TiO2-supported Single-atom Catalysts: Synthesis, Structure, and Application

doi:10.1007/s40242-022-2224-5

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (5): 1123-1138.doi: 10.1007/s40242-022-2224-5

TiO₂-supported Single-atom Catalysts: Synthesis, Structure, and Application

LIU Zailun¹, SUN Like¹, ZHANG Qitao¹, TENG Zhenyuan², SUN Hongli¹, SU Chenliang¹

1. International Collaboration Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, Institute of Microscale Optoelectronics, Shenzhen University, Shenzhen 518060, P. R. China;
2. Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, Kitakyushu 804-8550, Japan

收稿日期:2022-06-30 出版日期:2022-10-01 发布日期:2022-10-08
通讯作者: ZHANG Qitao, SU Chenliang E-mail:qitao-zhang@szu.edu.cn;chmsuc@szu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China(Nos.21805191, 21972094, 22102102), the China Postdoctoral Science Foundation(No.2021T140472), the Guangdong Basic and Applied Basic Research Foundation, China(No.2020A1515010982), the Shenzhen Science and Technology Program, China(Nos.20200812122947002, 20200812160737002, RCJC20200714114434086, 827-000421).

TiO₂-supported Single-atom Catalysts: Synthesis, Structure, and Application

LIU Zailun¹, SUN Like¹, ZHANG Qitao¹, TENG Zhenyuan², SUN Hongli¹, SU Chenliang¹

1. International Collaboration Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, Institute of Microscale Optoelectronics, Shenzhen University, Shenzhen 518060, P. R. China;
2. Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, Kitakyushu 804-8550, Japan

Received:2022-06-30 Online:2022-10-01 Published:2022-10-08
Contact: ZHANG Qitao, SU Chenliang E-mail:qitao-zhang@szu.edu.cn;chmsuc@szu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China(Nos.21805191, 21972094, 22102102), the China Postdoctoral Science Foundation(No.2021T140472), the Guangdong Basic and Applied Basic Research Foundation, China(No.2020A1515010982), the Shenzhen Science and Technology Program, China(Nos.20200812122947002, 20200812160737002, RCJC20200714114434086, 827-000421).

摘要/Abstract

摘要： In recent years, single-atom catalysts(SACs) have attracted increasing attention in catalysis. However, their stability is considerably challenging. As a result, fine-tuning the interaction of metal single atoms(SA) with different types of supports has emerged as an effective strategy for improving their thermal and chemical stabilities. Owing to its non-toxicity, cost-effectiveness, high abundance, and excellent stability, as well as presence of rich, tunable, and reliable anchor sites for metal SA, TiO₂ has been extensively explored as a superior support for SACs. In this review, recent advances of TiO₂-supported SACs(M₁/TiO₂) are discussed, and synthetic strategies, structure elucidation, and catalytic applications are summarized. First, the recently developed synthetic strategies for M₁/TiO₂arehighlighted and summarized, identifying the major challenges for the precise fabrication of M₁/TiO₂. Subsequently, key characterization techniques for the structure identification of M₁/TiO₂are discussed. Next, catalytic applications of M₁/TiO₂ are highlighted, viz. photocatalysis, electrocatalysis, and thermocatalysis. In addition, the mechanism via geometric structures and electronic states of metal centers facilitate catalytic reactions is outlined. Finally, opportunities and challenges of M₁/TiO₂ in catalysis are discussed, which may inspire the future development of M₁/TiO₂ for multifunctional catalytic applications.

关键词: Single-atom catalyst, TiO₂ support, Synthetic strategy, Characterization, Catalytic application

Abstract: In recent years, single-atom catalysts(SACs) have attracted increasing attention in catalysis. However, their stability is considerably challenging. As a result, fine-tuning the interaction of metal single atoms(SA) with different types of supports has emerged as an effective strategy for improving their thermal and chemical stabilities. Owing to its non-toxicity, cost-effectiveness, high abundance, and excellent stability, as well as presence of rich, tunable, and reliable anchor sites for metal SA, TiO₂ has been extensively explored as a superior support for SACs. In this review, recent advances of TiO₂-supported SACs(M₁/TiO₂) are discussed, and synthetic strategies, structure elucidation, and catalytic applications are summarized. First, the recently developed synthetic strategies for M₁/TiO₂arehighlighted and summarized, identifying the major challenges for the precise fabrication of M₁/TiO₂. Subsequently, key characterization techniques for the structure identification of M₁/TiO₂are discussed. Next, catalytic applications of M₁/TiO₂ are highlighted, viz. photocatalysis, electrocatalysis, and thermocatalysis. In addition, the mechanism via geometric structures and electronic states of metal centers facilitate catalytic reactions is outlined. Finally, opportunities and challenges of M₁/TiO₂ in catalysis are discussed, which may inspire the future development of M₁/TiO₂ for multifunctional catalytic applications.

Key words: Single-atom catalyst, TiO₂ support, Synthetic strategy, Characterization, Catalytic application

LIU Zailun, SUN Like, ZHANG Qitao, TENG Zhenyuan, SUN Hongli, SU Chenliang. TiO₂-supported Single-atom Catalysts: Synthesis, Structure, and Application[J]. 高等学校化学研究, 2022, 38(5): 1123-1138.

LIU Zailun, SUN Like, ZHANG Qitao, TENG Zhenyuan, SUN Hongli, SU Chenliang. TiO₂-supported Single-atom Catalysts: Synthesis, Structure, and Application[J]. Chemical Research in Chinese Universities, 2022, 38(5): 1123-1138.

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TiO₂-supported Single-atom Catalysts: Synthesis, Structure, and Application

TiO₂-supported Single-atom Catalysts: Synthesis, Structure, and Application

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