Hydrothermal Synthesis, Characterization and Photoluminescence Properties of GdOHCO3 Rhombic Microcrystals

doi:10.1007/s40242-013-3022-x

高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (5): 841-844.doi: 10.1007/s40242-013-3022-x

Hydrothermal Synthesis, Characterization and Photoluminescence Properties of GdOHCO₃ Rhombic Microcrystals

ZHANG You-jin, XU Zhen-yu, YIN Xiao-bin, HE Hong-mei

Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China

收稿日期:2013-01-11 修回日期:2013-03-28 出版日期:2013-10-01 发布日期:2013-09-17
通讯作者: ZHANG You-jin E-mail:zyj@ustc.edu.cn

Hydrothermal Synthesis, Characterization and Photoluminescence Properties of GdOHCO₃ Rhombic Microcrystals

ZHANG You-jin, XU Zhen-yu, YIN Xiao-bin, HE Hong-mei

Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China

Received:2013-01-11 Revised:2013-03-28 Online:2013-10-01 Published:2013-09-17
Contact: ZHANG You-jin E-mail:zyj@ustc.edu.cn

摘要/Abstract

摘要：

GdOHCO₃ rhombic microcrystals were synthesized by hydrothermal method with urea used as the precipitator. Experimental parameters, such as the molar ratio of the starting reagents, reaction temperature and reaction time were examined. The as-obtained product was characterized by powder X-ray diffraction(XRD), field-emission scanning electron microscopy(FESEM), X-ray photoelectron spectroscopy(XPS), Fourier transform infrared spectroscopy(FTIR) and spectrofluorometry. The main reactions to form GdOHCO₃were proposed. In addition, the photoluminescence(PL) properties of GdOHCO₃ rhombic microcrystals were discussed. The broad band located between 350 nm and 600 nm in the emission spectrum can be attributed to the self-trapped exciton luminescence.

关键词: GdOHCO₃, Hydrothermal method, Crystal growth, Rhombic microcrystal, Photoluminescence

Abstract:

Key words: GdOHCO₃, Hydrothermal method, Crystal growth, Rhombic microcrystal, Photoluminescence

ZHANG You-jin, XU Zhen-yu, YIN Xiao-bin, HE Hong-mei. Hydrothermal Synthesis, Characterization and Photoluminescence Properties of GdOHCO₃ Rhombic Microcrystals[J]. 高等学校化学研究, 2013, 29(5): 841-844.

ZHANG You-jin, XU Zhen-yu, YIN Xiao-bin, HE Hong-mei. Hydrothermal Synthesis, Characterization and Photoluminescence Properties of GdOHCO₃ Rhombic Microcrystals[J]. Chemical Research in Chinese Universities, 2013, 29(5): 841-844.

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Hydrothermal Synthesis, Characterization and Photoluminescence Properties of GdOHCO₃ Rhombic Microcrystals

Hydrothermal Synthesis, Characterization and Photoluminescence Properties of GdOHCO₃ Rhombic Microcrystals

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