Co3O4 Decorated Ti/TiO2 Nanotubes for Photogenerated Cathodic Protection of 304 Stainless Steel

doi:10.1007/s40242-020-0226-8

高等学校化学研究 ›› 2021, Vol. 37 ›› Issue (3): 704-710.doi: 10.1007/s40242-020-0226-8

Co₃O₄ Decorated Ti/TiO₂ Nanotubes for Photogenerated Cathodic Protection of 304 Stainless Steel

LI Wenfeng, FANG Xue, LYU Jiahui, WANG Guowen, MA Chun, MA Hongchao

School of Light Industry & Chemical Engineering, Dalian Polytechnic University, Dalian 116034, P. R. China

收稿日期:2020-07-03 修回日期:2020-08-24 出版日期:2021-06-01 发布日期:2021-05-31
通讯作者: MA Hongchao E-mail:m-h-c@sohu.com
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos.21875026, 21878031), the Revitalization Talents Program of China (No.XLYC1802124), the Liaoning BaiQianWan Talents Program, China, the Scientific Research Fund of the Educational Department of Liaoning Province, China(No.J2019013) and the Joint Research Fund of Liaoning-Shenyang National Laboratory for Materials Science, China(No. 2019JH3/30100034).

Co₃O₄ Decorated Ti/TiO₂ Nanotubes for Photogenerated Cathodic Protection of 304 Stainless Steel

LI Wenfeng, FANG Xue, LYU Jiahui, WANG Guowen, MA Chun, MA Hongchao

School of Light Industry & Chemical Engineering, Dalian Polytechnic University, Dalian 116034, P. R. China

Received:2020-07-03 Revised:2020-08-24 Online:2021-06-01 Published:2021-05-31
Contact: MA Hongchao E-mail:m-h-c@sohu.com
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.21875026, 21878031), the Revitalization Talents Program of China (No.XLYC1802124), the Liaoning BaiQianWan Talents Program, China, the Scientific Research Fund of the Educational Department of Liaoning Province, China(No.J2019013) and the Joint Research Fund of Liaoning-Shenyang National Laboratory for Materials Science, China(No. 2019JH3/30100034).

摘要/Abstract

摘要： The Co₃O₄ decorated TiO₂ nanotube arrays(NTAs) coatings are fabricated by the combination of anodization and impregna-ting methods. It is found that the introduction of Co₃O₄ can reduce the diffraction intensity of (101) plane of the TiO₂ and accelerate the separation of photogenerated electron/hole pairs. In addition, the open circuit potential(OCP) and the corrosion potential of 304 stainless steel(304SS) with or without Co₃O₄ decorated TiO₂ NTAs were measured under visible light, which indicated the 304SS coupled with Co₃O₄ decorated TiO₂ NTAs had better anticorrosion performance than that of the 304SS or the 304SS coupled with pure TiO₂ NTAs. The enhancement of the cathodic protection performance of the Co₃O₄ decorated TiO₂ NTAs can be ascribed to the matched energy levels and strong interaction between Co₃O₄ and TiO₂ NTAs, and the improvement of light absorption.

关键词: Photogenerated cathodic protection, Corrosion, Stainless steel, Ti/TiO₂Co₃O₄

Abstract: The Co₃O₄ decorated TiO₂ nanotube arrays(NTAs) coatings are fabricated by the combination of anodization and impregna-ting methods. It is found that the introduction of Co₃O₄ can reduce the diffraction intensity of (101) plane of the TiO₂ and accelerate the separation of photogenerated electron/hole pairs. In addition, the open circuit potential(OCP) and the corrosion potential of 304 stainless steel(304SS) with or without Co₃O₄ decorated TiO₂ NTAs were measured under visible light, which indicated the 304SS coupled with Co₃O₄ decorated TiO₂ NTAs had better anticorrosion performance than that of the 304SS or the 304SS coupled with pure TiO₂ NTAs. The enhancement of the cathodic protection performance of the Co₃O₄ decorated TiO₂ NTAs can be ascribed to the matched energy levels and strong interaction between Co₃O₄ and TiO₂ NTAs, and the improvement of light absorption.

Key words: Photogenerated cathodic protection, Corrosion, Stainless steel, Ti/TiO₂Co₃O₄

LI Wenfeng, FANG Xue, LYU Jiahui, WANG Guowen, MA Chun, MA Hongchao. Co₃O₄ Decorated Ti/TiO₂ Nanotubes for Photogenerated Cathodic Protection of 304 Stainless Steel[J]. 高等学校化学研究, 2021, 37(3): 704-710.

LI Wenfeng, FANG Xue, LYU Jiahui, WANG Guowen, MA Chun, MA Hongchao. Co₃O₄ Decorated Ti/TiO₂ Nanotubes for Photogenerated Cathodic Protection of 304 Stainless Steel[J]. Chemical Research in Chinese Universities, 2021, 37(3): 704-710.

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Co₃O₄ Decorated Ti/TiO₂ Nanotubes for Photogenerated Cathodic Protection of 304 Stainless Steel

Co₃O₄ Decorated Ti/TiO₂ Nanotubes for Photogenerated Cathodic Protection of 304 Stainless Steel

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