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高等学校化学研究 ›› 2003, Vol. 19 ›› Issue (1): 120-126.

• Articles • 上一篇    

Preparation of Nano-porous Materials(Ⅱ) by Cross-linking of Amphiphilic Self-assemblies

YU Jiong2, YUE Dong-mei1, ZHANG Qiang1, ZHANG Li-qun1   

  1. 1. College of Material Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China;

    2. Case Western Reserve University, Cleveland OH. 441064, USA
  • 收稿日期:2001-10-22 出版日期:2003-01-24 发布日期:2011-08-06
  • 基金资助:

    Supported by National Natural Science Foundation of China(No.05173003), Beijing Science and Technology New Star Program(No.H010410010112) and Important Natural Science Foundation of Beijing(No.2031001).

Preparation of Nano-porous Materials(Ⅱ) by Cross-linking of Amphiphilic Self-assemblies

YU Jiong2, YUE Dong-mei1, ZHANG Qiang1, ZHANG Li-qun1   

  1. 1. College of Material Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China;

    2. Case Western Reserve University, Cleveland OH. 441064, USA
  • Received:2001-10-22 Online:2003-01-24 Published:2011-08-06
  • Supported by:

    Supported by National Natural Science Foundation of China(No.05173003), Beijing Science and Technology New Star Program(No.H010410010112) and Important Natural Science Foundation of Beijing(No.2031001).

摘要: Amphiphilic block copolymers can exhibit rich and complex morphologies in aqueous solutions, but these structures are usually delicate, easily disturbed by composition change or temperature change. In this work, the use of different methods to cross-link block copolymer self-assemblies in the presence of a selective solvent and to stabilize the structures is reviewed. In addition, the cross-linking reaction kinetics of block copolymer amphiphilic self-assemblies is briefly discussed.

关键词: Amphiphilic self-assembly, Cross-linking, Morphology, Block copolymer, Kinetics

Abstract: Amphiphilic block copolymers can exhibit rich and complex morphologies in aqueous solutions, but these structures are usually delicate, easily disturbed by composition change or temperature change. In this work, the use of different methods to cross-link block copolymer self-assemblies in the presence of a selective solvent and to stabilize the structures is reviewed. In addition, the cross-linking reaction kinetics of block copolymer amphiphilic self-assemblies is briefly discussed.

Key words: Amphiphilic self-assembly, Cross-linking, Morphology, Block copolymer, Kinetics