Synthesis of N-TiO2@NH2-MIL-88(Fe) Core-shell Structure for Efficient Fenton Effect Assisted Methylene Bluedegradation under Visible Light

doi:10.1007/s40242-020-0285-x

Synthesis of N-TiO₂@NH₂-MIL-88(Fe) Core-shell Structure for Efficient Fenton Effect Assisted Methylene Bluedegradation under Visible Light

Core-shell TiO₂-based photocatalyst swith specific composition, morphology, and functionality have attracted considerable attention for their excellent degradation properties on organic pollutants via a photocatalytic oxidation process. Herein, a N-TiO2@NH2-MIL-88(Fe) core-shell structure was prepared by coating NH2-MIL-88(Fe) on nitrogen-doped TiO2 (N-TiO2) nanoparticles. Introduction of heteroatomnitrogen to pure TiO₂ expands the spectral response range, leading to enhanced quantum efficiency of photocatalyst. Furthermore, Loading NH₂-MIL-88(Fe) on N-TiO2 improved the adsorption ability of the nanocomposites due to the porous tunnels of NH2-MIL-88(Fe). The resulted 2-MIL-88(Fe) rapidly, partially reduced Fe3+ to Fe2+ in NH2-MIL-88(Fe), and further enhanced the Fenton effect to efficiently degrade methycore-shell N-TiO2@NH₂-MIL-88(Fe) nanocomposites realized transfer photo excited electrons from N-TiO₂ to NHlene blue dye (MB) under visible light (λ ≥ 420 nm) with the assistance of H₂O₂.

Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory of Function Materials for Molecule & Structure Construction, School of Materials Science and Engineering, University of Science and Technology Beijing, People’s Republic of China

收稿日期:2020-09-13 修回日期:2020-10-11 接受日期:2020-10-13 发布日期:2020-10-15
通讯作者: YUAN Huiting*, DONG Wenjun* E-mail:wdong@ustb.edu.cn
作者简介:YUAN Huiting*, REN Huizhen, LI Minning, LI Zetong, LIU Mingrui, DONG Wenjun*, WANG Ge and ZHUANG Tao
基金资助:
the National Natural Science Foundation of China (Nos.52071027, 51872025), the National Key Research and Development Program of China (No.2016 YFB0701100)， the National Key Research and Development H863 Program of China (No.18H86303ZT0032702) and the Fundamental Research Funds for the Central Universities (Nos.FRF-GF-20-03A，FRF-GF-19-006B).

Synthesis of N-TiO₂@NH₂-MIL-88(Fe) Core-shell Structure for Efficient Fenton Effect Assisted Methylene Bluedegradation under Visible Light

Core-shell TiO₂-based photocatalyst swith specific composition, morphology, and functionality have attracted considerable attention for their excellent degradation properties on organic pollutants via a photocatalytic oxidation process. Herein, a N-TiO2@NH2-MIL-88(Fe) core-shell structure was prepared by coating NH2-MIL-88(Fe) on nitrogen-doped TiO2 (N-TiO2) nanoparticles. Introduction of heteroatomnitrogen to pure TiO₂ expands the spectral response range, leading to enhanced quantum efficiency of photocatalyst. Furthermore, Loading NH2-MIL-88(Fe) on N-TiO2 improved the adsorption ability of the nanocomposites due to the porous tunnels of NH2-MIL-88(Fe). The resulted core-shell N-TiO2@NH2-MIL-88(Fe) nanocomposites realized transfer photo excited electrons from N-TiO₂ to NH₂-MIL-88(Fe) rapidly, partially reduced Fe3+ to Fe2+ in NH2-MIL-88(Fe), and further enhanced the Fenton effect to efficiently degrade methylene blue dye (MB) under visible light (λ ≥ 420 nm) with the assistance of H2O2.

Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory of Function Materials for Molecule & Structure Construction, School of Materials Science and Engineering, University of Science and Technology Beijing, People’s Republic of China

Received:2020-09-13 Revised:2020-10-11 Accepted:2020-10-13 Published:2020-10-15
Contact: YUAN Huiting*, DONG Wenjun* E-mail:wdong@ustb.edu.cn
About author:YUAN Huiting*, REN Huizhen, LI Minning, LI Zetong, LIU Mingrui, DONG Wenjun*, WANG Ge and ZHUANG Tao
Supported by:
the National Natural Science Foundation of China (Nos.52071027, 51872025), the National Key Research and Development Program of China (No.2016 YFB0701100)， the National Key Research and Development H863 Program of China (No.18H86303ZT0032702) and the Fundamental Research Funds for the Central Universities (Nos.FRF-GF-20-03A，FRF-GF-19-006B).

摘要/Abstract

摘要：

_{Core-shell TiO2-based photocatalyst swith specific composition, morphology, and functionality have attracted considerable attention for their excellent degradation properties on organic pollutants via a photocatalytic oxidation process. Herein, a N-TiO2@NH2-MIL-88(Fe) core-shell structure was prepared by coating NH2-MIL-88(Fe) on nitrogen-doped TiO2 (N-TiO2) nanoparticles. Introduction of heteroatomnitrogen to pure TiO2 expands the spectral response range, leading to enhanced quantum efficiency of photocatalyst. Furthermore, Loading NH2-MIL-88(Fe) on N-TiO2 improved the adsorption ability of the nanocomposites due to the porous tunnels of NH2-MIL-88(Fe). The resulted core-shell N-TiO2@NH2-MIL-88(Fe) nanocomposites realized transfer photo excited electrons from N-TiO2 to NH2-MIL-88(Fe) rapidly, partially reduced Fe3+ to Fe2+ in NH2-MIL-88(Fe), and further enhanced the Fenton effect to efficiently degrade methylene blue dye (MB) under visible light (λ ≥ 420 nm) with the assistance of H2O2.}

关键词: NH2-MIL-88(Fe), N-TiO2, Photocatalysis, Fenton effect

Abstract: Core-shell TiO2-based photocatalyst swith specific composition, morphology, and functionality have attracted considerable attention for their excellent degradation properties on organic pollutants via a photocatalytic oxidation process. Herein, a N-TiO2@NH2-MIL-88(Fe) core-shell structure was prepared by coating NH2-MIL-88(Fe) on nitrogen-doped TiO2 (N-TiO2) nanoparticles. Introduction of heteroatomnitrogen to pure TiO2 expands the spectral response range, leading to enhanced quantum efficiency of photocatalyst. Furthermore, Loading NH2-MIL-88(Fe) on N-TiO2 improved the adsorption ability of the nanocomposites due to the porous tunnels of NH2-MIL-88(Fe). The resulted core-shell N-TiO2@NH2-MIL-88(Fe) nanocomposites realized transfer photo excited electrons from N-TiO2 to NH2-MIL-88(Fe) rapidly, partially reduced Fe3+ to Fe2+ in NH2-MIL-88(Fe), and further enhanced the Fenton effect to efficiently degrade methylene blue dye (MB) under visible light (λ ≥ 420 nm) with the assistance of H2O2.

Key words: NH2-MIL-88(Fe), N-TiO2, Photocatalysis, Fenton effect

YUAN Huiting, REN Huizhen, LI Minning, LI Zetong, LIU Mingrui, DONG Wenjun, WANG Ge and ZHUANG Tao. Synthesis of N-TiO₂@NH₂-MIL-88(Fe) Core-shell Structure for Efficient Fenton Effect Assisted Methylene Bluedegradation under Visible Light[J]. 高等学校化学研究, doi: 10.1007/s40242-020-0285-x.

YUAN Huiting, REN Huizhen, LI Minning, LI Zetong, LIU Mingrui, DONG Wenjun, WANG Ge and ZHUANG Tao. Synthesis of N-TiO₂@NH₂-MIL-88(Fe) Core-shell Structure for Efficient Fenton Effect Assisted Methylene Bluedegradation under Visible Light[J]. Chemical Research in Chinese Universities, doi: 10.1007/s40242-020-0285-x.

[1]	Samavia RAFIQ, Zulfiqar Ali RAZA, Muhammad ASLAM, Muhammad Junaid BAKHTIYAR. Graphene Nanosheets Decorated with Copper Oxide Nanoparticles for the Photodegradation of Methylene Blue[J]. 高等学校化学研究, 2022, 38(6): 1518-1525.
[2]	SONG Weiyu, LV Xintong, GAO Yang, WANG Lu. Photocatalytic HER Performance of TiO₂-supported Single Atom Catalyst Based on Electronic Regulation:A DFT Study[J]. 高等学校化学研究, 2022, 38(4): 1025-1031.
[3]	DU Shihao, BIAN Xuanang, ZHAO Yunxuan, SHI Run, and ZHANG Tierui. Progress and Prospect of Photothermal Catalysis[J]. 高等学校化学研究, 2022, 38(3): 723-734.
[4]	LIU Shujing, GUO Jia. Two-dimensional Covalent Organic Frameworks: Intrinsic Synergy Promoting Photocatalytic Hydrogen Evolution[J]. 高等学校化学研究, 2022, 38(2): 373-381.
[5]	HU Guilin, HE Jingyi, LI Yongjun. Application of Graphdiyne and Its Analogues in Photocatalysis and Photoelectrochemistry[J]. 高等学校化学研究, 2021, 37(6): 1195-1212.
[6]	MA Yuying, HE Dayong, LIU Jiadi, WANG Yuannan, YANG Mei, WANG Hao, QIU Ju, LI Wenyan, LI Yongxin, WANG Ce. Adsorption and Visible Light Photocatalytic Degradation of Electrospun PAN@W₁₈O₄₉ Nanofibers[J]. 高等学校化学研究, 2021, 37(3): 428-435.
[7]	JIAN Shaoju, TIAN Zhiwei, ZHANG Kaiyin, DUAN Gaigai, YANG Weisen, JIANG Shaohua. Hydrothermal Synthesis of Ce-doped ZnO Heterojunction Supported on Carbon Nanofibers with High Visible Light Photocatalytic Activity[J]. 高等学校化学研究, 2021, 37(3): 565-570.
[8]	ZHAO Weifeng, HAO Ning, ZHANG Gai, MA Aijie, CHEN Weixing, ZHOU Hongwei, YANG Dong, XU Ben Bin, KONG Jie. In situ Carbon Modification of g-C₃N₄ from Urea co-Crystal with Enhanced Photocatalytic Activity Towards Degradation of Organic Dyes Under Visible Light[J]. 高等学校化学研究, 2020, 36(6): 1265-1271.
[9]	GU Xianmo, MA Pengwei, LIU Pei, WANG Ruiyi, LI Xincheng, ZHENG Zhanfeng. Visible-light-driven Hydroamination of Alkynes over a New Type of Activated Carbon Immobilized Cu²⁺ Photocatalyst[J]. 高等学校化学研究, 2020, 36(6): 1039-1044.
[10]	CHEN Ting, ZHONG Lei, YANG Zhen, MOU Zhigang, LIU Lei, WANG Yan, SUN Jianhua, LEI Weiwei. Enhanced Visible-light Photocatalytic Activity of g-C₃N₄/Nitrogen-doped Graphene Quantum Dots/TiO₂ Ternary Heterojunctions for Ciprofloxacin Degradation with Narrow Band Gap and High Charge Carrier Mobility[J]. 高等学校化学研究, 2020, 36(6): 1083-1090.
[11]	JIANG Wenshuai, ZONG Xupeng, WANG Xiayan, SUN Zaicheng. Transparent Coating with TiO₂ Nanorods for High-performance Photocatalytic Self-cleaning and Environmental Remediation[J]. 高等学校化学研究, 2020, 36(6): 1097-1101.
[12]	CEN Qing, XIAO Wei, LIU Yingqi, WANG Qi, NAFADY Ayman, MA Shengqian. Fabrication of Fe-POMs as Visible-light-active Heterogeneous Photocatalyst[J]. 高等学校化学研究, 2020, 36(6): 1128-1135.
[13]	WANG Changhua, ZHANG Xintong. Anatase/Bronze TiO₂ Heterojunction: Enhanced Photocatalysis and Prospect in Photothermal Catalysis[J]. 高等学校化学研究, 2020, 36(6): 992-999.
[14]	YU Qiuying, LIN Xiu, LI Xinhao, CHEN Jiesheng. Photocatalytic Stille Cross-coupling on Gold/g-C₃N₄Nano-heterojunction[J]. 高等学校化学研究, 2020, 36(6): 1013-1016.
[15]	LI Xiaodong, SU Qing, LIU Ziqian, LUO Kexin, LI Guanghua, WU Qiaolin. A Triformylphloroglucinol-based Covalent Organic Polymer: Synthesis, Characterization and Its Application in Visible-light-driven Oxidative Coupling Reactions of Primary Amines[J]. 高等学校化学研究, 2020, 36(6): 1017-1023.

Synthesis of N-TiO₂@NH₂-MIL-88(Fe) Core-shell Structure for Efficient Fenton Effect Assisted Methylene Bluedegradation under Visible Light

Synthesis of N-TiO₂@NH₂-MIL-88(Fe) Core-shell Structure for Efficient Fenton Effect Assisted Methylene Bluedegradation under Visible Light

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价