Hydrothermal Synthesis of a New Zinc Phosphite (C5H7N2)2·[Zn3(HPO3)4] with Intersecting 8- and 12-Ring Channels

doi:10.1007/s40242-015-5021-6

高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (4): 498-502.doi: 10.1007/s40242-015-5021-6

Hydrothermal Synthesis of a New Zinc Phosphite (C₅H₇N₂)₂·[Zn₃(HPO₃)₄] with Intersecting 8- and 12-Ring Channels

DONG Zhaojun^1,2, YAN Yan², ZHANG Wenqing¹, WANG Yu¹, LI Jiyang²

1. Key Lab of Groundwater Resources and Environment, Ministry of Education, College of Environment and Resources, Jilin University, Changchun 130021, P. R. China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2015-01-16 修回日期:2015-04-09 出版日期:2015-08-01 发布日期:2015-04-27
通讯作者: WANG Yu, LI Jiyang E-mail:wyu@jlu.edu.cn;lijiyang@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China (No.21271081).

Hydrothermal Synthesis of a New Zinc Phosphite (C₅H₇N₂)₂·[Zn₃(HPO₃)₄] with Intersecting 8- and 12-Ring Channels

DONG Zhaojun^1,2, YAN Yan², ZHANG Wenqing¹, WANG Yu¹, LI Jiyang²

1. Key Lab of Groundwater Resources and Environment, Ministry of Education, College of Environment and Resources, Jilin University, Changchun 130021, P. R. China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2015-01-16 Revised:2015-04-09 Online:2015-08-01 Published:2015-04-27
Contact: WANG Yu, LI Jiyang E-mail:wyu@jlu.edu.cn;lijiyang@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China (No.21271081).

摘要/Abstract

摘要：

Using 4-aminopyridine as the structure-directing agent(SDA), a new open-framework zinc phosphite, (C₅H₇N₂)₂·[Zn₃(HPO₃)₄](ZnHPO-CJ70), was synthesized under hydrothermal condition. Single-crystal X-ray diffraction analysis reveals that ZnHPO-CJ70 is constructed by the strictly alternating ZnO₄ tetrahedra and HPO₃ pseudo-pyramids, with their vertexes linked to generate a three-dimensional(3D) open framework with intersecting 8- and 12-ring channels. Further characterizations of ZnHPO-CJ70 were performed by means of X-ray powder diffraction(XRD), elemental analysis(ICP, CHN), infrared spectroscopy(IR) and thermogravimetric(TG) analyses. The results of luminescent test shows that ZnHPO-CJ70 exhibits strong fluorescence emissions in the solid state at room temperature.

关键词: Hydrothermal synthesis, Zinc phosphite, Open framework, Photoluminescence

Abstract:

Key words: Hydrothermal synthesis, Zinc phosphite, Open framework, Photoluminescence

DONG Zhaojun, YAN Yan, ZHANG Wenqing, WANG Yu, LI Jiyang. Hydrothermal Synthesis of a New Zinc Phosphite (C₅H₇N₂)₂·[Zn₃(HPO₃)₄] with Intersecting 8- and 12-Ring Channels[J]. 高等学校化学研究, 2015, 31(4): 498-502.

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Hydrothermal Synthesis of a New Zinc Phosphite (C₅H₇N₂)₂·[Zn₃(HPO₃)₄] with Intersecting 8- and 12-Ring Channels

Hydrothermal Synthesis of a New Zinc Phosphite (C₅H₇N₂)₂·[Zn₃(HPO₃)₄] with Intersecting 8- and 12-Ring Channels

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