A Novel 3D Metal Organic Framework Based on an Azolate Ligand

doi:10.1007/s40242-014-3501-8

高等学校化学研究 ›› 2014, Vol. 30 ›› Issue (1): 1-3.doi: 10.1007/s40242-014-3501-8

A Novel 3D Metal Organic Framework Based on an Azolate Ligand

YIN Xinbo, AN Tiance, WANG Yang, ZHANG Lijuan

Laboratory of Advanced Materials, Fudan University, Shanghai 200438, P. R. China

收稿日期:2013-11-15 修回日期:2013-12-31 出版日期:2014-02-01 发布日期:2014-01-13
通讯作者: ZHANG Lijuan,E-mail:zhanglijuan@fudan.edu.cn E-mail:zhanglijuan@fudan.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21071032).

A Novel 3D Metal Organic Framework Based on an Azolate Ligand

YIN Xinbo, AN Tiance, WANG Yang, ZHANG Lijuan

Laboratory of Advanced Materials, Fudan University, Shanghai 200438, P. R. China

Received:2013-11-15 Revised:2013-12-31 Online:2014-02-01 Published:2014-01-13
Contact: ZHANG Lijuan,E-mail:zhanglijuan@fudan.edu.cn E-mail:zhanglijuan@fudan.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21071032).

摘要/Abstract

摘要：

Metal organic frameworks (MOFs) constructed from metal ions and organic ligands have been investigated greatly due to the variety of the MOF structures. Azolate type ligands are used frequently to synthesize MOFs to make zeolitic imidazolate frameworks (ZIFs) with high stabilities. We synthesize a 3D MOF {[Zn(BBI)(MSM)(DMSO)]n, H2BBI = benzo-bis (imidazole), MSM = methylsulfonylmethane, DMSO = dimethyl sulfoxide}, constructed from tetrahedral Zn(II) and four-coordinated BBI ligand, with 11.27 ? 1D pore size. In this framework, considering Zn(II) as the vertex, and the BBI together MSM as the edge, dmp topology is obtained.

关键词: Metal-organic framework, Azolate ligand, Porosity, dmp Topology

Abstract:

Key words: Metal-organic framework, Azolate ligand, Porosity, dmp Topology

YIN Xinbo, AN Tiance, WANG Yang, ZHANG Lijuan. A Novel 3D Metal Organic Framework Based on an Azolate Ligand[J]. 高等学校化学研究, 2014, 30(1): 1-3.

YIN Xinbo, AN Tiance, WANG Yang, ZHANG Lijuan. A Novel 3D Metal Organic Framework Based on an Azolate Ligand[J]. Chemical Research in Chinese Universities, 2014, 30(1): 1-3.

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A Novel 3D Metal Organic Framework Based on an Azolate Ligand

A Novel 3D Metal Organic Framework Based on an Azolate Ligand

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