Syntheses and Characterization of ZSM-5 Zeolites Containing Diethylamine and Ethylenediamine

高等学校化学研究 ›› 1993, Vol. 9 ›› Issue (2): 95-98.

• Articles • 下一篇

Syntheses and Characterization of ZSM-5 Zeolites Containing Diethylamine and Ethylenediamine

ZHAO Da-qing, QIU Shi-lun, PANG Wen-qin

Department of Chemistry, Jilin University, Changchun, 130023

收稿日期:1992-03-20 出版日期:1993-04-24 发布日期:2011-08-17

Syntheses and Characterization of ZSM-5 Zeolites Containing Diethylamine and Ethylenediamine

ZHAO Da-qing, QIU Shi-lun, PANG Wen-qin

Department of Chemistry, Jilin University, Changchun, 130023

Received:1992-03-20 Online:1993-04-24 Published:2011-08-17

摘要/Abstract

摘要： Syntheses of ZSM-5 zeolites from R-SiO₂-Al₂O₃-H₂O-HF(R = diethylamine and ethylenediamine, respectively) were investigated by using the hydrothermal crystallization. The large single crystals of ZSM-5 containing diethylamine and ethylenediamine were synthesized. The ZSM-5 precursors were characterized by means of X-ray powder diffraction, scanning electron microscopy, thermal analysis and electron microprobe analysis. The analysis result of aluminium distribution shows that the interior aluminium content of large crystals of ZSM-5 zeolites is rather low.

关键词: ZSM-5, Hydrothermal crystallization, Template, Aluminium distribution

Abstract: Syntheses of ZSM-5 zeolites from R-SiO₂-Al₂O₃-H₂O-HF(R = diethylamine and ethylenediamine, respectively) were investigated by using the hydrothermal crystallization. The large single crystals of ZSM-5 containing diethylamine and ethylenediamine were synthesized. The ZSM-5 precursors were characterized by means of X-ray powder diffraction, scanning electron microscopy, thermal analysis and electron microprobe analysis. The analysis result of aluminium distribution shows that the interior aluminium content of large crystals of ZSM-5 zeolites is rather low.

Key words: ZSM-5, Hydrothermal crystallization, Template, Aluminium distribution

ZHAO Da-qing, QIU Shi-lun, PANG Wen-qin . Syntheses and Characterization of ZSM-5 Zeolites Containing Diethylamine and Ethylenediamine[J]. 高等学校化学研究, 1993, 9(2): 95-98.

ZHAO Da-qing, QIU Shi-lun, PANG Wen-qin . Syntheses and Characterization of ZSM-5 Zeolites Containing Diethylamine and Ethylenediamine[J]. Chemical Research in Chinese Universities, 1993, 9(2): 95-98.

[1]	XIAO Peiwen, LI Hui, WANG Pingmei, LIU Bolun, JING Wendan, HE Lipeng, WANG Runwei, HAN Xue, ZHANG Zongtao, QIU Shilun, LUO Jianhui. Functionalized Hierarchical ZSM-5 Zeolites for the Viscosity Reduction of Heavy Oil at Low Temperature[J]. 高等学校化学研究, 2022, 38(4): 1083-1088.
[2]	LI Jun, RONG Huazhen, CHEN Cong, LI Ziyi, ZUO Jiayu, WANG Wenjian, LIU Xinjian, GUAN Yixing, YANG Xiong, LIU Yingshu, ZOU Xiaoqin, ZHU Guangshan. Synthesis Optimization of SSZ-13 Zeolite Membranes by Dual Templates for N₂/NO₂ Separation[J]. 高等学校化学研究, 2022, 38(1): 250-256.
[3]	LUO Li, WANG Sen, WU Zhiwei, QIN Zhangfeng, DONG Mei, WANG Jianguo, FAN Weibin. Influence of the ZSM-5 Support Acidity on the Catalytic Performance of Pd/ZSM-5 in Lean Methane Oxidation[J]. 高等学校化学研究, 2022, 38(1): 229-236.
[4]	DENG Tianyin, HE Xiaohui, LIU Haichao. Insights into the Active Acid Sites for Isosorbide Synthesis from Renewable Sorbitol and Cellulose on Solid Acid Catalysts[J]. 高等学校化学研究, 2022, 38(1): 257-264.
[5]	ZHU Jinjin, SHANG Yingxu, YU Haiyin, LI Na, DING Baoquan. Shape-controllable Synthesis of Functional Nanomaterials on DNA Templates[J]. 高等学校化学研究, 2020, 36(2): 171-176.
[6]	LIN Xinchen, XIE Feng, YU Xiaodan, TANG Xin, GUAN Heda, CHEN Yu, FENG Wei. Ultraviolet Light Assisted Hierarchical Porous Fe₂O₃ Catalyzing Heterogeneous Fenton Degradation of Tetracycline Under Neutral Condition with a Low Requirement of H₂O₂[J]. 高等学校化学研究, 2019, 35(2): 304-310.
[7]	XIA Qi, PAN Shaofeng, ZHANG Yi, AN Qi, ZHANG Qian, ZHANG Yihe. Preparation of Highly Loaded PAA/PAH Layer-by-layer Films by Combining Acid Transformation and Templating Methods[J]. 高等学校化学研究, 2019, 35(2): 353-358.
[8]	MENG Qingling, XIE Chenchen, DING Ran, CAO Liang, MA Ke, LI Li, WENG Zhankun and WANG Zuobin. Bio-template Synthesis of Spirulina/α-Fe₂O₃ Composite with Improved Surface Wettability[J]. 高等学校化学研究, 2018, 34(6): 1058-1062.
[9]	YI Ting, LI Jingwei, ZHANG Yibo, YANG Xiangguang. A Novel Nano-sized Catalyst CeO₂-CuO/Hollow ZSM-5 for NO_x Reduction with NH₃[J]. 高等学校化学研究, 2018, 34(4): 661-664.
[10]	LIU Xiaofang, ZENG Shangjing, WANG Runwei, ZHANG Zongtao, QIU Shilun. Sustainable Synthesis of Hierarchically Porous Silicalite-1 Zeolite by Steam-assisted Crystallization of Solid Raw Materials Without Secondary Templates[J]. 高等学校化学研究, 2018, 34(3): 350-357.
[11]	YU Xue, ZHANG Yuewei, LIU Bing, MA Huiyong, WANG Yan, BAO Qiang, WANG Zhenlü. Effect of Phosphoric Acid on HZSM-5 Catalysts for Prins Condensation to Isoprene from Isobutylene and Formaldehyde[J]. 高等学校化学研究, 2018, 34(3): 485-489.
[12]	DONG Lei, LIU Huan, LI Yanjuan, ZHANG Hongtao, YU Liangmin, JIA Lanni. Template Effect of Hydrophobically Associating Polymers on theConstruction of Cuprous Oxide Micro Structure[J]. 高等学校化学研究, 2018, 34(1): 138-144.
[13]	JI Yanyan, ZHANG Bing, ZHANG Wu, ZHAO Bo, LI Hongbo, WANG Dongmei, LI Ying. High-efficient Synthesis of Zeolite LTA via a Wet-gel Crystallization Route[J]. 高等学校化学研究, 2017, 33(4): 520-524.
[14]	WANG Xiaodong, HUANG Yujiao, ZHANG Xiaoxiao, FENG Xianshe, HUANG Wei. Synthesis of Hydrophilic Acid-resistant Ge-ZSM-5 Membranes via Secondary Growth Method Using Silicalite-1 Zeolite as Seeds[J]. 高等学校化学研究, 2017, 33(1): 12-16.
[15]	JIA Yongchang, WANG Shuyuan, LU Jiqing, LUO Mengfei. Effect of Structural Properties of Mesoporous Co₃O₄ Catalysts on Methane Combustion[J]. 高等学校化学研究, 2016, 32(5): 808-811.

Syntheses and Characterization of ZSM-5 Zeolites Containing Diethylamine and Ethylenediamine

Syntheses and Characterization of ZSM-5 Zeolites Containing Diethylamine and Ethylenediamine

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价