Configurational Selectivity Study of Two-dimensional Covalent Organic Frameworks Isomers Containing D2h and C2 Building Blocks

doi:10.1007/s40242-022-2001-5

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (2): 639-642.doi: 10.1007/s40242-022-2001-5

• Articles • 上一篇

Configurational Selectivity Study of Two-dimensional Covalent Organic Frameworks Isomers Containing D_2h and C₂ Building Blocks

ZHENG Xuhan, ZHANG Lin, XIE Chenxiao, WANG Hui, LIU Hui, PAN Qingyan, ZHAO Yingjie

College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

收稿日期:2022-01-01 修回日期:2022-02-10 出版日期:2022-04-01 发布日期:2022-05-18
通讯作者: ZHAO Yingjie, PAN Qingyan E-mail:yz@qust.edu.cn;Qingyanpan@qust.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos.31202117, 31202152) and the Natural Science Foundation of Shandong Province, China(No.ZR2020ZD38).

Configurational Selectivity Study of Two-dimensional Covalent Organic Frameworks Isomers Containing D_2h and C₂ Building Blocks

ZHENG Xuhan, ZHANG Lin, XIE Chenxiao, WANG Hui, LIU Hui, PAN Qingyan, ZHAO Yingjie

College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

Received:2022-01-01 Revised:2022-02-10 Online:2022-04-01 Published:2022-05-18
Contact: ZHAO Yingjie, PAN Qingyan E-mail:yz@qust.edu.cn;Qingyanpan@qust.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.31202117, 31202152) and the Natural Science Foundation of Shandong Province, China(No.ZR2020ZD38).

摘要/Abstract

摘要： The isomerization of covalent organic frameworks(COFs) materials is still a mysterious and attractive topic. Diversified monomer structures are still urgently needed to explore the in-depth mechanism of isomerization in these special COFs. This work provides a new D₂_h monomer for the construction of [D₂_h+C₂] 2D COFs isomers. A new D₂_h monomer adopted here was proven to tend to form a single pore framework structure.

关键词: Covalent organic framework, Isomerization, Kagome, Dynamic covalent bond

Abstract: The isomerization of covalent organic frameworks(COFs) materials is still a mysterious and attractive topic. Diversified monomer structures are still urgently needed to explore the in-depth mechanism of isomerization in these special COFs. This work provides a new D₂_h monomer for the construction of [D₂_h+C₂] 2D COFs isomers. A new D₂_h monomer adopted here was proven to tend to form a single pore framework structure.

Key words: Covalent organic framework, Isomerization, Kagome, Dynamic covalent bond

ZHENG Xuhan, ZHANG Lin, XIE Chenxiao, WANG Hui, LIU Hui, PAN Qingyan, ZHAO Yingjie. Configurational Selectivity Study of Two-dimensional Covalent Organic Frameworks Isomers Containing D_2h and C₂ Building Blocks[J]. 高等学校化学研究, 2022, 38(2): 639-642.

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Configurational Selectivity Study of Two-dimensional Covalent Organic Frameworks Isomers Containing D_2h and C₂ Building Blocks

Configurational Selectivity Study of Two-dimensional Covalent Organic Frameworks Isomers Containing D_2h and C₂ Building Blocks

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