Hydrothermal Synthesis and Magnetic Properties ofSmCr0.5M0.5O3(M=Fe and Mn) Micro-plates

doi:10.1007/s40242-017-7334-0

高等学校化学研究 ›› 2018, Vol. 34 ›› Issue (1): 1-7.doi: 10.1007/s40242-017-7334-0

Hydrothermal Synthesis and Magnetic Properties ofSmCr_0.5M_0.5O₃(M=Fe and Mn) Micro-plates

ZHANG Jiaqi¹, WANG Shan², YUAN Long¹, HOU Changmin¹

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Department of Materials Science and Engineering, Jilin Institute of Chemical Technology, Jilin 132022, P. R. China

收稿日期:2017-10-24 出版日期:2018-02-01 发布日期:2018-01-20
通讯作者: HOU Changmin,E-mail:houcm@jlu.edu.cn E-mail:houcm@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21427802), the “Twelfth Five Year” Project of Science and Technology Research in the Education Department of Jilin Province, China(No.2015-466) and the Natural Science Fund of Jilin Provincial Science & Technology Department, China(No.20160101326JC).

Hydrothermal Synthesis and Magnetic Properties ofSmCr_0.5M_0.5O₃(M=Fe and Mn) Micro-plates

ZHANG Jiaqi¹, WANG Shan², YUAN Long¹, HOU Changmin¹

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Department of Materials Science and Engineering, Jilin Institute of Chemical Technology, Jilin 132022, P. R. China

Received:2017-10-24 Online:2018-02-01 Published:2018-01-20
Contact: HOU Changmin,E-mail:houcm@jlu.edu.cn E-mail:houcm@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21427802), the “Twelfth Five Year” Project of Science and Technology Research in the Education Department of Jilin Province, China(No.2015-466) and the Natural Science Fund of Jilin Provincial Science & Technology Department, China(No.20160101326JC).

摘要/Abstract

摘要： Nanostructured B-site Fe and Mn doped SmCrO₃ was prepared by mild hydrothermal growth. The as-prepared crystals are mainly micrometer-scale plates, ranging from rhombus(SmCr_0.5Fe_0.5O₃) to elongated he- xagonal(SmCr_0.5Mn_0.5O₃), and finally to well-edged rectangular(SmCr_0.17Mn_0.5Fe_0.33O₃) plates. Fe and Mn doped SmCrO₃ crystals are indexed into Pbnm space group. The cell parameters of SmCr_0.5Fe_0.5O₃ are slightly smaller than that of pristine SmCrO₃. Binding energy analysis of Cr, Mn and Fe in SmCr_0.17Mn_0.5Fe_0.33O₃ sample indicates that they all possess +3 oxidation states. Temperature dependent magnetization of the as-prepared samples presents obviously stronger ferromagnetic interactions than the undoped counterparts. This work represents a remarkable development for hydrothermal synthesis into fabricating perovskite oxide crystals with uniform distribution of doping ions.

关键词: Hydrothermal synthesis, Perovskite structure, B-Site ordering, Magnetic property

Abstract: Nanostructured B-site Fe and Mn doped SmCrO₃ was prepared by mild hydrothermal growth. The as-prepared crystals are mainly micrometer-scale plates, ranging from rhombus(SmCr_0.5Fe_0.5O₃) to elongated he- xagonal(SmCr_0.5Mn_0.5O₃), and finally to well-edged rectangular(SmCr_0.17Mn_0.5Fe_0.33O₃) plates. Fe and Mn doped SmCrO₃ crystals are indexed into Pbnm space group. The cell parameters of SmCr_0.5Fe_0.5O₃ are slightly smaller than that of pristine SmCrO₃. Binding energy analysis of Cr, Mn and Fe in SmCr_0.17Mn_0.5Fe_0.33O₃ sample indicates that they all possess +3 oxidation states. Temperature dependent magnetization of the as-prepared samples presents obviously stronger ferromagnetic interactions than the undoped counterparts. This work represents a remarkable development for hydrothermal synthesis into fabricating perovskite oxide crystals with uniform distribution of doping ions.

Key words: Hydrothermal synthesis, Perovskite structure, B-Site ordering, Magnetic property

ZHANG Jiaqi, WANG Shan, YUAN Long, HOU Changmin. Hydrothermal Synthesis and Magnetic Properties ofSmCr_0.5M_0.5O₃(M=Fe and Mn) Micro-plates[J]. 高等学校化学研究, 2018, 34(1): 1-7.

ZHANG Jiaqi, WANG Shan, YUAN Long, HOU Changmin. Hydrothermal Synthesis and Magnetic Properties ofSmCr_0.5M_0.5O₃(M=Fe and Mn) Micro-plates[J]. Chemical Research in Chinese Universities, 2018, 34(1): 1-7.

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Hydrothermal Synthesis and Magnetic Properties ofSmCr_0.5M_0.5O₃(M=Fe and Mn) Micro-plates

Hydrothermal Synthesis and Magnetic Properties ofSmCr_0.5M_0.5O₃(M=Fe and Mn) Micro-plates

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