Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method

doi:10.1007/s40242-013-3104-9

高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (3): 589-595.doi: 10.1007/s40242-013-3104-9

Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method

LIU Feng^1,2, WANG Lu^1,2, ZHANG Guang-chun^1,2, ZHENG Jun^1,2, TANG Tao¹

1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

收稿日期:2013-03-11 修回日期:2013-03-20 出版日期:2013-06-01 发布日期:2013-05-15
通讯作者: TANG Tao, E-mail: ttang@ciac.jl.cn E-mail:ttang@ciac.jl.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.51073149, 51233005).

Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method

LIU Feng^1,2, WANG Lu^1,2, ZHANG Guang-chun^1,2, ZHENG Jun^1,2, TANG Tao¹

1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received:2013-03-11 Revised:2013-03-20 Online:2013-06-01 Published:2013-05-15
Contact: Tao Tang E-mail:ttang@ciac.jl.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.51073149, 51233005).

摘要/Abstract

摘要：

Comb-like polyethylene(PE) was prepared via anionic polymerization combined with “graft-onto” process. The polybutadiene(PB) backbone underwent hydroxylation at 1,2-vinyl groups to obtain a controlled number of hydro- xyl groups along the main chain. After the translation of hydroxyl groups to tosyl groups, a nucleophilic substitution by living anionic PB chains was achieved. The comb PE was finally obtained by the hydrogenation of the obtained unsaturated comb polymer. Since the living anionic polymerization was used to prepare the backbones and the branch chains, molecular weight to molecular weight distribution(M_w/M_n<1.5) can be well-controlled in the final comb polymer, including the average number and length of branches.

关键词: Long chain branching, Polyethylene, Anionic polymerization, Comb-like polymer

Abstract:

Key words: Long chain branching, Polyethylene, Anionic polymerization, Comb-like polymer

LIU Feng, WANG Lu, ZHANG Guang-chun, ZHENG Jun, TANG Tao. Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method[J]. 高等学校化学研究, 2013, 29(3): 589-595.

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Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method

Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method

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