Effective Removal of Tetracycline by Using Biochar Supported Fe3O4 as a UV-Fenton Catalyst

doi:10.1007/s40242-018-8213-z

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (1): 79-84.doi: 10.1007/s40242-018-8213-z

Effective Removal of Tetracycline by Using Biochar Supported Fe₃O₄ as a UV-Fenton Catalyst

YU Xiaodan^1,2, LIN Xinchen³, LI Weiguang⁴, FENG Wei^2,3

1. School of Environment, Harbin Institute of Technology, Harbin 150090, P. R. China;
2. Key Labroratory of Songliao Aquatic Environnment, Ministry of Education, Jilin Jianzhu University, Changchun 130118, P. R. China;
3. Key Laboratory of Groundwater Resource and Environment, Ministry Education, College of Environment and Resources, Jilin University, Changchun 130021, P. R. China;
4. State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, P. R. China

收稿日期:2018-06-26 修回日期:2018-09-14 出版日期:2019-02-01 发布日期:2018-10-29
通讯作者: LI Weiguang, FENG Wei E-mail:hitliwg@126.com;weifeng@jlu.edu.cn

Effective Removal of Tetracycline by Using Biochar Supported Fe₃O₄ as a UV-Fenton Catalyst

YU Xiaodan^1,2, LIN Xinchen³, LI Weiguang⁴, FENG Wei^2,3

1. School of Environment, Harbin Institute of Technology, Harbin 150090, P. R. China;
2. Key Labroratory of Songliao Aquatic Environnment, Ministry of Education, Jilin Jianzhu University, Changchun 130118, P. R. China;
3. Key Laboratory of Groundwater Resource and Environment, Ministry Education, College of Environment and Resources, Jilin University, Changchun 130021, P. R. China;
4. State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, P. R. China

Received:2018-06-26 Revised:2018-09-14 Online:2019-02-01 Published:2018-10-29
Contact: LI Weiguang, FENG Wei E-mail:hitliwg@126.com;weifeng@jlu.edu.cn

摘要/Abstract

摘要： Novel Fe₃O₄-decorate hierarchical porous carbon skeleton derived from maize straw (Fe₃O₄@MSC) was synthesized by a facile co-precipitation process and a calcination process, which was developed as a UV assisted heterogeneous Fenton-like catalyst. The as-synthesized catalysts were characterized via X-ray powder diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), Brunauer-Emmet-Teller (BET) and vibrating sample magnetometer (VSM) at room temperature. The morphology and structure analysis revealed that the as-prepared Fe₃O₄@MSC retained the original pore morphology of the maize straw material. The non-uniform polyhedral Fe₃O₄ grew on the whole surface of the MSC, which reduced the aggragation of Fe₃O₄ and provided more active sites to strengthen the UV-assisted Fenton-like reaction. As a result, the tetracycline (TC) degradation efficiency after 40 min reaction and total organic carbon (TOC) removal efficiency after 2 h reaction of Fe₃O₄@MSC catalyzing UV-Fenton system reached 99.2% and 72.1%, respectively, which were more substantial than those of Fe₃O₄@MSC/H₂O₂ (31.5% and 2%), UV/H₂O₂ system (68% and 23.4%) and UV/Fe₃O₄/H₂O₂ (80% and 37.5%). The electron spin resonance (ESR) results showed that the ^·OH played an important role in the catalytic reaction. A possible degradation pathway of TC was proposed on the basis of the identified intermediates. Overall, the UV assisted heterogeneous Fenton-like process in Fe₃O₄@MSC improved the cycle of Fe³⁺/Fe²⁺ and activated the interfacial catalytic site, which eventually realized the enhancement of degradation and mineralization to tetracycline.

关键词: Fe₃O₄, Carbon skeleton of maize straw, Heterogeneous Fenton-like catalyst, UV irradiation, Degradation of tetracycline

Abstract: Novel Fe₃O₄-decorate hierarchical porous carbon skeleton derived from maize straw (Fe₃O₄@MSC) was synthesized by a facile co-precipitation process and a calcination process, which was developed as a UV assisted heterogeneous Fenton-like catalyst. The as-synthesized catalysts were characterized via X-ray powder diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), Brunauer-Emmet-Teller (BET) and vibrating sample magnetometer (VSM) at room temperature. The morphology and structure analysis revealed that the as-prepared Fe₃O₄@MSC retained the original pore morphology of the maize straw material. The non-uniform polyhedral Fe₃O₄ grew on the whole surface of the MSC, which reduced the aggragation of Fe₃O₄ and provided more active sites to strengthen the UV-assisted Fenton-like reaction. As a result, the tetracycline (TC) degradation efficiency after 40 min reaction and total organic carbon (TOC) removal efficiency after 2 h reaction of Fe₃O₄@MSC catalyzing UV-Fenton system reached 99.2% and 72.1%, respectively, which were more substantial than those of Fe₃O₄@MSC/H₂O₂ (31.5% and 2%), UV/H₂O₂ system (68% and 23.4%) and UV/Fe₃O₄/H₂O₂ (80% and 37.5%). The electron spin resonance (ESR) results showed that the ^·OH played an important role in the catalytic reaction. A possible degradation pathway of TC was proposed on the basis of the identified intermediates. Overall, the UV assisted heterogeneous Fenton-like process in Fe₃O₄@MSC improved the cycle of Fe³⁺/Fe²⁺ and activated the interfacial catalytic site, which eventually realized the enhancement of degradation and mineralization to tetracycline.

Key words: Fe₃O₄, Carbon skeleton of maize straw, Heterogeneous Fenton-like catalyst, UV irradiation, Degradation of tetracycline

YU Xiaodan, LIN Xinchen, LI Weiguang, FENG Wei. Effective Removal of Tetracycline by Using Biochar Supported Fe₃O₄ as a UV-Fenton Catalyst[J]. 高等学校化学研究, 2019, 35(1): 79-84.

YU Xiaodan, LIN Xinchen, LI Weiguang, FENG Wei. Effective Removal of Tetracycline by Using Biochar Supported Fe₃O₄ as a UV-Fenton Catalyst[J]. Chemical Research in Chinese Universities, 2019, 35(1): 79-84.

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Effective Removal of Tetracycline by Using Biochar Supported Fe₃O₄ as a UV-Fenton Catalyst

Effective Removal of Tetracycline by Using Biochar Supported Fe₃O₄ as a UV-Fenton Catalyst

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