Solvothermal Synthesis, Structural Characterization and Properties of Two New Layered Lanthanide Sulfates

doi:10.1007/s40242-013-3060-4

高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (5): 831-836.doi: 10.1007/s40242-013-3060-4

Solvothermal Synthesis, Structural Characterization and Properties of Two New Layered Lanthanide Sulfates

LÜ Yun, ZHANG Deng, XU Yan

State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, P. R. China

收稿日期:2013-02-04 修回日期:2013-03-11 出版日期:2013-10-01 发布日期:2013-09-17
通讯作者: XU Yan E-mail:yanxu@njut.edu.cn
基金资助:
Supported by the Natural Science Foundation of Jiangsu Province, China(No.BK2012823) and the Ph. D. Programs Fundation of Ministry of Education of China(No.20113221120002).

Solvothermal Synthesis, Structural Characterization and Properties of Two New Layered Lanthanide Sulfates

LÜ Yun, ZHANG Deng, XU Yan

State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, P. R. China

Received:2013-02-04 Revised:2013-03-11 Online:2013-10-01 Published:2013-09-17
Contact: XU Yan E-mail:yanxu@njut.edu.cn
Supported by:
Supported by the Natural Science Foundation of Jiangsu Province, China(No.BK2012823) and the Ph. D. Programs Fundation of Ministry of Education of China(No.20113221120002).

摘要/Abstract

摘要：

Two new layered lanthanide sulfates,[C₁₀H₁₀N₂][Pr₂(SO₄)₄(H₂O)₂](1)and[H₅O₂][Sm(SO₄)₂(H₂O)₃](2)were synthesized via solvothermal reaction and structurally characterized by single-crystal X-ray diffraction(XRD), infrared(IR) spectroscopy, thermal analysis, fluorescent spectra and inductively coupled plasma(ICP). Crystal data for compound 1, triclinic, P space group, a=0.8052(4) nm, b=0.9438(4) nm, c=1.4990(7) nm, α=79.450(5)°, β= 83.703(5)°, γ=74.048(5)°, V=1.0746(9) nm³, Z=2; for compound 2, monoclinic, P2₁/c space group, a=0.6599(11) nm, b=1.8940(3) nm, c=0.8765(14) nm, β=96.596(2)°, V=1.0883(3) nm³, Z=4. Structure analysis indicates that both the compounds exhibit a 2D corrugated layer structure, with protonated 4,4'-bipyridine cations and water dimmers (H₅O₂)⁺ located between the inorganic layers of compounds 1 and 2, respectively. Luminescent properties of compounds 1 and 2 were further investigated.

关键词: Solvothermal synthesis, Open-framework, Lanthanide sulfate, Layered structure, Luminescence

Abstract:

Key words: Solvothermal synthesis, Open-framework, Lanthanide sulfate, Layered structure, Luminescence

LÜ Yun, ZHANG Deng, XU Yan. Solvothermal Synthesis, Structural Characterization and Properties of Two New Layered Lanthanide Sulfates[J]. 高等学校化学研究, 2013, 29(5): 831-836.

LÜ Yun, ZHANG Deng, XU Yan. Solvothermal Synthesis, Structural Characterization and Properties of Two New Layered Lanthanide Sulfates[J]. Chemical Research in Chinese Universities, 2013, 29(5): 831-836.

参考文献

[1] Wang B., Cote A. P., Furukawa H., O'Keeffe M., Yaghi O. M., Nature, 2008, 453, 207
[2] Liu Y., Xu X., Zheng F. K., Cui Y., Angew. Chem. Int. Ed., 2008, 47, 4538
[3] Zhang J. P., Chen X. M., J. Am. Chem. Soc., 2009, 131, 5516
[4] Zeng Y. F., Hu X., Liu F. C., Bu X. H., Chem. Soc. Rev., 2009, 38, 469
[5] Eddaoudi M., Kim J., Rosi J., Vodak N., Wachter D., O'Keeffe M.,Yaghi O. M., Science, 2002, 295, 469
[6] Zhang D., Fan X. R., Lu Y., Xu Y., Chem. Res. Chinese Universities, 2013, 29(1), 10
[7] Gutschke S. O. H. V., Price D. J., Powell A. K., Wood P. T., Angew. Chem. Int. Ed., 2001, 40, 1920
[8] Robinson F., Zaworotko M. J., Chem. Commun., 1995, 23, 2413
[9] Yaghi O. M., Li H., J. Am. Chem. Soc., 1996, 118, 295
[10] Seo J. S., Whang D., Lee H., Jun S. I., Oh J., Jeon Y. J., Kim K., Nature, 2000, 404, 982
[11] Zheng L., Qiu X. M., Zhang Z. B., Zhu D. R., Xu Y., Inorg. Chem. Commun., 2011, 14, 906
[12] Li H., Zhu Y. L., Zheng L., Xu Y., Chin. J. Inorg. Chem., 2011, 12,2453
[13] Zhou W. L., Xu Y., Chin. J. Inorg. Chem., 2011, 12,2507
[14] Zheng L., Xu Y., Zhang X. L., Zhang Z. B., Zhu D. R., Chen S., Elangovan S. P., CrystEngComm, 2010, 12, 694
[15] Zhou W. L., Ding X. R., Zhang Z. B., Xu Y., Zhu D. R., Z. Anorg. Allg. Chem., 2009, 636, 882
[16] Xu Y., Ding S., Zheng X., J. Solid State Chem., 2007, 180, 2020
[17] Zhang Q., Lu C., Yang W., Chen S., Yu Y., Inorg. Chem. Commun., 2004, 7, 889
[18] Zhang D., Lu Y., Zhu D. R., Xu Y., Inorg. Chem., 2013, 6, 3253
[19] Xing Y., Liu Y., Shi Z., Meng H., Pang W., J. Solid State Chem., 2003, 174, 381
[20] Ju W. W., Zhang D., Zhu D. R., Xu Y., Inorg. Chem., 2012, 51, 13373
[21] Zhu Y. L., Sun X. C., Zhu D. R., Xu Y., Inorganica Chimica Acta, 2009, 362, 2565
[22] Zhou W. L., Chen Q., Zhu D. R., Xu Y., Z. Anorg. Allg. Chem., 2009, 635, 572
[23] Zhou W. L., Chen Q., Jiang N., Meng X., Zhu D. R., Xu Y., Inorg. Chim. Acta, 2009,362, 3299
[24] Zhou W. L., Xu Y., Han L. J., Zhu D. R., Dalton Trans., 2010,39, 3681
[25] Zhang D., Lu Y., Chen L., Xu Y., CrystEngComm, 2012, 14, 6627
[26] Ge G. W., Liu M. P., Ni Z. G., Du H. B., Chem. J. Chinese Universities, 2011, 32(3), 644
[27] Zhang D., Zheng L., Qiu X. M., Xu Y., Fu J., Zhu D. R., RSC Advances, 2012, 2, 217
[28] Fu J., Zheng L.,Yuan Y., Song Y., Xu Y., J. Chem. Crystallogr., 2011, 41, 1737
[29] Yotnoi B., Rujiwatra A., Reddy M., Sarma D., Natarajan S., Cryst. Growth Des., 2011,11, 1347
[30] Sheldrick G. M., SHELXTL Version 5.10, Bruker AXS Inc., Madsion, 1997
[31] Keutsch F. N., Saykally R. J., PNAS, 2001, 98, 10533
[32] Dyke T. R., Mack K. M., Muenter J. S., J. Chem. Phys., 1977, 66, 498
[33] Madhab C. D., Shubhra B. M., Parimal K. B., Current Opinion in Solid State and Materials Science, 2009, 13, 76
[34] Zhang Z. B., Xu Y., Zheng L., Zhu D. R., Song Y., CrystEngComm, 2011, 13, 2191

Solvothermal Synthesis, Structural Characterization and Properties of Two New Layered Lanthanide Sulfates

Solvothermal Synthesis, Structural Characterization and Properties of Two New Layered Lanthanide Sulfates

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