₅O₁₈·11H₂O[J]. 高等学校化学研究, 1998, 14(4): 351-355.

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Hydrothermal Synthesis and Structural Characterization of a Novel Mixed-Valence Sodium Vanadium(Ⅳ,Ⅴ) Phosphate Na_3.6H_1.4P₂V₅O₁₈·11H₂O

Hydrothermal Synthesis and Structural Characterization of a Novel Mixed-Valence Sodium Vanadium(Ⅳ,Ⅴ) Phosphate Na_3.6H_1.4P₂V₅O₁₈·11H₂O

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