Selenium-catalyzed Oxidative Carbonylation of Benzylamines to 1, 3-Dibenzylureas

doi:10.1007/s40242-017-6427-0

高等学校化学研究 ›› 2017, Vol. 33 ›› Issue (3): 384-387.doi: 10.1007/s40242-017-6427-0

Selenium-catalyzed Oxidative Carbonylation of Benzylamines to 1, 3-Dibenzylureas

ZHANG Xiaopeng, LI Zhengwei, WANG Ping, FAN Xuesen, ZHANG Guisheng

Key Laboratory of Organic Functional Molecule and Drug Innovation, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, P. R. China

收稿日期:2016-10-17 修回日期:2016-11-14 出版日期:2017-06-01 发布日期:2016-12-26
通讯作者: ZHANG Xiaopeng,Z,E-mail:zhangxiaopengv@sina.com;HANG Guisheng,E-mail:zgs@htu.cn E-mail:zhangxiaopengv@sina.com;zgs@htu.cn
基金资助:
Supported by the Program for Changjiang Scholars and Innovative Research Team in University, China(No.IRT1061), the Program for Innovative Research Team in Science and Technology in University of Henan Province, China(No.15IRTSTHN003) and the Young Backbone Teachers Training Fund of the Education Department of Henan Province, China(No.2013GGJS-059).

Selenium-catalyzed Oxidative Carbonylation of Benzylamines to 1, 3-Dibenzylureas

ZHANG Xiaopeng, LI Zhengwei, WANG Ping, FAN Xuesen, ZHANG Guisheng

Key Laboratory of Organic Functional Molecule and Drug Innovation, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, P. R. China

Received:2016-10-17 Revised:2016-11-14 Online:2017-06-01 Published:2016-12-26
Contact: ZHANG Xiaopeng,Z,E-mail:zhangxiaopengv@sina.com;HANG Guisheng,E-mail:zgs@htu.cn E-mail:zhangxiaopengv@sina.com;zgs@htu.cn
Supported by:
Supported by the Program for Changjiang Scholars and Innovative Research Team in University, China(No.IRT1061), the Program for Innovative Research Team in Science and Technology in University of Henan Province, China(No.15IRTSTHN003) and the Young Backbone Teachers Training Fund of the Education Department of Henan Province, China(No.2013GGJS-059).

摘要/Abstract

摘要：

A facile, efficient and cost-effective approach to 1,3-dibenzylurea was reported. With cheap and recyclable nonmetal selenium as catalyst, carbon monoxide instead of phosgene derivatives as carbonylation agent and oxygen as oxidant, the selenium-catalyzed oxidative carbonylation reaction of benzylamines can proceed efficiently in one-pot manner in the presence of triethylamine to afford the desired 1,3-dibenzylureas mostly in moderate to excellent yields. Selenium catalyst can be easily recovered due to its phase-transfer catalytic function and recycled.

关键词: Selenium, Oxidative carbonylation, 1, 3-Dibenzylurea

Abstract:

Key words: Selenium, Oxidative carbonylation, 1, 3-Dibenzylurea

ZHANG Xiaopeng, LI Zhengwei, WANG Ping, FAN Xuesen, ZHANG Guisheng. Selenium-catalyzed Oxidative Carbonylation of Benzylamines to 1, 3-Dibenzylureas[J]. 高等学校化学研究, 2017, 33(3): 384-387.

ZHANG Xiaopeng, LI Zhengwei, WANG Ping, FAN Xuesen, ZHANG Guisheng. Selenium-catalyzed Oxidative Carbonylation of Benzylamines to 1, 3-Dibenzylureas[J]. Chemical Research in Chinese Universities, 2017, 33(3): 384-387.

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Selenium-catalyzed Oxidative Carbonylation of Benzylamines to 1, 3-Dibenzylureas

Selenium-catalyzed Oxidative Carbonylation of Benzylamines to 1, 3-Dibenzylureas

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