Synthesis and Characterization of Layered Co2(OH)3(CH3COO)?H2O

高等学校化学研究 ›› 2011, Vol. 27 ›› Issue (6): 910-914.

Synthesis and Characterization of Layered Co2(OH)3(CH3COO)?H2O

ZHENG De-shan^1,2*, WANG Yan-zhong¹, SHI Li-min¹ and SUN Si-xiu²

1. School of Materials and Chemical Engineering, Xi'an Technological University, Xi'an 710032, P. R. China;
2. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, P. R. China

收稿日期:2010-12-30 修回日期:2011-05-19 出版日期:2011-11-25 发布日期:2011-11-07
通讯作者: ZHENG De-shan E-mail:deshan.zheng@sdu.edu.cn
基金资助:
Supported by the President Fund of Xi'an Technological University, China(No.XAGDXJJ1009).

Synthesis and Characterization of Layered Co2(OH)3(CH3COO)?H2O

ZHENG De-shan^1,2*, WANG Yan-zhong¹, SHI Li-min¹ and SUN Si-xiu²

1. School of Materials and Chemical Engineering, Xi'an Technological University, Xi'an 710032, P. R. China;
2. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, P. R. China

Received:2010-12-30 Revised:2011-05-19 Online:2011-11-25 Published:2011-11-07
Contact: ZHENG De-shan E-mail:deshan.zheng@sdu.edu.cn
Supported by:
Supported by the President Fund of Xi'an Technological University, China(No.XAGDXJJ1009).

摘要/Abstract

摘要： Layered hydroxide metal acetate Co2(OH)3(CH3COO)?H2O with an interlayer spacing of 1.282 nm has been synthesized by a novel method which is employed in ethanol-aqueous mixed solvents media. Experiment results show that the purity of the product by the modified method is higher compared with that by the previous methods. A complete characterization of the as-prepared samples was performed by means of X-ray powder diffraction, IR spectroscopy, scanning electron microscope, as well as magnetic measurement. The facile and effective approach for the preparation of this compound in this study is very interesting and important because it has wide application in the field of anionic exchange reaction for the synthesis of hybrid organic-inorganic compounds.

关键词: Anionic exchange reaction, Hybrid organic-inorganic compound, Layered hydroxide cobalt acetate, Magnetic property

Abstract: Layered hydroxide metal acetate Co2(OH)3(CH3COO)?H2O with an interlayer spacing of 1.282 nm has been synthesized by a novel method which is employed in ethanol-aqueous mixed solvents media. Experiment results show that the purity of the product by the modified method is higher compared with that by the previous methods. A complete characterization of the as-prepared samples was performed by means of X-ray powder diffraction, IR spectroscopy, scanning electron microscope, as well as magnetic measurement. The facile and effective approach for the preparation of this compound in this study is very interesting and important because it has wide application in the field of anionic exchange reaction for the synthesis of hybrid organic-inorganic compounds.

Key words: Anionic exchange reaction, Hybrid organic-inorganic compound, Layered hydroxide cobalt acetate, Magnetic property

ZHENG De-shan*, WANG Yan-zhong, SHI Li-min and SUN Si-xiu. Synthesis and Characterization of Layered Co2(OH)3(CH3COO)?H2O[J]. 高等学校化学研究, 2011, 27(6): 910-914.

ZHENG De-shan*, WANG Yan-zhong, SHI Li-min and SUN Si-xiu. Synthesis and Characterization of Layered Co2(OH)3(CH3COO)?H2O[J]. Chemical Research in Chinese Universities, 2011, 27(6): 910-914.

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Synthesis and Characterization of Layered Co2(OH)3(CH3COO)?H2O

Synthesis and Characterization of Layered Co2(OH)3(CH3COO)?H2O

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