Hydrothermal Synthesis and Characterization of Double Perovskites RSrMnFeO6(R=La, Pr, Nd, Sm)

高等学校化学研究 ›› 2010, Vol. 26 ›› Issue (4): 517-521.

Hydrothermal Synthesis and Characterization of Double Perovskites RSrMnFeO₆(R=La, Pr, Nd, Sm)

ZHANG Gang-hua, YUAN Hong-ming, CHEN Yan, LI Wei-juan, YANG Mei-qi and FENG Shou-hua*

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2009-05-20 修回日期:2009-09-15 出版日期:2010-07-25 发布日期:2010-10-01
通讯作者: FENG Shou-hua. E-mail: shfeng@mail.jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.20631010, 90922034 and 20771042).

Hydrothermal Synthesis and Characterization of Double Perovskites RSrMnFeO₆(R=La, Pr, Nd, Sm)

ZHANG Gang-hua, YUAN Hong-ming, CHEN Yan, LI Wei-juan, YANG Mei-qi and FENG Shou-hua*

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2009-05-20 Revised:2009-09-15 Online:2010-07-25 Published:2010-10-01
Contact: FENG Shou-hua. E-mail: shfeng@mail.jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.20631010, 90922034 and 20771042).

摘要/Abstract

摘要： A series of double perovskites RSrMnFeO₆(R=La, Pr, Nd, Sm) was synthesized under mild hydrothermal conditions. Crystal growths of the samples were sensitive to alkalinity, temperature, filling fraction, and composition of initial reaction mixture. The desired series of compounds belongs to the class of AA′BB′O6 perovskites with a random distribution of Mn and Fe atoms over the B-cation sub-lattice. Their structures show the distorted orthorhombic symmetry with space group Pnma. The shapes and sizes of the crystals were analyzed on a Rigaku JSM-6700F by scanning electron microscopy. Analysis done by XPS, M?ssbauer spectroscopy and iodometric titration reveals that Mn and Fe ions have +4 and +3 oxidation states, respectively.

关键词: Double perovskites, Orthorhombic, Hydrothermal synthesis

Abstract: A series of double perovskites RSrMnFeO₆(R=La, Pr, Nd, Sm) was synthesized under mild hydrothermal conditions. Crystal growths of the samples were sensitive to alkalinity, temperature, filling fraction, and composition of initial reaction mixture. The desired series of compounds belongs to the class of AA′BB′O6 perovskites with a random distribution of Mn and Fe atoms over the B-cation sub-lattice. Their structures show the distorted orthorhombic symmetry with space group Pnma. The shapes and sizes of the crystals were analyzed on a Rigaku JSM-6700F by scanning electron microscopy. Analysis done by XPS, M?ssbauer spectroscopy and iodometric titration reveals that Mn and Fe ions have +4 and +3 oxidation states, respectively.

Key words: Double perovskites, Orthorhombic, Hydrothermal synthesis

ZHANG Gang-hua, YUAN Hong-ming, CHEN Yan, LI Wei-juan, YANG Mei-qi and FENG Shou. Hydrothermal Synthesis and Characterization of Double Perovskites RSrMnFeO₆(R=La, Pr, Nd, Sm)[J]. 高等学校化学研究, 2010, 26(4): 517-521.

参考文献

[1] Yamazoe N., Teraoka Y., Catal. Today, 1990, 8, 175 [2] Tejuca L. G., Fierro J. L. G., Properties and Applications of Perovskite Type Oxides, Marcel Dekker, NewYork, 1993 [3] Hong K. P., Choi Y. H., Kwon Y. U., Jung D. Y., Lee J. S., Lee C. H., J. Solid State Chem., 2000, 150, 383 [4] Ganguli A. K., Grover V., Thirumal M., Mater. Res. Bull., 2001, 36, 1967 [5] Kobayashi K. L., Kimura T., Sawada H., Terakura K., Tokura Y., Nature, 1998, 395, 677 [6] Kobayashi K. I., Kimura T., Tomioka Y., Sawada H., Terakura K., Tokura Y., Phys. Rev. B, 1999, 59, 11159 [7] Garcia-Landa B., Ritter C., Ibarra M. R., Blasco J., Algarabel P. A., Mahendiran R., Garcia J., Solid State Commun., 1999, 110, 435 [8] Zeng Z., Fawcett I. D., Greenblatt M., Croft M., Mater. Res. Bull., 2001, 36, 705 [9] Han H., Kim C. S., Lee B. W., J. Magn. Magn. Mater., 2003, 254/255, 574 [10] Anderson M. T., Greenwood K. B., Taylor G. A., Poeppelmeier K. R., Prog. Solid State Chem., 1993, 22, 197 [11] Attfield M. P., Battle P. D., Bollen S. K., Gibb T. C., Whitehead R. J., J. Solid State Chem., 1992, 100, 37 [12] Attfield M. P., Battle P. D., Bollen S. K., Kim S. H., Powell A. V., Workman M., J Solid State Chem., 1992, 96, 344 [13] Ramesha K., Thangadurai V., Sutar D., Subramanyam S. V., Subbanna G. N., Gopalakrishnan, Mater. Res. Bull., 2000, 35, 559 [14] Shaheen R., Bashir J., Rundl?f H., Rennie A. R., Mater. Lett., 2005, 59, 2296 [15] Battle P. D., Jones C. W., J. Solid State Chem., 1989, 18, 108 [16] Anderson M. T., Poeppelmeier K. R., Chem. Mater., 1991, 3, 476 [17] Abakumov A. M., Rossell M. D., Seryakov S. A., Antipov E. V., J. Mater. Chem., 2005, 15, 4899 [18] Tian S. Z., Zhao J. C., Qiao C. D., Ji X. L., Jiang B. Z., Mater. Lett., 2006, 60, 2747 [19] Chen Y., Yuan H., Tian G., Zhang G., Feng S., J. Solid State Chem., 2007, 180, 167 [20] Wang D., Yu R. B., Feng S. H., Zheng W. J., Pang G. S., Zhao H., Chem. J. Chinese Universities, 1998, 19(1), 165 [21] Li B., Hakuta Y., Hayashi H., Chem. Commun., 2005, 1732 [22] Mao Y. C., Li G. S., Xu W., Feng S. H., J. Mater. Chem., 2000, 10, 479 [23] Song Z., Li G. H., Yu Y., Shi Z., Feng S. H., Chem. Res. Chinese Universities, 2009, 25(1), 1 [24] Wang L., Zhang H., Dong W., Shi Z., Feng S. H., Chem. Res. Chinese Universities, 2008, 24(4), 389 [25] Feng S., Xu R., Acc. Chem. Res., 2001, 34, 239 [26] Feng S., Yuan H., Shi Z., Chen Y., Wang Y., Huang K., Hou C., Li J., Pang G., Hou Y., J. Mater. Sci., 2008, 43, 2131 [27] Marezio M., Remeika J. P., Dernier P. D., Acta Crystallogr., Sect. B, 1970, B26, 2008 [28] Nakamura T., Choy J. H., J. Solid State Chem., 1977, 20, 233 [29] Galasso F., Pyle J., Inorg. Chem., 1963, 2, 482 [30] Bernal S.,?Botana F. J.,?Laachir A., Moral P., Martin G. A., Perrichon V., Eur. J. Solid State Inorg. Chem., 1991, 28, 421 [31] Seyama H., Soma M., J. Electron Spectrosc. Relat. Phemon., 1987, 42, 97 [32] Da Costa F. M. A., Dos Santos A. J. C., Inorg. Chim. Acta, 1987, 140, 105 [33] Hernandez T., Plazaola F., Rojo T., Barandiaran H. M., J. Alloys Compd., 2001, 323/324, 440

Hydrothermal Synthesis and Characterization of Double Perovskites RSrMnFeO₆(R=La, Pr, Nd, Sm)

Hydrothermal Synthesis and Characterization of Double Perovskites RSrMnFeO₆(R=La, Pr, Nd, Sm)

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