Phase Behavior of Ionic Liquids-Cesium Carbonate-Water Aqueous Two-phase Systems and Their Extraction of L-Tryptophan

doi:10.1007/s40242-018-7148-8

高等学校化学研究 ›› 2018, Vol. 34 ›› Issue (1): 127-131.doi: 10.1007/s40242-018-7148-8

Phase Behavior of Ionic Liquids-Cesium Carbonate-Water Aqueous Two-phase Systems and Their Extraction of L-Tryptophan

LI Shuang, LI Shuni, ZHAI Quanguo, JIANG Yucheng, HU Mancheng

Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, P. R. China

收稿日期:2017-04-19 出版日期:2018-02-01 发布日期:2018-01-20
通讯作者: LI Shuni,E-mail:lishuni@snnu.edu.cn;HU Mancheng,E-mail:hmch@snnu.edu.cn E-mail:lishuni@snnu.edu.cn;hmch@snnu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21571120) and the Fundamental Research Funds for the Central Universities, China(No.GK201701003).

Phase Behavior of Ionic Liquids-Cesium Carbonate-Water Aqueous Two-phase Systems and Their Extraction of L-Tryptophan

LI Shuang, LI Shuni, ZHAI Quanguo, JIANG Yucheng, HU Mancheng

Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, P. R. China

Received:2017-04-19 Online:2018-02-01 Published:2018-01-20
Contact: LI Shuni,E-mail:lishuni@snnu.edu.cn;HU Mancheng,E-mail:hmch@snnu.edu.cn E-mail:lishuni@snnu.edu.cn;hmch@snnu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21571120) and the Fundamental Research Funds for the Central Universities, China(No.GK201701003).

摘要/Abstract

摘要： Phase behavior and extraction ability of aqueous two-phase systems(ATPs) consisting of ionic liquids(ILs), Cs₂CO₃ and water were investigated in this paper. Four kinds of ionic liquids, namely, 1-amyl-3-methylimidazolium bromide([C₅mim]Br), 1-hexyl-3-methylimidazolium bromide([C₆mim]Br), 1-heptyl-3-methylimidazolium bromide ([C₇mim]Br) and 1-octyl-3-methylimidazolium bromide([C₈mim]Br), were examined to discuss the influence of alkyl groups. Binodal curves and tie-lines at 288.15, 298.15 and 308.15 K were obtained. The partitioning behavior for L-tryptophan in such ATPs was further investigated. The effect of temperature, pH, Cs₂CO₃ concentration and the structure of ionic liquids on the partitioning were discussed in detail.

关键词: Aqueous two-phase system, Ionic liquid, Cs₂CO₃, Partitioning behavior

Abstract: Phase behavior and extraction ability of aqueous two-phase systems(ATPs) consisting of ionic liquids(ILs), Cs₂CO₃ and water were investigated in this paper. Four kinds of ionic liquids, namely, 1-amyl-3-methylimidazolium bromide([C₅mim]Br), 1-hexyl-3-methylimidazolium bromide([C₆mim]Br), 1-heptyl-3-methylimidazolium bromide ([C₇mim]Br) and 1-octyl-3-methylimidazolium bromide([C₈mim]Br), were examined to discuss the influence of alkyl groups. Binodal curves and tie-lines at 288.15, 298.15 and 308.15 K were obtained. The partitioning behavior for L-tryptophan in such ATPs was further investigated. The effect of temperature, pH, Cs₂CO₃ concentration and the structure of ionic liquids on the partitioning were discussed in detail.

Key words: Aqueous two-phase system, Ionic liquid, Cs₂CO₃, Partitioning behavior

LI Shuang, LI Shuni, ZHAI Quanguo, JIANG Yucheng, HU Mancheng. Phase Behavior of Ionic Liquids-Cesium Carbonate-Water Aqueous Two-phase Systems and Their Extraction of L-Tryptophan[J]. 高等学校化学研究, 2018, 34(1): 127-131.

参考文献

[1] Albertsson P. A., Nature, 1958, 182(4637), 709
[2] Danielsson R., Albertsson P. A., Prep. Biochem. & Biotech., 2013, 43(5), 512
[3] Silva D. N. R., Ferreira L. A., Madeira P. P., Teixeira J. A., Uversky V. N., Zaslavsky B. Y., J. Chromatogr. A, 2015, 1415(10), 1
[4] Plechkova N. V., Seddon K. R., Chem. Soc. Rev., 2008, 37(1), 123
[5] Rogers R. D., Seddon K. R., Science, 2003, 302(5646), 792
[6] Durga G., Mishra A., Ionic Liquids: Industrial Applications. Encyclopedia of Inorganic and Bioinorganic Chemistry, John Wiley & Sons, New Jersy, 2016, 1
[7] Amarasekara A. S., Chem. Rev., 2016, 116(10), 6133
[8] Dong K., Liu X. M., Dong H. F., Zhang X., Zhang S. J., Chem. Rev., 2017, 117(10), 6636
[9] Zhu J., Jin Z. M., Chem. Res. Chinese Universities, 2016, 32(4), 630
[10] Bian M., Tian L., Yao C., Chem. Res. Chinese Universities, 2017, 33(4), 552
[11] Gao S. H., Gao R. C., Chem. Res. Chinese Universities, 2017, 33(4), 678
[12] Gutowski K. E., Broker G. A., Willauer H. D., Huddleston J. G., Swatloski R. P., Holbrey J. D., Rogers R. D., J. Am. Chem. Soc., 2003, 125(22), 6632
[13] Desai R. K., Streefland M., Wijffels R. H., Eppink M. H. M., Green Chem., 2014, 16(5), 2670
[14] Fan Y. C., Dong X., Li Y., Zhong Y. Y., Miao J., Hua S. F., Sun Y. C., Ind. Eng. Chem. Res., 2015, 54(51), 12966
[15] Wang Z., Pei Y. C., Zhao J., Li Z. Y., Chen, Y. J., Zhuo K. L., J. Phy. Chem. B, 2015, 119(12), 4471
[16] Yan J. K., Ma H. L., Pei J. J., Wang Z. B., Wu J. Y., Sep. Purif. Technol., 2014, 135(10), 278
[17] Shu Y., Gao M. C., Wang X. Y., Song R. S., Lu J., Chen X. W., Talanta, 2016, 149, 6
[18] Cízová A., Korcová J., Farkaš P., Bystrický S., Int. J. Biol. Macrmol., 2017, 98, 314
[19] Yang Z. Z., Tan Z. J., Li F. F., Li X. D., Ind. Crop. Prod., 2016, 89, 78
[20] Lee S. Y., Khoiroh L., Ling T. C., Show P. L., Sep. Purif. Technol., 2017, 179, 152
[21] Freire M. G., Green Chem. & Sustain. Technol., 2016, 23(7), 514
[22] Freire M. G., Cláudio A. F. M., Araújo J. M. M., Coutinho J. A. P., Marrucho I. M., Canongia Lopes J. N., Rebelo L. P. N., Chem. Soc. Rev., 2012, 41(14), 4966
[23] Salabat A., Sanij F. D., Bull. Korean Chem. Soc., 2012, 33(33), 3387
[24] Raizada P., Vyas V., Sharma U., Indian J. Chem. Technol., 2010, 17(4), 267
[25] Hu M. C., Zhai Q. G., Liu Z. L., J. Chem. Eng. Data., 2004, 49(3), 717
[26] Hu M. C., Zhu X., Li S. N., Zhai Q. G., Jiang Y. C., Lin X. Y., Tuo C. S., J. Chem. Eng. Data, 2009, 54(10), 2866
[27] Singh M. R., Bell A. T., Energ. Environ. Sci., 2016, 9(1), 193
[28] Pei Y. C., Wang J. J., Liu L., Wu K., Zhao Y., J. Chem. Eng. Data, 2007, 52(5), 2026
[29] Merchuk J. C., Andrews B. A., Asenjo J. A., J. Chromatogr. B, 1998, 711(1/2), 285
[30] Othmer D. F., Tobias P. E., Ind. Eng. Chem. Res., 1942, 34(6), 690
[31] Gonzalez-Tello P., Camacho F., Lázquez G., Alarcón F. J., J. Chem. Eng. Data, 1996, 41(6), 1333
[32] Salabat A., Abnosi M. H., Motahari A., J. Chem. Eng. Data, 2008, 53(9), 2018
[33] Hamzehzadeh S., Vasiresh M., Fluid Phase Equilib., 2004, 382(6), 80

Phase Behavior of Ionic Liquids-Cesium Carbonate-Water Aqueous Two-phase Systems and Their Extraction of L-Tryptophan

Phase Behavior of Ionic Liquids-Cesium Carbonate-Water Aqueous Two-phase Systems and Their Extraction of L-Tryptophan

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	YU Fengli, CHI Yujie, GAO Chong, CHEN Ruirui, XIE Congxia, YU Shitao. Baeyer-Villiger Oxidation of Cyclic Ketones Catalyzed by Amino Acid Ionic Liquids[J]. 高等学校化学研究, 2020, 36(5): 865-869.
[2]	ZHAO Qi, LIANG Xiaoxiao, YOU Yingxue, WANG Yuliang, DU Xinwei, LIU Baijun, HU Wei. Proton Conductivity Improvement Effect of Cellulose on SPEEKK Based PEM[J]. 高等学校化学研究, 2019, 35(5): 916-923.
[3]	GUO Donggang, NI Liang, WANG Liang, SHAO Li. Separation/Extraction/Detection of Chloramphenicol Using Binary Small Molecule Alcohol-Salt Aqueous Two-phase System Coupled with High-performance Liquid Chromatography[J]. 高等学校化学研究, 2019, 35(2): 209-215.
[4]	GUAN Lianyue, LUO Qiang, LIANG Na, YU Wei. Determination of Lignans in Schisandra sphenanthera and Schisandra chinensis Using Ionic Liquid-based Ultrasonic-assisted Extraction and High-performance Liquid Chromatography[J]. 高等学校化学研究, 2018, 34(6): 887-892.
[5]	CHEN Siyan, GAO Zhenhai. Structure of a Mixture of Graphene Plates and Ionic Liquid 1-Octyl-3-methylimidazolium Hexafluoroborate[J]. 高等学校化学研究, 2018, 34(4): 598-603.
[6]	XU Chao, YIN Xuhan, ZHANG Chuan, CHEN Hongyue, HUANG He, HU Yi. Improving Catalytic Performance of Burkholderiacepacia Lipase by Chemical Modification with Functional Ionic Liquids[J]. 高等学校化学研究, 2018, 34(2): 279-284.
[7]	WANG Jingyang, ZHANG Meng, XU Xiaodong, FENG Jing, WANG Yanli, ZHANG Milin, HAN Wei, CHEN Yitung, TIAN Guoxin. Synthesis and Characterization of [Cu(N-MeIm)₄(BF₄)₂] in Ionic Liquid[J]. 高等学校化学研究, 2018, 34(1): 8-12.
[8]	Ana Maria POPESCU, Kazimir YANUSHKEVICH, Vasile SOARE, Cristina DONATH, Elena Ionela NEACSU, Virgil CONSTANTIN. Recovery of Metals from Anodic Dissolution Slime of Waste from Electric and Electronic Equipment(WEEE) by Extraction in Ionic Liquids[J]. 高等学校化学研究, 2018, 34(1): 113-118.
[9]	BU Luxia, LIU Daying, WEI Zhen, MA Zhanlin. Physicochemical Properties of Bi-containing Ionic Liquid Analogs Based on Choline Chloride[J]. 高等学校化学研究, 2017, 33(6): 929-933.
[10]	TONG Jing, ZHENG Xu, TONG Jian, QU Ye, LIU Lu, LI Hui. Molar Surface Gibbs Energy of the Aqueous Solution of Ionic Liquid[C₄mim] [OAc][J]. 高等学校化学研究, 2017, 33(5): 828-832.
[11]	ZHANG Lifeng, DU Suqing, SONG Qiaolan, LIU Yi, GUO Shouwu. Fluorine-free Ionic Liquid Based on Thiocyanate Anion with Propylene Carbonate as Electrolytes for Supercapacitors:Effects of Concentration and Temperature[J]. 高等学校化学研究, 2017, 33(5): 779-784.
[12]	BIAN Min, TIAN Ling, YAO Cheng. An Improved Method of Simultaneous Determination of Four Bioactive Compounds in Evodiae Fructus Using Ionic Liquids as Mobile Phase Additives in High Performance Liquid Chromatography[J]. 高等学校化学研究, 2017, 33(4): 552-558.
[13]	GAO Shenghan, GAO Ruichang. Antibacterial Cellulose Composite Membranes Prepared in Ionic Liquid via Phase Inversion Method[J]. 高等学校化学研究, 2017, 33(4): 678-683.
[14]	LIU Lihong, WANG Chunfeng, ZHUO Kelei. Cetyltrimethylammonium Bromide(CTAB)-Ionic Liquid Composite Modified Electrode for Sensitive Cyclic Voltammetric Determination of Bisphenol A[J]. 高等学校化学研究, 2016, 32(6): 992-995.
[15]	ZHU Jian, JIN Zhimin. Efficient Purification of Camptothecin via Aqueous Two-phase System Composed of 1,1,3,3-Tetramethylguanidinium Benzoate Ionic Liquid and K₂CO₃[J]. 高等学校化学研究, 2016, 32(4): 630-633.