Lignin-Phenylhydrazone as a Corrosion Inhibitor of API X52 Carbon Steel in 3.5% NaCl and 0.1 mol/L HCl Medium

doi:10.1007/s40242-021-0334-0

高等学校化学研究 ›› 2021, Vol. 37 ›› Issue (3): 718-728.doi: 10.1007/s40242-021-0334-0

Lignin-Phenylhydrazone as a Corrosion Inhibitor of API X52 Carbon Steel in 3.5% NaCl and 0.1 mol/L HCl Medium

Nabila AISSIOU^1,2, Moussa BOUNOUGHAZ^1,2, Amel DJEDDI²

1. Laboratoire de Traitement et Mise en Forme des Polymères, Université M'Hamed Bougara, Boumerdes, 35000, Algeria;
2. Université M'hamed Bougara, Faculté des Sciences, Boumerdes, 35000, Algeria

收稿日期:2020-10-21 修回日期:2021-01-15 出版日期:2021-06-01 发布日期:2021-05-31
通讯作者: Nabila AISSIOU E-mail:nabila.aissiou@univ-boumerdes.dz
基金资助:
We hereby acknowledge the efforts of Prof. Aliouche, the director of our research laboratory, Dr. Hadjadj whose support allowed this research to be completed. We extend our sincere thanks to our colleagues and all those who contributed directly or indirectly to this manuscript.

Lignin-Phenylhydrazone as a Corrosion Inhibitor of API X52 Carbon Steel in 3.5% NaCl and 0.1 mol/L HCl Medium

Nabila AISSIOU^1,2, Moussa BOUNOUGHAZ^1,2, Amel DJEDDI²

1. Laboratoire de Traitement et Mise en Forme des Polymères, Université M'Hamed Bougara, Boumerdes, 35000, Algeria;
2. Université M'hamed Bougara, Faculté des Sciences, Boumerdes, 35000, Algeria

Received:2020-10-21 Revised:2021-01-15 Online:2021-06-01 Published:2021-05-31
Contact: Nabila AISSIOU E-mail:nabila.aissiou@univ-boumerdes.dz
Supported by:
We hereby acknowledge the efforts of Prof. Aliouche, the director of our research laboratory, Dr. Hadjadj whose support allowed this research to be completed. We extend our sincere thanks to our colleagues and all those who contributed directly or indirectly to this manuscript.

摘要/Abstract

摘要： The best alternative to fight against corrosion is the use of an inhibitor, the purpose of this work is the formulation of a new biomass-based molecule against corrosion of carbon steel. Lignin was extracted using the Kraft process and phenylhydrazine molecules have been scratched. The influence of the lignin-phenylhydrazone(LP) on the corrosion of carbon steel in salt and the acidic medium was studied by the polarization resistance, the potentiodynamic polarization, and the electrochemical impedance spectroscopy. The results of these tests reveal that the behavior of the inhi-bitor is a mixed type. The adsorption mechanism of the inhibitor follows the Langmuir isothermal model. Gibbs energy shows that the process of inhibition of carbon steel is spontaneous. The SEM confirms that the inhibitor reduces the corrosion of the steel and stops the corrosion pitting phenomenon. The modified lignin shown as a good corrosion inhibitor in acid medium is highly saline with an efficiency> 96%.

关键词: Kraft Lignin, Phenylhydrazone, Corrosion inhibitor, Corrosion pitting, Electrochemical Impedance

Abstract: The best alternative to fight against corrosion is the use of an inhibitor, the purpose of this work is the formulation of a new biomass-based molecule against corrosion of carbon steel. Lignin was extracted using the Kraft process and phenylhydrazine molecules have been scratched. The influence of the lignin-phenylhydrazone(LP) on the corrosion of carbon steel in salt and the acidic medium was studied by the polarization resistance, the potentiodynamic polarization, and the electrochemical impedance spectroscopy. The results of these tests reveal that the behavior of the inhi-bitor is a mixed type. The adsorption mechanism of the inhibitor follows the Langmuir isothermal model. Gibbs energy shows that the process of inhibition of carbon steel is spontaneous. The SEM confirms that the inhibitor reduces the corrosion of the steel and stops the corrosion pitting phenomenon. The modified lignin shown as a good corrosion inhibitor in acid medium is highly saline with an efficiency> 96%.

Key words: Kraft Lignin, Phenylhydrazone, Corrosion inhibitor, Corrosion pitting, Electrochemical Impedance

Nabila AISSIOU, Moussa BOUNOUGHAZ, Amel DJEDDI. Lignin-Phenylhydrazone as a Corrosion Inhibitor of API X52 Carbon Steel in 3.5% NaCl and 0.1 mol/L HCl Medium[J]. 高等学校化学研究, 2021, 37(3): 718-728.

Nabila AISSIOU, Moussa BOUNOUGHAZ, Amel DJEDDI. Lignin-Phenylhydrazone as a Corrosion Inhibitor of API X52 Carbon Steel in 3.5% NaCl and 0.1 mol/L HCl Medium[J]. Chemical Research in Chinese Universities, 2021, 37(3): 718-728.

参考文献 61

[1]	Pluvinage G., Sedmak A., Science for Peace and Security Series C:Environmental Security, Springer Netherlands, Dordrecht, 2009
[2]	Cen H., Chen Z., Guo X., J. Taiwan. Inst. Chem. Eng., 2019, 99, 224
[3]	Abdallah M., Al-Tass H. M., Jahdaly B. A., Fouda A. S., J. Mol. Liq., 2016, 216, 590
[4]	Avdee Y. G., Kuznetsov Y. I., Buryak A. K., Corros. Sci., 2013, 69, 50
[5]	Finšgar M., Jackson J., Corros. Sci., 2014, 86,17
[6]	Macedo R. A., Marques N. N., Tonholo J., Balaban R. C., Carbohydr. Polym., 2019, 205, 371
[7]	Rodríguez-Gómez F. J., Valdelamar M. P., Vazquez A. E., Perez P. V., Mata R., Miralrio A., Castro M., J. Mol. Struct., 2019, 1183, 168
[8]	Erami R. S., Amirnasr M., Meghdadi S., Talebian M., Farrokhpour H., Raeissi K., Corros. Sci., 2019, 151, 190
[9]	Kuznetsov Y. I., Organic Inhibitors of Corrosion of Metals, Springer-Verlag, New York, 2013
[10]	Ebenso E. E., Kabanda M. M., Murulana L. C., Singh A. K., Shukla S. K., Ind. Eng. Chem. Res, 2012, 51, 12940
[11]	Kumari P. P., Shetty P., Rao S. A., Arab. J. Chem., 2017, 10, 653
[12]	Guo L., Zhu S., Zhang S., He Q., Li, W., Corros. Sci., 2014, 87, 366
[13]	Ghailane T., Balkhmima R. A., Ghailane R., Souizi A., Touir R., Touhami M. E., Marakchi K., Komiha N., Corros. Sci., 2013, 76, 317
[14]	Anusuya N., Saranya J., Sounthari P., Zarrouk A., Chitra S., J. Mol. Liq., 2017, 225, 406
[15]	Oguzie E. E., Corros. Sci., 2008, 50, 2993
[16]	Lahhit N., Bouyanzer A., Desjobert J. M., Hammouti B., Salghi R., Costa J., Jama C., Bentiss F., Majidi L., Port. Electrochimica Acta, 2011, 29, 127
[17]	Ameh P. O., Int. J. Met., 2015, 2015, 1
[18]	Abu-Dalo M. A., Al-Rawashdeh N. A. F., Ababneh A., Desalination, 2013, 313, 105
[19]	Guo Y., Gao W., Fatehi P., Ind. Crops Prod., 2018, 124, 273
[20]	Rastogi S., Dwivedi U. N., Plant Sci., 2008, 174, 264
[21]	Kamm B., Gruber P. R., Kamm M., Biorefineries Industrial Processes and Products:Status Quo and Future Directions, WILEY-VCH Verlag GmbH & Co., KGaA, Weinheim, 2006
[22]	Xin J., Zhang P., Wolcott M. P., Zhang J., Hiscox W. C., Zhang V., J. Polym. Environ., 2017, 25, 599
[23]	Laurichesse S., Avérous L., Prog. Polym. Sci., 2014, 39, 1266
[24]	Sabirneeza A. A. F., Geethanjali R., Subhashini S., Chem. l Eng. Commun., 2015, 202, 232
[25]	Figueiredo P., Lintinen K., Hirvonen J. T., Kostiainen M. A., Santos H. A., Prog. Mat. Sci., 2018, 93, 233
[26]	Mansouri N. E. E., Yuan Q., Huang F., BioResources, 2011, 6, 2492
[27]	Du X., Li J., Lindström M.E., Ind. Crops Prod., 2014, 52, 729
[28]	Calvo-Flores F. G., Jiménez J. A. D., Garcia J. I., Martínez F. J., Lignin and Lignans as Renewable Raw Materials:Chemistry, Technology and Applications, John Wiley and Sons, Inc., Chichester, 2015
[29]	Biermann C. J., Handbook of Pulping and Papermaking, Elsevier Science, London, 1996
[30]	Rahimi A., Ulbrich A., Coon J. J., Stahl S. S., Nature, 2014, 515, 249
[31]	Liu P., Pan Y. M., Xu Y. L., Wang H. S., Org. Biomol. Chem., 2012, 10, 4696
[32]	Ravikumar C., Joe I. H., Jayakumar V. S., Chem. Phys. Lett., 2008, 460, 552
[33]	Farahmand R., Sohrabi B., Ghaffarinejad A., Meymian M. R. Z., Corros. Sci., 2018, 136, 393
[34]	Bahrami M. J., Hosseini S. M. A., Pilvar P., Corros. Sci., 2010, 52, 2793
[35]	Han T., Sophonrat N., Evangelopoulos P., Persson H., Yang W., Jönsson P., J. Anal. Appl. Pyrolysis, 2018, 133, 162
[36]	Hu K., Zhuang J., Ding J., Ma Z., Wang F., Zeng X., Corros. Sci., 2017, 125, 68
[37]	Luo X., Ci C., Li J., Lin K., Du S., Zhang H., Li X., Cheng Y. F., Zang J., Liu Y., Corros. Sci., 2019, 151, 132
[38]	Angst U., Büchler M., Mater. Corros., 2015, 10, 1017
[39]	Obot I. B., Umoren S. A., Ankah N.K., J. Mol. Liq., 2019, 277, 749
[40]	Moretti G., Guidi F., Fabris F., Corros. Sci., 2013, 76, 206
[41]	Fernandes C. M., Alvarez L. X., Santos N. E., Barrios A. C. M., Ponzio E. A., Corros. Sci., 2019, 149, 185
[42]	Roberge P. R., Handbook of Corrosion Engineering, McGraw-Hill, New York, 2000
[43]	Asefi D., Arami M., Mahmood N. M., Corros. Sci., 2010, 52, 794
[44]	Perez N., Electrochemistry and Corrosion Science, Kluwer Academic Publ, Boston, 2004
[45]	He X., Mao J., Ma Q., Tang Y., J. Mol. Liq., 2018, 269, 260
[46]	Aldana-González J., Espinoza-Vázquez A., Romero-Romo M., Uruchurtu-Chavarin J., PalomarPardavé M., Arab. J. Chem., 2019, 12, 3244
[47]	Orazem M. E., Tribollet B., Electrochemical Impedance Spectroscopy, Wiley, Hoboken, New Jersey, 2008
[48]	Lebrini M., Robert F., Lecante A., Roos C., Corros. Sci., 2011, 53, 687
[49]	Perini N., Prado A. R., Sad C. M. S., Castro E. V. R., Freitas M. B. J. G., Fuel, 2012, 91, 224228
[50]	Sacco A., Renew. Sustain. Energy Rev., 2017, 79, 814
[51]	Huang J., Li Z., Liaw B. Y., Zhang J., J. Power Sources, 2016, 309, 82
[52]	Lvovich V. F., Impedance Spectroscopy:Applications to Electrochemical and Dielectric Phenomena, Wiley, Hoboken, New Jersey, 2012
[53]	Kanoun O., Lecture Notes on Impedance Spectroscopy:Measurement, Modeling and Applications, Volume 1, CRC Press/Balkema, Raton, Fla, 2011
[54]	Bouammali H., Jama C., Bekkouch K., Aouniti A., Hammouti B., Bentiss F., J. Ind. Eng. Chem., 2015, 26, 270
[55]	Hemapriya V., Prabakaran M., Parameswari K., Chitra S., Kim S. H., Chung I. M., J. Ind. Eng. Chem., 2016, 40, 106
[56]	Mourya P., Banerjee S., Singh M. M., Corros. Sci., 2014, 85, 352
[57]	Qian B., Wang J., Zheng M., Hou B., Corros. Sci., 2013, 75, 184
[58]	Ai O., Kj U., Mc E., Pc O., Ec O., J. Phys. Chem. Biophys., 2018, 8, 1
[59]	Hamdy A., El-Gendy N., Egypt. J. Pet., 2013, 22, 17
[60]	Douadi T., Hamani H., Daoud D., Al-Noaimi M., Chafaa S., J. Taiwan Inst. Chem. Eng., 2017, 71, 388
[61]	Fekry A. M., Mohamed R. R., Electrochimica Acta, 2010, 55, 1933

Lignin-Phenylhydrazone as a Corrosion Inhibitor of API X52 Carbon Steel in 3.5% NaCl and 0.1 mol/L HCl Medium

Lignin-Phenylhydrazone as a Corrosion Inhibitor of API X52 Carbon Steel in 3.5% NaCl and 0.1 mol/L HCl Medium

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