Preparation and Properties of Hybrid Silane-crosslinked Sulfonated Poly(aryl ether ketone)s as Proton Exchange Membranes

doi:10.1007/s40242-019-9066-9

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (5): 937-944.doi: 10.1007/s40242-019-9066-9

Preparation and Properties of Hybrid Silane-crosslinked Sulfonated Poly(aryl ether ketone)s as Proton Exchange Membranes

LIU Zhenchao¹, WANG Peng¹, HU Wei², LIU Baijun¹

1. Key Laboratory of High Performance Plastics, Ministry of Education, National & Local Joint Engineering Laboratory for Synthesis Technology of High Performance Polymer, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. College of Chemical Engineering, Changchun University of Technology, Changchun 130012, P. R. China

收稿日期:2019-03-07 出版日期:2019-10-01 发布日期:2019-09-24
通讯作者: LIU Baijun E-mail:liubj@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.51873076, 21404013), the Science and Technology Development Project of Jilin Province, China(Nos.20170101110JC, 20180201076GX, 20180201075GX), and the Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, China(No.201826).

Preparation and Properties of Hybrid Silane-crosslinked Sulfonated Poly(aryl ether ketone)s as Proton Exchange Membranes

LIU Zhenchao¹, WANG Peng¹, HU Wei², LIU Baijun¹

1. Key Laboratory of High Performance Plastics, Ministry of Education, National & Local Joint Engineering Laboratory for Synthesis Technology of High Performance Polymer, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. College of Chemical Engineering, Changchun University of Technology, Changchun 130012, P. R. China

Received:2019-03-07 Online:2019-10-01 Published:2019-09-24
Contact: LIU Baijun E-mail:liubj@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.51873076, 21404013), the Science and Technology Development Project of Jilin Province, China(Nos.20170101110JC, 20180201076GX, 20180201075GX), and the Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, China(No.201826).

摘要/Abstract

摘要： A series of novel organic-inorganic hybrid proton-conducting electrolyte membranes with silane-crosslinked sulfonated poly(aryl ether ketone)(SC-SPAEK) networks was prepared via a simple procedure that includes solution casting and acid treatment. The organosilicon pendants of the silane-grafted SPAEK, which were expected to serve as coupling and crosslinking agents, were found to play a key role in the homogenous dispersion of inorganic particles and improved the performance of hybrid membranes. The hybrid membranes exhibited enhanced proton conductivity, and SC-SPAEK/TiO₂-4 showed an extremely high proton conductivity of 0.1472 S/cm at 100℃. The crosslinked hybrid membranes also demonstrated good chemical resistance, oxidative stability, and mechanical properties. The crosslinked hybrid membranes with excellent comprehensive performance may be a promising material for proton exchange membrane fuel cells.

关键词: Proton-conducting electrolyte membrane, Sulfonated poly(aryl ether ketones), Cross-linked network, Hybrid

Abstract: A series of novel organic-inorganic hybrid proton-conducting electrolyte membranes with silane-crosslinked sulfonated poly(aryl ether ketone)(SC-SPAEK) networks was prepared via a simple procedure that includes solution casting and acid treatment. The organosilicon pendants of the silane-grafted SPAEK, which were expected to serve as coupling and crosslinking agents, were found to play a key role in the homogenous dispersion of inorganic particles and improved the performance of hybrid membranes. The hybrid membranes exhibited enhanced proton conductivity, and SC-SPAEK/TiO₂-4 showed an extremely high proton conductivity of 0.1472 S/cm at 100℃. The crosslinked hybrid membranes also demonstrated good chemical resistance, oxidative stability, and mechanical properties. The crosslinked hybrid membranes with excellent comprehensive performance may be a promising material for proton exchange membrane fuel cells.

Key words: Proton-conducting electrolyte membrane, Sulfonated poly(aryl ether ketones), Cross-linked network, Hybrid

LIU Zhenchao, WANG Peng, HU Wei, LIU Baijun. Preparation and Properties of Hybrid Silane-crosslinked Sulfonated Poly(aryl ether ketone)s as Proton Exchange Membranes[J]. 高等学校化学研究, 2019, 35(5): 937-944.

LIU Zhenchao, WANG Peng, HU Wei, LIU Baijun. Preparation and Properties of Hybrid Silane-crosslinked Sulfonated Poly(aryl ether ketone)s as Proton Exchange Membranes[J]. Chemical Research in Chinese Universities, 2019, 35(5): 937-944.

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Preparation and Properties of Hybrid Silane-crosslinked Sulfonated Poly(aryl ether ketone)s as Proton Exchange Membranes

Preparation and Properties of Hybrid Silane-crosslinked Sulfonated Poly(aryl ether ketone)s as Proton Exchange Membranes

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