Highly Sensitive and Selective Chemosensor for Cu2+ Based on a Schiff Base

doi:10.1007/s40242-013-2449-4

高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (3): 419-423.doi: 10.1007/s40242-013-2449-4

Highly Sensitive and Selective Chemosensor for Cu²⁺ Based on a Schiff Base

CAO Ben-nan¹, HU Qin¹, HUANG Yan², JIA Chun-man¹, ZHANG Qi^1,2

1. Key Study Center of Ministry of Education for Tropical Resources Utilization, Hainan Provincial Key Lab of Fine Chemicals, Hainan University, Haikou 570228, P. R. China;
2. Department of Chemistry and Chemical Engineering, Jiangsu University, Jiangsu 212013, P. R. China

收稿日期:2012-11-20 修回日期:2013-02-04 出版日期:2013-06-01 发布日期:2013-05-15
通讯作者: ZHANG Qi, E-mail: hnfinechem@163.com E-mail:hnfinechem@163.com
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21166008, 21261008), the Natural Science Foundation of Hainan Province, China(No.209001), the Youth Fund of Hainan University, China(No.qnjj1169) and the Technology Support Program of the Jiangsu Province, China(No.SBE 201077304).

Highly Sensitive and Selective Chemosensor for Cu²⁺ Based on a Schiff Base

CAO Ben-nan¹, HU Qin¹, HUANG Yan², JIA Chun-man¹, ZHANG Qi^1,2

1. Key Study Center of Ministry of Education for Tropical Resources Utilization, Hainan Provincial Key Lab of Fine Chemicals, Hainan University, Haikou 570228, P. R. China;
2. Department of Chemistry and Chemical Engineering, Jiangsu University, Jiangsu 212013, P. R. China

Received:2012-11-20 Revised:2013-02-04 Online:2013-06-01 Published:2013-05-15
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21166008, 21261008), the Natural Science Foundation of Hainan Province, China(No.209001), the Youth Fund of Hainan University, China(No.qnjj1169) and the Technology Support Program of the Jiangsu Province, China(No.SBE 201077304).

摘要/Abstract

摘要：

A new chemosensor based on a Schiff base has been designed and synthesized. Its sensing behavior toward various metal ions was investigated by fluorescence and UV-Vis spectroscopic methods. The fluorescence of the sensor was quenched and the color rapidly changed from canary yellow to brown after the addition of Cu²⁺, while no changes occurred after the addition of other metal ions, which contributes to the detection of Cu²⁺ with naked eyes. The fluorescence quantum yield of the ligand was calculated to be 0.52. The corresponding detection limit of Cu²⁺ was 5.721×10^-7mol/L, and the 1:1 binding mode of the sensor with Cu²⁺was revealed by Job's plot.

关键词: Chemosensor, Schiff base, Copper ion, Naked-eye detection, Quench

Abstract:

Key words: Chemosensor, Schiff base, Copper ion, Naked-eye detection, Quench

CAO Ben-nan, HU Qin, HUANG Yan, JIA Chun-man, ZHANG Qi. Highly Sensitive and Selective Chemosensor for Cu²⁺ Based on a Schiff Base[J]. 高等学校化学研究, 2013, 29(3): 419-423.

CAO Ben-nan, HU Qin, HUANG Yan, JIA Chun-man, ZHANG Qi. Highly Sensitive and Selective Chemosensor for Cu²⁺ Based on a Schiff Base[J]. Chemical Research in Chinese Universities, 2013, 29(3): 419-423.

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Highly Sensitive and Selective Chemosensor for Cu²⁺ Based on a Schiff Base

Highly Sensitive and Selective Chemosensor for Cu²⁺ Based on a Schiff Base

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