Artificial Solid Electrolyte Interphase Acting as “Armor” to Protect the Anode Materials for High-performance Lithium-ion Battery

doi:10.1007/s40242-020-0091-5

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (3): 402-409.doi: 10.1007/s40242-020-0091-5

Artificial Solid Electrolyte Interphase Acting as “Armor” to Protect the Anode Materials for High-performance Lithium-ion Battery

WANG Haitao, TANG Yongbing

Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, P. R. China

收稿日期:2020-04-05 修回日期:2020-04-20 出版日期:2020-06-01 发布日期:2020-05-30
通讯作者: TANG Yongbing E-mail:tangyb@siat.ac.cn
基金资助:
Supported by the Key-Area Research and Development Program of Guangdong Province, China(No.2019B090914003), the National Natural Science Foundation of China(Nos.51822210, 51972329), the Shenzhen Science and Technology Planning Project, China(No.JCYJ20190807172001755), the China Postdoctoral Science Foundation(No.2018M643235) and the Science and Technology Planning Project of Guangdong Province, China(No. 2019A1515011902).

Artificial Solid Electrolyte Interphase Acting as “Armor” to Protect the Anode Materials for High-performance Lithium-ion Battery

WANG Haitao, TANG Yongbing

Functional Thin Films Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, P. R. China

Received:2020-04-05 Revised:2020-04-20 Online:2020-06-01 Published:2020-05-30
Contact: TANG Yongbing E-mail:tangyb@siat.ac.cn
Supported by:
Supported by the Key-Area Research and Development Program of Guangdong Province, China(No.2019B090914003), the National Natural Science Foundation of China(Nos.51822210, 51972329), the Shenzhen Science and Technology Planning Project, China(No.JCYJ20190807172001755), the China Postdoctoral Science Foundation(No.2018M643235) and the Science and Technology Planning Project of Guangdong Province, China(No. 2019A1515011902).

摘要/Abstract

摘要： The electrochemical performances of lithium-ion batteries(LIBs) are closely related to the interphase between the electrode materials and electrolytes. However, the development of lithium-ion batteries is hampered by the formation of uncontrollable solid electrolyte interphase(SEI) and subsequent potential safety issues associated with dendritic formation and cell short-circuits during cycling. Fabricating artificial SEI layer can be one promising approach to solve the above issues. This review summarizes the principles and methods of fabricating artificial SEI for three types of main anodes:deposition-type(e.g., Li), intercalation-type(e.g., graphite) and alloy-type(e.g., Si, Al). The review elucidates recent progress and discusses possible methods for constructing stable artificial SEIs composed of salts, polymers, oxides, and nanomaterials that simultaneously passivate anode against side reactions with electrolytes and regulate Li⁺ ions transport at interfaces. Moreover, the reaction mechanism of artificial SEIs was briefly analyzed, and the research prospect was also discussed.

关键词: Lithium-ion battery, Artificial solid electrolyte interphase (SEI), Anode, Reaction mechanism

Abstract: The electrochemical performances of lithium-ion batteries(LIBs) are closely related to the interphase between the electrode materials and electrolytes. However, the development of lithium-ion batteries is hampered by the formation of uncontrollable solid electrolyte interphase(SEI) and subsequent potential safety issues associated with dendritic formation and cell short-circuits during cycling. Fabricating artificial SEI layer can be one promising approach to solve the above issues. This review summarizes the principles and methods of fabricating artificial SEI for three types of main anodes:deposition-type(e.g., Li), intercalation-type(e.g., graphite) and alloy-type(e.g., Si, Al). The review elucidates recent progress and discusses possible methods for constructing stable artificial SEIs composed of salts, polymers, oxides, and nanomaterials that simultaneously passivate anode against side reactions with electrolytes and regulate Li⁺ ions transport at interfaces. Moreover, the reaction mechanism of artificial SEIs was briefly analyzed, and the research prospect was also discussed.

Key words: Lithium-ion battery, Artificial solid electrolyte interphase (SEI), Anode, Reaction mechanism

WANG Haitao, TANG Yongbing. Artificial Solid Electrolyte Interphase Acting as “Armor” to Protect the Anode Materials for High-performance Lithium-ion Battery[J]. 高等学校化学研究, 2020, 36(3): 402-409.

WANG Haitao, TANG Yongbing. Artificial Solid Electrolyte Interphase Acting as “Armor” to Protect the Anode Materials for High-performance Lithium-ion Battery[J]. Chemical Research in Chinese Universities, 2020, 36(3): 402-409.

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Artificial Solid Electrolyte Interphase Acting as “Armor” to Protect the Anode Materials for High-performance Lithium-ion Battery

Artificial Solid Electrolyte Interphase Acting as “Armor” to Protect the Anode Materials for High-performance Lithium-ion Battery

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