Controllable Synthesis of JIS-10:Eu3+ Red Phosphor and Performance Optimization of Fluorescent Probe for Antibiotic Detection

doi:10.1007/s40242-025-5161-2

高等学校化学研究 ›› 2025, Vol. 41 ›› Issue (5): 1186-1192.doi: 10.1007/s40242-025-5161-2

Controllable Synthesis of JIS-10:Eu³⁺ Red Phosphor and Performance Optimization of Fluorescent Probe for Antibiotic Detection

ZHANG Xinyuan¹, CAI Xiaoyu¹, GUO Wenhang², SU Tan¹, SU Zhongmin^1,2,3

1. Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, College of Chemistry, Jilin University, Changchun 130021, P. R. China;
2. School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China;
3. State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2025-07-31 接受日期:2025-09-11 出版日期:2025-10-01 发布日期:2025-09-26
通讯作者: SU Tan, E-mail: sutan_jlu@jlu.edu.cn E-mail:sutan_jlu@jlu.edu.cn
基金资助:
This work was supported by the Science and Technology Research Project of the Jilin Provincial Education Department, China (No. JJKH20231132KJ), the National Natural Science Foundation of China (No. 22271023), and the Major Research Plan of the National Natural Science Foundation of China (No. 92461310).

Controllable Synthesis of JIS-10:Eu³⁺ Red Phosphor and Performance Optimization of Fluorescent Probe for Antibiotic Detection

ZHANG Xinyuan¹, CAI Xiaoyu¹, GUO Wenhang², SU Tan¹, SU Zhongmin^1,2,3

1. Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, College of Chemistry, Jilin University, Changchun 130021, P. R. China;
2. School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China;
3. State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2025-07-31 Accepted:2025-09-11 Online:2025-10-01 Published:2025-09-26
Contact: SU Tan, E-mail: sutan_jlu@jlu.edu.cn E-mail:sutan_jlu@jlu.edu.cn
Supported by:
This work was supported by the Science and Technology Research Project of the Jilin Provincial Education Department, China (No. JJKH20231132KJ), the National Natural Science Foundation of China (No. 22271023), and the Major Research Plan of the National Natural Science Foundation of China (No. 92461310).

摘要/Abstract

摘要： A series of Eu³⁺ doped manganese phosphite (JIS-10:Eu³⁺) red phosphors was prepared via the hydrothermal method. The regulation of Eu³⁺ doping concentration on the material structure, luminescence properties, and antibiotic fluorescence sensing characteristics was systematically investigated. Experiments showed that when the Eu³⁺ doping concentration (molar fraction) was 0.01, the material exhibited the strongest red emission at 617 nm. Under near-ultraviolet excitation at 394 nm, the luminescence intensity of JIS-10:0.01Eu³⁺ showed a linear relationship with the Eu³⁺ concentration. When this material was used as a fluorescent probe for tetracycline detection, its fluorescence intensity exhibited a good linear response to tetracycline concentration in the range of 0.1—200 μmol/L, and it showed significant selectivity towards structural analogs, such as sulfadiazine and norfloxacin.

关键词: Rare-earth, Photoluminescence, Red phosphor, Antibiotic detection

Abstract: A series of Eu³⁺ doped manganese phosphite (JIS-10:Eu³⁺) red phosphors was prepared via the hydrothermal method. The regulation of Eu³⁺ doping concentration on the material structure, luminescence properties, and antibiotic fluorescence sensing characteristics was systematically investigated. Experiments showed that when the Eu³⁺ doping concentration (molar fraction) was 0.01, the material exhibited the strongest red emission at 617 nm. Under near-ultraviolet excitation at 394 nm, the luminescence intensity of JIS-10:0.01Eu³⁺ showed a linear relationship with the Eu³⁺ concentration. When this material was used as a fluorescent probe for tetracycline detection, its fluorescence intensity exhibited a good linear response to tetracycline concentration in the range of 0.1—200 μmol/L, and it showed significant selectivity towards structural analogs, such as sulfadiazine and norfloxacin.

Key words: Rare-earth, Photoluminescence, Red phosphor, Antibiotic detection

ZHANG Xinyuan, CAI Xiaoyu, GUO Wenhang, SU Tan, SU Zhongmin. Controllable Synthesis of JIS-10:Eu³⁺ Red Phosphor and Performance Optimization of Fluorescent Probe for Antibiotic Detection[J]. 高等学校化学研究, 2025, 41(5): 1186-1192.

参考文献

[1] Chio H., Guest E. E., Hobman J. L., Dottorini T., Hirst J. D., Stekel D. J., J. Molecular Graph. Model., 2023, 123, 108508.
[2] Dong S., Ding Y., Feng H., Xu, J., Han, J., Jiang, W., Wang, A., Water Res., 2023, 235, 119876.
[3] Kumar R., Lakshmi G. B. V. S., Dhiman T. K., Singh K., Solanki P. R., J. Electroanal. Chem., 2021, 892, 115266.
[4] Alm R. A., Lahiri S. D., Antibiotics, 2020, 9, 418.
[5] Mutharani B., Chen T. W., Chen S. M., Liu X., Sens. Actua. B: Chem., 2020, 316, 128103.
[6] Li C. P., Long W. W., Lei Z., Guo L., Xie M. J., Lü J., Zhu X. D., Chem. Commun., 2020, 56, 12403.
[7] Wang K., Li L., Yang L., Guo J., Wang Z., Tang H., Ma Y., Polyhedron, 2022, 226, 116092.
[8] Wang G. D., Li Y. Z., Shi W. J., Zhang B., Hou L., Wang Y. Y., Sens. Actua. B: Chem., 2021, 331, 129377.
[9] Zhong S. F., Yang B., Lei H. J., Xiong Q., Zhang Q. Q., Liu F., Ying G. G., Sci. Total Environ., 2022, 830, 154647.
[10] Li X., Liu F., Xi S., Xie H., Li J., Liu G., J. Environ. Chem. Engineering, 2023, 11, 109699.
[11] Lakshmi G. B. V. S., Kondal S., Dhiman, T. K., Gupta P. K., Solanki P., ECS Transactions, 2022, 107, 18113.
[12] Lakshmi G. B. V. S., Poddar M., Dhiman T. K., Singh A. K., Solanki P. R., Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 653, 129819.
[13] Hashmi S. Z. H., Dhiman T. K., Chaudhary N., Singh A. K., Kumar R., Sharma J. G., Solanki P. R., Front. Nanotech., 2021, 3, 616186.
[14] Sajwan R. K., Pandey S., Kumar R., Dhiman T. K., Eremin S. A., Solanki P. R., Environ. Sci.: Nano, 2021, 8, 2693.
[15] Li K., Li D., Jia M., Guo D., Dai M., Zhao J., Fu Z., Nano Lett., 2025, 25, 776.
[16] Milićević D., Hlaváč J., Chemosensors, 2021, 9, 359.
[17] Verma A. K., Dhiman T. K., Lakshmi G. B. V. S., Solanki P., BioRxiv, 2022,11, 90.
[18] Kim D., Yoo S., Chemosensors, 2021, 9, 318.
[19] Zhang W., Zhang X., Sun J., Lv Y., Li X., Hou J., Su Z., Food Chem., 2025, 492, 8.
[20] Song J., Liu X., Zhang X., Fan J., Zhang R., Feng X., Talanta, 2023, 265, 124874.
[21] Ma J. X., Ma T., Qian R., Zhou L., Guo Q., Yang J. H., Yang Q., Inorg. Chem., 2021, 60, 7937.
[22] Li Y., Wang M., Yang G., Wang Y. Y., Inorg. Chem., 2023, 62, 4735.
[23] Dang J., Li M., Fang W., Wu Y., Xin S., Cao Y., Zhao H., Talanta, 2024, 267, 125164.
[24] Jiang Y., Fang X., Zhang Z., Guo X., Huo J., Wang Q., Ding B., Chinese Chem. Lett., 2023, 34, 108426.
[25] Liu W., Huang Y., Ji C., Grimes C. A., Liang Z., Hu H., Zhou Y. G., ACS Sensors, 2024, 9, 759.
[26] Deng T., He H., Chen H., Peng X., Li H., Yan X., Luo L., Talanta, 2024, 276,126200.
[27] Wang X., Li Q., Zong B., Fang X., Liu M., Li Z., Ostrikov K. K., Sens. Actua. B: Chem., 2022, 373, 132701.
[28] Sha H., Yan B., Talanta, 2023, 257, 124326.
[29] Su T., Xing H., Li Y., Wu J., Song X., Nakano T., Yu J., Inorg. Chem. Front., 2016, 3, 924.
[30] Xing H., Yang W., Su T., Li Y., Xu J., Nakano T., Xu R., Angew. Chem. Int. Ed., 2010, 49, 2328.
[31] Xing H., Li Y., Su T., Xu J., Yang W., Zhu E., Xu R., Dalton Transactions, 2010, 39, 1713.
[32] Su T., Xing H. Z., Xu J., Yu J. H., Xu R. R., Inorg. Chem., 2011, 50, 1073.
[33] Wu L., Sun S., Bai Y., Xia Z., Wu L., Chen H., Xu J., Adv. Optical Mater., 2021, 9, 2100870.
[34] Cao R., Chen C., Cheng F., Chen T., Lan B., Li L., Wang J., J. Luminescence, 2023, 257, 119731.
[35] Niu Y., Wu F., Teng Y., Huang Y., Yang Z., Mu Z., J. Luminescence, 2024, 275, 120748.
[36] Tang Z., Du F., Zhao L., Liu H., Leng Z., Xie H., Wang Y., Laser & Photonics Rev., 2023, 17, 2200911.
[37] Qiao J., Zhang S., Zhou X., Chen W., Gautier R., Xia Z., Adv. Mater., 2022, 34, 2201887.
[38] Nashivochnikov A. A., Kostyukov A. I., Rakhmanova M. I., Kibis L. S., Cherepanova S. V., Suprun E. A., J. Rare Earths, 2025, 43, 21.
[39] Wang S., Xu Y., Chen T., Jiang W., Liu J., Zhang X., Wang L., Chem. Engineering J., 2021, 404, 125912.
[40] Cao R., Wang J., Zhong B., Chen T., Lan B., Cheng F., Wang J., J. Phys. Chem. Solids, 2024, 188, 111925.
[41] Guo W., Zeng L., Zhang X., Cai X., Su T., Su Z., Chem. Res. Chinese Universities, 2025, 41, 557.
[42] Teng W., Dong H., Hu C., Yang X., Wang J., Liang X., Zhong D., J. Luminescence, 2024, 269, 120524.
[43] Sao S., Sharma R., Brahme N., Bisen D. P., Thakkar K., Richhariya T., Dubey K. K., J. Electron. Mater., 2025, 54, 2952.
[44] Yao W., Lu G., Zhao H., Huang D., Bai B., Huang N., Xie A., Optical Mater., 2024, 157, 116212.
[45] Lazoryak B. I., Dikhtyar Y. Y., Spassky D. A., Fedyunin F. D., Baryshnikova O. V., Pavlova E. T., Deyneko D. V., Mater. Res. Bulletin, 2024, 176, 112799.
[46] Tan H., Liu B., Chen Y., J. Phys. Chem. C, 2012, 116, 2292.
[47] Deol K. K., Muller G., ChemPlusChem, 2019, 84, 1796.
[48] Motorina A., Tananaiko O., Kozytska I., Raks V., Badia R., Díaz-García M. E., Zaitsev V. N., Sens. Actua. B: Chem., 2014, 200, 198.
[49] Yu M., Yao X., Wang X., Li Y., Li G., Polymers, 2019, 11, 99.
[50] Huang C., Luo Y., Li J., Liu C., Zhou T., Deng J., Anal. Chem., 2021, 93, 9183.
[51] Zhu J., Wu Y., Xue C., Zhang M., Zhang Y., Zhang X., Deng J., Chem. Engineering J., 2024, 500, 156839.
[52] Attia M. S., Youssef A. O., Essawy A. A., Abdel-Mottaleb M. S. A., J. Luminescence, 2012, 132, 2741.
[53] Hu X. L., Guo Y., Zhang J. N., Wang X. H., Fang G. Z., Wang S., Chem. Eng. J., 2022, 433, 14.
[54] Wang Y., Liang Z., Jiang K., Lin Y., He D., Liu J., Yu R., Ceramics International, 2023, 49, 579.
[55] Ouyang X., Liu R., Hu X., Li J., Tang R., Jin X., Yu R., J. Alloys Comp., 2023, 939, 168715.
[56] Kong J., Su H., Li C., Cheng S., Wang Y., Ran Y., Yu R., Ceramics International, 2023, 49, 39329.
[57] Xie Y., Geng X., Guo J., Shi W., Lv Q., Kong J., Yu R., Mater. Research Bulletin, 2022, 146, 111574.

Controllable Synthesis of JIS-10:Eu³⁺ Red Phosphor and Performance Optimization of Fluorescent Probe for Antibiotic Detection

Controllable Synthesis of JIS-10:Eu³⁺ Red Phosphor and Performance Optimization of Fluorescent Probe for Antibiotic Detection

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	GUO Wenhang, ZENG Liang, ZHANG Xinyuan, CAI Xiaoyu, SU Tan, SU Zhongmin. Rice Husk-derived Biomass Silicon for Single-phase White-light Inorganic Phosphor and WLEDs[J]. 高等学校化学研究, 2025, 41(3): 557-563.
[2]	JIAO Ziyue, WANG Xinli, GAO Jie, HUANG Xiao, WANG Yi. Waterproof Perovskite Quantum Dots for In-vivo Photoluminescence Bioimaging[J]. 高等学校化学研究, 2024, 40(5): 901-906.
[3]	ZHANG Jingmei, MENG Zhihao, ZHEN Yonggang, HE Ping, YU Panpan, HU Wenping. Halogenated Thienoacene Derivatives with Improved Emission Properties[J]. 高等学校化学研究, 2024, 40(4): 699-703.
[4]	XU Xinran, LIU An-an, PANG Daiwen. Rational Design of Capping Ligands of Quantum Dots for Biosensing[J]. 高等学校化学研究, 2024, 40(2): 162-172.
[5]	YANG Yiming, QIU Lili, SHI Xueliang. Chalcogen Effect of Atom Substitution on the Properties of Tris(2,4,6-trichlorophenyl)methyl(TTM) Radical[J]. 高等学校化学研究, 2023, 39(2): 197-201.
[6]	LU Feng, ZHAO Ting, SUN Xiaojun, WANG Zuqiang, FAN Quli, HUANG Wei. Rare-earth Doped Nanoparticles with Narrow NIR-II Emission for Optical Imaging with Reduced Autofluorescence[J]. 高等学校化学研究, 2021, 37(4): 943-950.
[7]	WANG Yan, XI Peng, SHU Dengkun, MENG Shuang, LIU Kai, WANG Xiaoqing, CHENG Bowen. Preparation and Properties of Electrospun Sheath-core Modified-PMMA Nanofibers with Photoluminescence and Photochromic Functions[J]. 高等学校化学研究, 2021, 37(3): 549-557.
[8]	ZHANG Tianning, ZHANG Kenan, CHEN Xiren, WANG Shuxia, ZHANG Rongjun, SHAO Jun, CHEN Xin, DAI Ning. Temperature-dependent Photoluminescence of Silicon Nanocrystals Embedded in SiO₂ Matrix[J]. 高等学校化学研究, 2018, 34(4): 513-516.
[9]	CHEN Yanli, DONG Xinglong, ZHANG Zhenyu, FENG Lai. Multicolor Photoluminescence in ITQ-16 Zeolite Film[J]. 高等学校化学研究, 2016, 32(5): 713-718.
[10]	WU Xiaomei, LIU Guocheng, WANG Xiuli, SHAO Jiyan, LIN Hongyan, WANG Xiang. Three Ni(Ⅱ) Coordination Polymers with Various Architectures Based on Asymmetric Bis-pyridyl-amide and Polycarboxylates: Syntheses, Structures and Properties[J]. 高等学校化学研究, 2016, 32(5): 719-724.
[11]	DONG Weili, ZHANG Xiyan, SHI Hui, WANG Nengli, ZHANG Wenmin, LI Liang, XUE Qingxue. Preparation and Luminescence Properties of Color-tunable Single-phased LaPO₄: Eu³⁺/Tb³⁺ Phosphors[J]. 高等学校化学研究, 2016, 32(2): 248-252.
[12]	HUANG Yantao, LAN Yuwei, YI Qilei, HUANG Hualin, WANG Yilin, LU Jianping. Microwave-assisted Synthesis of CdTe Quantum Dots Using 3-Mercaptopropionic Acid as Both a Reducing Agent and a Stabilizer[J]. 高等学校化学研究, 2016, 32(1): 16-19.
[13]	DONG Zhaojun, YAN Yan, ZHANG Wenqing, WANG Yu, LI Jiyang. Hydrothermal Synthesis of a New Zinc Phosphite (C₅H₇N₂)₂·[Zn₃(HPO₃)₄] with Intersecting 8- and 12-Ring Channels[J]. 高等学校化学研究, 2015, 31(4): 498-502.
[14]	ZHANG Guochun, QIAO Chengfang, LIANG Jiehui, WEI Qing, XIA Zhengqiang, CHEN Sanping. Hydrothermal Synthesis, Structure and Property of Transition Metal(Mn, Zn, Cd or Pb) Coordination Frameworks Using Quinoline-8-oxy-acetate Acid and Dicarboxylic Acid as Ligands[J]. 高等学校化学研究, 2015, 31(4): 489-497.
[15]	GU Yipeng, SHEN Hongzhi, LI Liang, LIU Wenqiang, WANG Wenquan, XU Dapeng. Electrospinning Synthesis and Photoluminescence Properties of SnO₂:xEu³⁺ Nanofibers[J]. 高等学校化学研究, 2014, 30(6): 879-884.