Effect of Lanthanum on Catalytic Performance of Ru/Al2O3 Catalyst for Hydrogenation of Esters to Corresponding Alcohols

doi:10.1007/s40242-015-4382-1

高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (4): 615-620.doi: 10.1007/s40242-015-4382-1

Effect of Lanthanum on Catalytic Performance of Ru/Al₂O₃ Catalyst for Hydrogenation of Esters to Corresponding Alcohols

ZHANG Lei, ZHENG Xiaojuan, LI Ruixiang

Key Lab of Green Chemistry and Technology, Ministry of Education, Department of Chemistry, Sichuan University, Chengdu 610064, P. R. China

收稿日期:2014-10-13 修回日期:2015-01-04 出版日期:2015-08-01 发布日期:2015-03-30
通讯作者: LI Ruixiang E-mail:liruixiang@scu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21072138).

Effect of Lanthanum on Catalytic Performance of Ru/Al₂O₃ Catalyst for Hydrogenation of Esters to Corresponding Alcohols

ZHANG Lei, ZHENG Xiaojuan, LI Ruixiang

Key Lab of Green Chemistry and Technology, Ministry of Education, Department of Chemistry, Sichuan University, Chengdu 610064, P. R. China

Received:2014-10-13 Revised:2015-01-04 Online:2015-08-01 Published:2015-03-30
Contact: LI Ruixiang E-mail:liruixiang@scu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21072138).

摘要/Abstract

摘要：

Ru-La/γ-Al₂O₃ catalyst was prepared by impregnation method and characterized by temperature programmed reduction(TPR), transmission electron microscopy(TEM), X-ray photoelectron spectra(XPS), Brunauer- Emmett-Teller(BET), X-ray diffraction(XRD), and NH₃-temperature programmed desorption(NH₃-TPD). NH₃-TPD revealed that the strong acidic centers in γ-Al₂O₃ are not the major factor to cause the hydrolysis of esters to acids in the hydrogenation of esters. The results of TPR and TEM indicate that the appropriately added lanthanum results in the good dispersion of ruthenium and the easy reduction of ruthenium oxide on Ru-La/γ-Al₂O₃, which could promote the catalytic activity of Ru-La/γ-Al₂O₃ for the hydrogenation of methyl propionate to propanol. When the amount of lanthanum added in the catalyst was up to 9%(mass fraction), 4%Ru-9%La/γ-Al₂O₃ catalyst gave a conversion of methyl propionate of 98.1% and a selectivity of 94.8% to propanol at a reaction temperature of 180 ℃ and a hydrogen pressure of 5.0 MPa.

关键词: Ruthenium, Lanthanum, Alumina, Methyl propionate, Hydrogenation, Propanol

Abstract:

Key words: Ruthenium, Lanthanum, Alumina, Methyl propionate, Hydrogenation, Propanol

ZHANG Lei, ZHENG Xiaojuan, LI Ruixiang. Effect of Lanthanum on Catalytic Performance of Ru/Al₂O₃ Catalyst for Hydrogenation of Esters to Corresponding Alcohols[J]. 高等学校化学研究, 2015, 31(4): 615-620.

ZHANG Lei, ZHENG Xiaojuan, LI Ruixiang. Effect of Lanthanum on Catalytic Performance of Ru/Al₂O₃ Catalyst for Hydrogenation of Esters to Corresponding Alcohols[J]. Chemical Research in Chinese Universities, 2015, 31(4): 615-620.

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Effect of Lanthanum on Catalytic Performance of Ru/Al₂O₃ Catalyst for Hydrogenation of Esters to Corresponding Alcohols

Effect of Lanthanum on Catalytic Performance of Ru/Al₂O₃ Catalyst for Hydrogenation of Esters to Corresponding Alcohols

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