Extraction of Lithium from Salt Lake Brine with Triisobutyl Phosphate in Ionic Liquid and Kerosene

doi:10.1007/s40242-015-4376-z

高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (4): 621-626.doi: 10.1007/s40242-015-4376-z

Extraction of Lithium from Salt Lake Brine with Triisobutyl Phosphate in Ionic Liquid and Kerosene

GAO Daolin¹, YU Xiaoping¹, GUO Yafei¹, WANG Shiqiang¹, LIU Mingming¹, DENG Tianlong¹, CHEN Yuwei^1,2, BELZILE Nelson^1,2

1. Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Material Science, Tianjin University of Science and Technology, Tianjin 300457, P. R. China;
2. Department of Chemistry & Biochemistry, Laurentian University, Sudbury P3E2C6, Canada

收稿日期:2014-10-09 修回日期:2015-01-12 出版日期:2015-08-01 发布日期:2015-02-02
通讯作者: DENG Tianlong E-mail:tldeng@tust.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21276194, U1407113), the Training Program for Changjiang Scholars and Innovative Research Team in University, China(No.[2013]373) and the Innovative Research Team of Tianjin Municipal Education Commission, China(No.TD12-5004).

Extraction of Lithium from Salt Lake Brine with Triisobutyl Phosphate in Ionic Liquid and Kerosene

GAO Daolin¹, YU Xiaoping¹, GUO Yafei¹, WANG Shiqiang¹, LIU Mingming¹, DENG Tianlong¹, CHEN Yuwei^1,2, BELZILE Nelson^1,2

1. Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Material Science, Tianjin University of Science and Technology, Tianjin 300457, P. R. China;
2. Department of Chemistry & Biochemistry, Laurentian University, Sudbury P3E2C6, Canada

Received:2014-10-09 Revised:2015-01-12 Online:2015-08-01 Published:2015-02-02
Contact: DENG Tianlong E-mail:tldeng@tust.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21276194, U1407113), the Training Program for Changjiang Scholars and Innovative Research Team in University, China(No.[2013]373) and the Innovative Research Team of Tianjin Municipal Education Commission, China(No.TD12-5004).

摘要/Abstract

摘要：

Three ionic liquids(ILs), namely, 1-butyl-3-methylimidazolium hexafluorophosphate, 1-butyl-3-me- thylimidazolium bis[(trifluoromethyl)sulfonyl]imide and 1-ethyl-3-methylimidazolium bis[(trifluoromethyl)sul- fonyl]imide with the triisobutyl phosphate(TIBP) and kerosene system were respectively used to extract lithium ion from salt lake brine with a high concentration ratio of magnesium and lithium experimentally. Results indicate that the highest extraction selectivity for lithium was obtained with IL 1-ethyl-3-methylimidazolium bis[(trifluoromethyl)- sulfonyl]imide. The effects of solution pH and phase ratio R(O/A) on the extractive step and the influence of acid concentration of the stripping solution and R(O/A) on the back extraction step were also investigated systematically. The single-step extraction efficiency of lithium ion was 83.71% under the optimal extraction conditions, and the single-step back extraction efficiency was 85.61% with a 1.0 mol/L HCl in 1.0 mol/L NaCl medium as stripping agent at R(O/A)=2. The liquid-liquid extraction mechanism and the complex of the ligand with lithium were proposed.

关键词: Ionic liquid, Triisobutyl phosphate, Extraction, Lithium, Salt lake brine

Abstract:

Key words: Ionic liquid, Triisobutyl phosphate, Extraction, Lithium, Salt lake brine

GAO Daolin, YU Xiaoping, GUO Yafei, WANG Shiqiang, LIU Mingming, DENG Tianlong, CHEN Yuwei, BELZILE Nelson. Extraction of Lithium from Salt Lake Brine with Triisobutyl Phosphate in Ionic Liquid and Kerosene[J]. 高等学校化学研究, 2015, 31(4): 621-626.

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Extraction of Lithium from Salt Lake Brine with Triisobutyl Phosphate in Ionic Liquid and Kerosene

Extraction of Lithium from Salt Lake Brine with Triisobutyl Phosphate in Ionic Liquid and Kerosene

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