[an error occurred while processing this directive]

高等学校化学研究 ›› 2011, Vol. 27 ›› Issue (6): 915-918.

• Articles • 上一篇    下一篇

Solvothermal Synthesis and Characterization of Sheet Structure Containing Adamantane [Hg2Sn2S10]8– Anions

BAIYIN Meng-he1,2*, LIANG Feng-ying1, XU Xiao-qing1, TA Na1, NA Mi-la1, BAI Wu-yun1 and BAO Yong-sheng1   

  1. 1. College of Chemistry and Environmental Science,
    2. Inner Mongolian Key Laboratory for Physics and Chemistry of Functional Materials, Inner Mongolia Normal University, Huhhot 010022, P. R. China
  • 收稿日期:2010-12-15 修回日期:2011-04-29 出版日期:2011-11-25 发布日期:2011-11-07
  • 通讯作者: BAIYIN Meng-he E-mail:baiymh@imnu.edu.cn
  • 基金资助:

    Supported by the Natural Science Foundations of Inner Mongolia of China(No.20080404MS0212) and the Universities Scientific Research Foundations of Inner Mongolia of China(No.NJZY07034).

Solvothermal Synthesis and Characterization of Sheet Structure Containing Adamantane [Hg2Sn2S10]8– Anions

BAIYIN Meng-he1,2*, LIANG Feng-ying1, XU Xiao-qing1, TA Na1, NA Mi-la1, BAI Wu-yun1 and BAO Yong-sheng1   

  1. 1. College of Chemistry and Environmental Science,
    2. Inner Mongolian Key Laboratory for Physics and Chemistry of Functional Materials, Inner Mongolia Normal University, Huhhot 010022, P. R. China
  • Received:2010-12-15 Revised:2011-04-29 Online:2011-11-25 Published:2011-11-07
  • Contact: BAIYIN Meng-he E-mail:baiymh@imnu.edu.cn
  • Supported by:

    Supported by the Natural Science Foundations of Inner Mongolia of China(No.20080404MS0212) and the Universities Scientific Research Foundations of Inner Mongolia of China(No.NJZY07034).

PDF (PC)

摘要： Sheet Rb2HgSnS4 was synthesized solvothermally and characterized by X-ray single crystal diffraction. The compound is comprised of sheets with admantane-like [Hg2Sn2S10]8– units. The crystals belong to the space group C2/c, with the unit cell parameters a=1.1063(2) nm, b=1.1071(2) nm, c=1.5741(3) nm, a=90°, β=100.13(3)°, γ=90°. A reflectance spectroscopy study reveals the nature of the semiconductor with an energy of 2.1 eV for the compound.

关键词: Solvothermal synthesis, Quaternary thiostannate, Sheet structure

Abstract: Sheet Rb2HgSnS4 was synthesized solvothermally and characterized by X-ray single crystal diffraction. The compound is comprised of sheets with admantane-like [Hg2Sn2S10]8– units. The crystals belong to the space group C2/c, with the unit cell parameters a=1.1063(2) nm, b=1.1071(2) nm, c=1.5741(3) nm, a=90°, β=100.13(3)°, γ=90°. A reflectance spectroscopy study reveals the nature of the semiconductor with an energy of 2.1 eV for the compound.

Key words: Solvothermal synthesis, Quaternary thiostannate, Sheet structure