Comparison Between Performances of PbO2 and F--doped PbO2 Anodes for Electrochemical Degradation of Aniline

高等学校化学研究 ›› 2010, Vol. 26 ›› Issue (6): 991-995.

Comparison Between Performances of PbO₂and F^--doped PbO₂ Anodes for Electrochemical Degradation of Aniline

WANG Xuan¹, HUANG Wei-min^1,2, LI Hui-ting¹, ZHANG Xue-na¹, LU Hai-yan^1,2 and LIN Hai-bo^1,2*

1. College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Suzhou Nistar Chemical Technology Co. Ltd., Suzhou 215123, P. R. China

收稿日期:2010-04-09 修回日期:2010-09-03 出版日期:2010-11-25 发布日期:2010-12-01
通讯作者: LIN Hai-bo E-mail:lhb910@jlu.edu.cn
作者简介:LIN Hai-bo. E-mail: lhb910@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.20873051), the High-tech Research and Development Program of China(No. 2006AA06Z321) and the Natural Science Foundation of Jiangsu Province, China(No.BK2008555).

Comparison Between Performances of PbO₂and F^--doped PbO₂ Anodes for Electrochemical Degradation of Aniline

WANG Xuan¹, HUANG Wei-min^1,2, LI Hui-ting¹, ZHANG Xue-na¹, LU Hai-yan^1,2 and LIN Hai-bo^1,2*

1. College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Suzhou Nistar Chemical Technology Co. Ltd., Suzhou 215123, P. R. China

Received:2010-04-09 Revised:2010-09-03 Online:2010-11-25 Published:2010-12-01
Contact: LIN Hai-bo E-mail:lhb910@jlu.edu.cn
About author:LIN Hai-bo. E-mail: lhb910@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.20873051), the High-tech Research and Development Program of China(No. 2006AA06Z321) and the Natural Science Foundation of Jiangsu Province, China(No.BK2008555).

摘要/Abstract

摘要： The paper deals with the influence of anode material on the efficiency of degradation for organic pollutants in water system. The electrochemical performance of fluorine ion doped lead dioxide(F–-PbO2) electrode for the degradation of aniline was compared with that of undoped lead dioxide(PbO2) electrode by ultraviolet- visible(UV-Vis) spectroscopy, linear voltammetry and other analytical methods, such as the measurement by chemical oxygen demand analyzer, high performance liquid chromatography and scanning electron micrography. It was shown that both PbO2 electrode and F–-PbO2 electrode could make aniline be mineralized completely and have the same degradation course, but F–-PbO2 electrode has much higher electrocatalytic activity than undoped PbO2 electrode for the electrochemical degradation of aniline. The experimental results confirm that F–-PbO2 electrode has much higher potential for oxygen evolution than undoped PbO2 electrode.

关键词: Lead dioxide electrode, Electrochemical oxidation, Degradation, Aniline

Abstract: The paper deals with the influence of anode material on the efficiency of degradation for organic pollutants in water system. The electrochemical performance of fluorine ion doped lead dioxide(F–-PbO2) electrode for the degradation of aniline was compared with that of undoped lead dioxide(PbO2) electrode by ultraviolet- visible(UV-Vis) spectroscopy, linear voltammetry and other analytical methods, such as the measurement by chemical oxygen demand analyzer, high performance liquid chromatography and scanning electron micrography. It was shown that both PbO2 electrode and F–-PbO2 electrode could make aniline be mineralized completely and have the same degradation course, but F–-PbO2 electrode has much higher electrocatalytic activity than undoped PbO2 electrode for the electrochemical degradation of aniline. The experimental results confirm that F–-PbO2 electrode has much higher potential for oxygen evolution than undoped PbO2 electrode.

Key words: Lead dioxide electrode, Electrochemical oxidation, Degradation, Aniline

WANG Xuan, HUANG Wei-min, LI Hui-ting, ZHANG Xue-na, LU Hai-yan and LIN Hai-bo*. Comparison Between Performances of PbO₂and F^--doped PbO₂ Anodes for Electrochemical Degradation of Aniline[J]. 高等学校化学研究, 2010, 26(6): 991-995.

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Comparison Between Performances of PbO₂and F^--doped PbO₂ Anodes for Electrochemical Degradation of Aniline

Comparison Between Performances of PbO₂and F^--doped PbO₂ Anodes for Electrochemical Degradation of Aniline

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