A Selective and Sensitive Fluorescence Probe for Se(Ⅳ) Based on Fluorescence Quenching of Gatifloxacin

doi:10.1007/s40242-016-6015-8

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (5): 736-741.doi: 10.1007/s40242-016-6015-8

A Selective and Sensitive Fluorescence Probe for Se(Ⅳ) Based on Fluorescence Quenching of Gatifloxacin

LIU Qing¹, HUAN Yanfu¹, ZHENG Qingchuan², FEI Qiang¹, FEI Yanqun³, FAN Qian⁴, FENG Guodong¹, SHAN Hongyan¹

1. College of Chemistry, Jilin University, Changchun 130021, P. R. China;
2. Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun 130021, P. R. China;
3. Changchun WeiersaiBiotec Pharmaceutical Co., Ltd., Changchun 130616, P. R. China;
4. Changchun Vocational Institute of Technology, Changchun 130033, P. R. China

收稿日期:2016-01-15 修回日期:2016-05-30 出版日期:2016-10-01 发布日期:2016-07-11
通讯作者: SHAN Hongyan E-mail:shanhy@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21207047), the State Major Project for Science and Technology Development, China(No.2013YQ47078102-3), the Science-Technology Development Project of Jilin Province of China(Nos.20130206014GX, 20140623007TC, 20150204017YY), the Open Project of the State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, China(No.2014-07) and the Natural Science Foundation of Jilin Province, China(No.20160101314JC).

A Selective and Sensitive Fluorescence Probe for Se(Ⅳ) Based on Fluorescence Quenching of Gatifloxacin

LIU Qing¹, HUAN Yanfu¹, ZHENG Qingchuan², FEI Qiang¹, FEI Yanqun³, FAN Qian⁴, FENG Guodong¹, SHAN Hongyan¹

1. College of Chemistry, Jilin University, Changchun 130021, P. R. China;
2. Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun 130021, P. R. China;
3. Changchun WeiersaiBiotec Pharmaceutical Co., Ltd., Changchun 130616, P. R. China;
4. Changchun Vocational Institute of Technology, Changchun 130033, P. R. China

Received:2016-01-15 Revised:2016-05-30 Online:2016-10-01 Published:2016-07-11
Contact: SHAN Hongyan E-mail:shanhy@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21207047), the State Major Project for Science and Technology Development, China(No.2013YQ47078102-3), the Science-Technology Development Project of Jilin Province of China(Nos.20130206014GX, 20140623007TC, 20150204017YY), the Open Project of the State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, China(No.2014-07) and the Natural Science Foundation of Jilin Province, China(No.20160101314JC).

摘要/Abstract

摘要：

A novel high selective and sensitive fluorescence probe termed gatifloxacin was discovered based on fluorescence "on-off" phenomenon in the presence of Se(Ⅳ). In the Tris-HCl/acetonitrile(3:7, volume ratio, Tris-HCl 0.05 mol/L, pH=7.3) sys-tem, the fluorescence intensity of gatifloxacin was linearly decreased with the concentration increase of Se(Ⅳ) in a range of 1.0×10^-5-5.0×10^-5 mol/L with a correlation coefficient of 0.9979(R²=0.9958) and in a range of 5.0×10^-5-1.0×10^-4 mol/L with a correlation coefficient of 0.9973(R²=0.9946). The detection limit of Se(Ⅳ) was 1.70×10^-6 mol/L.

关键词: Gatifloxacin, Fluorescence probe, Quenching, Selenium

Abstract:

Key words: Gatifloxacin, Fluorescence probe, Quenching, Selenium

LIU Qing, HUAN Yanfu, ZHENG Qingchuan, FEI Qiang, FEI Yanqun, FAN Qian, FENG Guodong, SHAN Hongyan. A Selective and Sensitive Fluorescence Probe for Se(Ⅳ) Based on Fluorescence Quenching of Gatifloxacin[J]. 高等学校化学研究, 2016, 32(5): 736-741.

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A Selective and Sensitive Fluorescence Probe for Se(Ⅳ) Based on Fluorescence Quenching of Gatifloxacin

A Selective and Sensitive Fluorescence Probe for Se(Ⅳ) Based on Fluorescence Quenching of Gatifloxacin

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