Synthesis of CdS/m-TiO2 Mesoporous Spheres and Their Application in Photocatalytic Degradation of Rhodamine B Under Visible Light

doi:10.1007/s40242-017-6377-6

高等学校化学研究 ›› 2017, Vol. 33 ›› Issue (3): 436-441.doi: 10.1007/s40242-017-6377-6

Synthesis of CdS/m-TiO₂ Mesoporous Spheres and Their Application in Photocatalytic Degradation of Rhodamine B Under Visible Light

CUI Shu^1,2, LI Xuesong¹, LI Yanjuan¹, ZHAO Haixin¹, WANG Yuanyuan¹, LI Nan¹, LI Xiaotian¹, LI Guodong³

1. Key Laboratory of Automobile Materials, Ministry of Education, College of Material Science and Engineering, Jilin University, Changchun 130012, P. R. China;
2. School of Physics, Tonghua Normal University, Tonghua 134002, P. R. China;
3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2016-09-12 修回日期:2016-12-26 出版日期:2017-06-01 发布日期:2017-05-26
通讯作者: LI Nan,E-mail:lin@jlu.edu.cn;LI Xiaotian,E-mail:xiaotianli@jlu.edu.cn E-mail:lin@jlu.edu.cn;xiaotianli@jlu.edu.cn
基金资助:
Supported the National Natural Science Foundation of China(Nos.21076094 and 21673097).

Synthesis of CdS/m-TiO₂ Mesoporous Spheres and Their Application in Photocatalytic Degradation of Rhodamine B Under Visible Light

CUI Shu^1,2, LI Xuesong¹, LI Yanjuan¹, ZHAO Haixin¹, WANG Yuanyuan¹, LI Nan¹, LI Xiaotian¹, LI Guodong³

1. Key Laboratory of Automobile Materials, Ministry of Education, College of Material Science and Engineering, Jilin University, Changchun 130012, P. R. China;
2. School of Physics, Tonghua Normal University, Tonghua 134002, P. R. China;
3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2016-09-12 Revised:2016-12-26 Online:2017-06-01 Published:2017-05-26
Contact: LI Nan,E-mail:lin@jlu.edu.cn;LI Xiaotian,E-mail:xiaotianli@jlu.edu.cn E-mail:lin@jlu.edu.cn;xiaotianli@jlu.edu.cn
Supported by:
Supported the National Natural Science Foundation of China(Nos.21076094 and 21673097).

摘要/Abstract

摘要：

CdS/m-TiO₂ heteroarchitecture with CdS nanocrystals loaded on mesoporous TiO₂(m-TiO₂) spheres was successfully synthesized via sol-gel method followed by solvothermal treatment. The material with uniform diameter of ca. 750 nm possesses regular mesoporous structure and large specific surface area of 100.5 m²/g. When used to photodegradate Rhodamine B(RB) under visible light, the CdS/m-TiO₂ heteroarchitecture exhibits improved photocatalytic performance in comparison with pure m-TiO₂ or CdS. The excellent photocatalytic activity is closely related to the facilitated separation of electron-hole pairs derived from the CdS/m-TiO₂ heterojunction and mesoporous structure with high specific surface area and adequately exposed active sites.

关键词: Cadmium sulfide, Titanium dioxide, Heteroarchitecture, Mesoporous material, Photocatalysis, Visible light

Abstract:

Key words: Cadmium sulfide, Titanium dioxide, Heteroarchitecture, Mesoporous material, Photocatalysis, Visible light

CUI Shu, LI Xuesong, LI Yanjuan, ZHAO Haixin, WANG Yuanyuan, LI Nan, LI Xiaotian, LI Guodong. Synthesis of CdS/m-TiO₂ Mesoporous Spheres and Their Application in Photocatalytic Degradation of Rhodamine B Under Visible Light[J]. 高等学校化学研究, 2017, 33(3): 436-441.

参考文献

[1] Hoffmann M. R., Martin S. T., Choi W., Bahnemannt D. W., Chem. Rev., 1995, 95, 69
[2] Wang M. Y., Ioccozia J., Sun L., Lin C. J., Lin Z. Q., Energy Environ. Sci., 2014, 7, 2182
[3] Chen X. B., Mao S. S., Chem. Rev., 2007, 107, 2891
[4] Hernández-Alonso M. D., Fresno F., Suárez S., Coronado J. M., En-ergy Environ. Sci., 2009, 2, 1231
[5] Kudo A., Miseki Y., Chem. Soc. Rev., 2009, 38, 253
[6] Tachikawa T., Fujitsuka M., Majima T., J. Phys. Chem. C, 2007, 111, 5259
[7] Cui L. F., Huang F., Niu M. T., Zeng L. W., Xu J., Wang Y. S., J. Mol. Catal. A:Chem., 2010, 326, 1
[8] Guan H. Y., Wang X. H., Guo Y. H., Shao C. l., Zhang X. T., Liu Y. C., Louh R. F., Appl. Surf. Sci., 2013, 280, 720
[9] Wang X. H., Dahubaiyila, Li X. T., Chem.J.Chinese Universities, 2015, 36(5), 976
[10] Cao Y. Q., He T., Chen Y. M., Cao Y. A., J. Phys. Chem. C, 2010, 114, 3627
[11] Bhirud A. P., Sathaye S. D., Waichal R. P., Ambekar J. D., Park C. J., Kale B. B., Nanoscale, 2015, 7, 5023
[12] Wang J. Y., Liu Z. H., Zheng Q., He Z. K., Cai R. X., Nanotechnology, 2006, 17, 4561
[13] Xie Y., Ali G., Yoo S. H., Cho S. O., ACS Appl. Mater. Interfaces, 2010, 2, 2910
[14] Ismail A. A., Appl. Catal., B, 2012, 117/118, 67
[15] Li L., Cheng B., Wang Y., Yu J., J. Colloid Interface Sci., 2015, 449, 115
[16] Bi F., Ehsan M. F., Liu W., He T., Chin. J. Chem., 2015, 33, 112
[17] Hayden S. C., Allam N. K., El-Sayed M. A., J. Am. Chem. Soc., 2010, 132, 14406
[18] Bai S. L., Li H. Y., Guan Y. Y., Jiang S. T., Appl. Surf. Sci., 2011, 257, 6406
[19] Su C., Shao C., Liu Y., J. Colloid Interface Sci., 2011, 359, 220
[20] Serpone N., Borgarello E., Gratzel M., J. Chem. Soc., Chem. Com-mun., 1984, 342
[21] Jang J. S., Li W., Oh S. H., Lee J. S., Chem. Phys. Lett., 2006, 425, 278
[22] Zhu Y. X., Wang Y. F., Chen Z., Qin L. S., Yang L. B., Zhu L., Tang P., Gao T., Huang Y. X., Sha Z. L., Tang G., Appl. Catal., A, 2015, 498, 159
[23] Dong W. H., Pan F., Xu L. L., Zheng M. R., Sow C. H., Wu K., Xu G. Q., Chen W., Appl. Surf. Sci., 2015, 349, 279
[24] Xue C., Wang T., Yang G. D., Yang B. L., Ding S. J., J. Mater. Chem. A, 2014, 2, 7674
[25] Bessekhouad Y., Robert D., Weber J. V., J. Photochem. Photobiol., A, 2004, 163, 569
[26] Wu J. M., Zhang T. W., J. Photochem. Photobiol., A, 2004, 162, 171
[27] Lee M. S., Park S. S., Lee G. D., Ju C. S., Hong S. S., Catal. Today, 2005, 101, 283
[28] Lubomir S., Markus H., Horst W., Arnim H., J. Am. Chem. Soc., 1987, 109, 5649

Synthesis of CdS/m-TiO₂ Mesoporous Spheres and Their Application in Photocatalytic Degradation of Rhodamine B Under Visible Light

Synthesis of CdS/m-TiO₂ Mesoporous Spheres and Their Application in Photocatalytic Degradation of Rhodamine B Under Visible Light

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