Studies on Synthesis, Structure and Properties of Cobalt Complex [Co(Ⅰ) (dppe)2CO]2[Co2(Ⅱ) (dppe)Cl6O2]

高等学校化学研究 ›› 1993, Vol. 9 ›› Issue (2): 99-103.

Studies on Synthesis, Structure and Properties of Cobalt Complex [Co(Ⅰ) (dppe)₂CO]₂[Co₂(Ⅱ) (dppe)Cl₆O₂]

WANG Tao, FAN Yu-guo

Institute of Theoretical Chemistry, Jilin University, Changchun, 130023

收稿日期:1992-03-26 出版日期:1993-04-24 发布日期:2011-08-17

Studies on Synthesis, Structure and Properties of Cobalt Complex [Co(Ⅰ) (dppe)₂CO]₂[Co₂(Ⅱ) (dppe)Cl₆O₂]

WANG Tao, FAN Yu-guo

Institute of Theoretical Chemistry, Jilin University, Changchun, 130023

Received:1992-03-26 Online:1993-04-24 Published:2011-08-17

摘要/Abstract

摘要： Acobalt complex with mixed valence state [Co(Ⅰ) (dppe)₂CO]₂ [Co₂ (Ⅱ)(dppe) Cl]₆O₂] (dppe=1,2 -bis(diphenylphosphino) ethane) has been prepared. The compound crystallizes in triclinic space group P1 with unit cell parameters: a=1.1763(3)nm, b=1.2943(6)nm, c=2.1507(9)nm, a=81.44(4)°,β=82.58(3)°, r=79.82(3)°, V=3.1691nm³ and Z=1. The structure was solved by direct method according to ALPHAcriterion and was refined by a block diagonal matrix least-squares procedure to final R= 0.084, Moreover, infared spectra, electronic reflection spectra and cyclic voltammetry curve were mearsured.

关键词: Cobalt, Synthesis, Structure and properties

Abstract: Acobalt complex with mixed valence state [Co(Ⅰ) (dppe)₂CO]₂ [Co₂ (Ⅱ)(dppe) Cl]₆O₂] (dppe=1,2 -bis(diphenylphosphino) ethane) has been prepared. The compound crystallizes in triclinic space group P1 with unit cell parameters: a=1.1763(3)nm, b=1.2943(6)nm, c=2.1507(9)nm, a=81.44(4)°,β=82.58(3)°, r=79.82(3)°, V=3.1691nm³ and Z=1. The structure was solved by direct method according to ALPHAcriterion and was refined by a block diagonal matrix least-squares procedure to final R= 0.084, Moreover, infared spectra, electronic reflection spectra and cyclic voltammetry curve were mearsured.

Key words: Cobalt, Synthesis, Structure and properties

WANG Tao, FAN Yu-guo . Studies on Synthesis, Structure and Properties of Cobalt Complex [Co(Ⅰ) (dppe)₂CO]₂[Co₂(Ⅱ) (dppe)Cl₆O₂][J]. 高等学校化学研究, 1993, 9(2): 99-103.

WANG Tao, FAN Yu-guo . Studies on Synthesis, Structure and Properties of Cobalt Complex [Co(Ⅰ) (dppe)₂CO]₂[Co₂(Ⅱ) (dppe)Cl₆O₂][J]. Chemical Research in Chinese Universities, 1993, 9(2): 99-103.

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Studies on Synthesis, Structure and Properties of Cobalt Complex [Co(Ⅰ) (dppe)₂CO]₂[Co₂(Ⅱ) (dppe)Cl₆O₂]

Studies on Synthesis, Structure and Properties of Cobalt Complex [Co(Ⅰ) (dppe)₂CO]₂[Co₂(Ⅱ) (dppe)Cl₆O₂]

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