Naked Eye and Selective Detection of Copper(Ⅱ) in Mixed Aqueous Media Using a Cellulose-based Support

doi:10.1007/s40242-019-8313-4

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (4): 598-603.doi: 10.1007/s40242-019-8313-4

Naked Eye and Selective Detection of Copper(Ⅱ) in Mixed Aqueous Media Using a Cellulose-based Support

FETTOUCHE Souad^1,2, BOUKHRISS Aicha¹, TAHIRI Mohamed², CHERKAOUI Omar¹, BAZI Fathallaah³, GMOUH Said⁴

1. Laboratoire Recherche sur les Matériaux Textile(REMTEX), Ecole Supérieure des Induseries de Textile et de L'habillement(ESITH), Casablanca, BP 7731, Maroc;
2. Laboratoire Hydrogéochimie et Bassin versant, Faculté des Sciences Ain Chock, Université Hassan Ⅱ, Casablanca, B. P 5366, Maroc;
3. Laboratore Chimie Analytique et Physico-chimie des Matériaux, Faculté des Sciences Ben M'sik, Universitié Hassan Ⅱ, Casablanca, BP150, Macro;
4. Laboratoire d'lngénierie et Matériaux(LIMAT), Faculté des Sciences Ben M'sik, Université Hassan Ⅱ, Casablance, BP150, Maroc

收稿日期:2018-09-28 修回日期:2018-12-21 出版日期:2019-08-01 发布日期:2019-08-01
通讯作者: GMOUH Said E-mail:souad.fettouche@gmail.com

Naked Eye and Selective Detection of Copper(Ⅱ) in Mixed Aqueous Media Using a Cellulose-based Support

FETTOUCHE Souad^1,2, BOUKHRISS Aicha¹, TAHIRI Mohamed², CHERKAOUI Omar¹, BAZI Fathallaah³, GMOUH Said⁴

1. Laboratoire Recherche sur les Matériaux Textile(REMTEX), Ecole Supérieure des Induseries de Textile et de L'habillement(ESITH), Casablanca, BP 7731, Maroc;
2. Laboratoire Hydrogéochimie et Bassin versant, Faculté des Sciences Ain Chock, Université Hassan Ⅱ, Casablanca, B. P 5366, Maroc;
3. Laboratore Chimie Analytique et Physico-chimie des Matériaux, Faculté des Sciences Ben M'sik, Universitié Hassan Ⅱ, Casablanca, BP150, Macro;
4. Laboratoire d'lngénierie et Matériaux(LIMAT), Faculté des Sciences Ben M'sik, Université Hassan Ⅱ, Casablance, BP150, Maroc

Received:2018-09-28 Revised:2018-12-21 Online:2019-08-01 Published:2019-08-01
Contact: GMOUH Said E-mail:souad.fettouche@gmail.com

摘要/Abstract

摘要： A new colorimetric sensor based-azo dye for Cu²⁺ detection was synthesized and characterized by FTIR and NMR spectroscopies. The results showed that the azo dye had a high selective and sensitive recognition toward Cu²⁺. The solution containing the sensor changed color from pink to pale yellow with a hypsochromic shift in the presence of Cu²⁺. The sensor selectivity and sensitivity toward Cu²⁺ions were investigated by colorimetry and UV-Vis spectroscopy. For practical applications, a cellulosic textile test strip for high-selectivity detection of Cu²⁺ ions in aqueous solution was developed using the synthesized azo dye as chromogenic chemosensor molecule, while using a solid cellulose textile as a substrate. As a result, a spectacular color change of the test strip was observed depending on the amount of copper ions in contact with the strip, which allows an estimation of Cu²⁺ concentration by naked eye.

关键词: Copper(Ⅱ) ions detection, Azo dye, Chromogenic chemosensor, Cellulose-based probe

Abstract: A new colorimetric sensor based-azo dye for Cu²⁺ detection was synthesized and characterized by FTIR and NMR spectroscopies. The results showed that the azo dye had a high selective and sensitive recognition toward Cu²⁺. The solution containing the sensor changed color from pink to pale yellow with a hypsochromic shift in the presence of Cu²⁺. The sensor selectivity and sensitivity toward Cu²⁺ions were investigated by colorimetry and UV-Vis spectroscopy. For practical applications, a cellulosic textile test strip for high-selectivity detection of Cu²⁺ ions in aqueous solution was developed using the synthesized azo dye as chromogenic chemosensor molecule, while using a solid cellulose textile as a substrate. As a result, a spectacular color change of the test strip was observed depending on the amount of copper ions in contact with the strip, which allows an estimation of Cu²⁺ concentration by naked eye.

Key words: Copper(Ⅱ) ions detection, Azo dye, Chromogenic chemosensor, Cellulose-based probe

FETTOUCHE Souad, BOUKHRISS Aicha, TAHIRI Mohamed, CHERKAOUI Omar, BAZI Fathallaah, GMOUH Said. Naked Eye and Selective Detection of Copper(Ⅱ) in Mixed Aqueous Media Using a Cellulose-based Support[J]. 高等学校化学研究, 2019, 35(4): 598-603.

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Naked Eye and Selective Detection of Copper(Ⅱ) in Mixed Aqueous Media Using a Cellulose-based Support

Naked Eye and Selective Detection of Copper(Ⅱ) in Mixed Aqueous Media Using a Cellulose-based Support

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