RuCl3·3H2O Mediated Olefin Isomerizations in Ionic Liquids: A Highly Recyclable System for Olefin Isomerizations

高等学校化学研究 ›› 2012, Vol. 28 ›› Issue (1): 67-69.

RuCl₃·3H₂O Mediated Olefin Isomerizations in Ionic Liquids: A Highly Recyclable System for Olefin Isomerizations

SHAO Ming-bo¹, LIU Gui-yan², ZHAO Jing-jing¹, WANG Xiao-yu¹, WANG Jian-hui^1*

1. Department of Chemistry, College of Science, Tianjin University, Tianjin 300072, P. R. China;
2. Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry, Tianjin Normal University, Tianjin 300387, P. R. China

收稿日期:2011-03-16 修回日期:2011-04-28 出版日期:2012-01-25 发布日期:2011-12-27
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21072149, 20872108).

RuCl₃·3H₂O Mediated Olefin Isomerizations in Ionic Liquids: A Highly Recyclable System for Olefin Isomerizations

SHAO Ming-bo¹, LIU Gui-yan², ZHAO Jing-jing¹, WANG Xiao-yu¹, WANG Jian-hui^1*

1. Department of Chemistry, College of Science, Tianjin University, Tianjin 300072, P. R. China;
2. Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry, Tianjin Normal University, Tianjin 300387, P. R. China

Received:2011-03-16 Revised:2011-04-28 Online:2012-01-25 Published:2011-12-27
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21072149, 20872108).

摘要/Abstract

摘要： Herein lies a convenient and highly efficient method of olefin isomerization in the presence of RuCl₃·3H₂O in ionic liquid(IL). More importantly, RuCl₃·3H₂O is a robust and recyclable catalyst. Nine cycles of RuCl₃·3H₂O as the catalyst were performed for the isomerization reactions of the selected substrate in IL and MeOH.

关键词: Ruthenium trichloride, Ionic liquid, Olefin isomerization

Abstract: Herein lies a convenient and highly efficient method of olefin isomerization in the presence of RuCl₃·3H₂O in ionic liquid(IL). More importantly, RuCl₃·3H₂O is a robust and recyclable catalyst. Nine cycles of RuCl₃·3H₂O as the catalyst were performed for the isomerization reactions of the selected substrate in IL and MeOH.

Key words: Ruthenium trichloride, Ionic liquid, Olefin isomerization

SHAO Ming-bo, LIU Gui-yan, ZHAO Jing-jing, WANG Xiao-yu, WANG Jian-hui. RuCl₃·3H₂O Mediated Olefin Isomerizations in Ionic Liquids: A Highly Recyclable System for Olefin Isomerizations[J]. 高等学校化学研究, 2012, 28(1): 67-69.

参考文献

[1] Kajihara K., Arisawa M., Shuto S., J. Org. Chem., 2008, 73(23),9494 [2] Tanaka K., Okazaki E., Shibata Y., J. Am. Chem. Soc., 2009, 131(31),10822 [3] Terada M., Toda Y., J. Am. Chem. Soc., 2009, 131(18), 6354 [4] Wu W., Zhang X. Y., Kang S. X., Chem. Res. Chinese Universities,2010, 26(5), 768 [5] Cunningham J., Gigg R., Warren C. D., Tetrahedron Lett., 1964,5(19), 1191 [6] Riviere M., Latters A., Bull. Soc. Chim. Fr., 1972, 2, 730 [7] Kesteleyn B., Kimpe N. D., J. Org. Chem., 2000, 65(3), 640 [8] Gauthier D., Lindhardt A. T., Olsen E. P. K., Overgaard J., Skrydstrup T., J. Am. Chem. Soc., 2010, 132(23), 7998 [9] Mirza-Aghayan M., Boukherroub R., Bolourtchian M., J. Organomet.Chem., 2003, 678(1/2), 1 [10] Luo X. L., Tang D. Y., Li M., Journal of Molecular Structure: Theochem.,2005, 731(1―3), 139 [11] Morrill T. C., D'Souza C. A., Organometallics, 2003, 22(8), 1626 [12] Meltzer D., Avnir D., Fanun M., Gutkin V., Popov I., Schomäker R.,Schwarze M., Blum J., Journal of Molecular Catalysis A: Chemical,2011, 335(1/2), 8 [13] Arisawa M., Terada Y., Takahashi K., Nakagawa M., Nishida A., J. Org. Chem., 2006, 71(11), 4255 [14] Petkovska V. I., Hopkins T. E., Powell D. H., Wagener K. B., Macromolecules,2005, 38(14), 5878 [15] Urbala M., Applied Catalysis A: General, 2010, 377(1/2), 27 [16] Sharma S. K., Parikh P. A., Jasra R. V., Journal of Molecular Catalysis A: Chemical, 2010, 317(1/2), 27 [17] Small B. L., Organometallics, 2003, 22(16), 3178 [18] Kira K., Tanda H., Hamajima A., Baba T., Takai S., Isobe M.,Tetrahedron, 2002, 58(32), 6485 [19] Reddy M. R., Periasamy M., J. Organomet. Chem., 1995, 491(1/2),263 [20] Shaviv E., Botoshansky M., Eisen M. S., J. Organomet. Chem., 2003,683(1), 165 [21] Petrisor C. E., Gómez-Bengoa E., Royo E., Cuenca T., Organometallics,2009, 28(14), 4165 [22] Averbuj C., Eisen M. S., J. Am. Chem. Soc., 1999, 121(38), 8755 [23] Coleto I., Roldán R., Jiménez-Sanchidrián C., Gómez J. P., Romero-Salguero F. J., Catalysis Today, 2010, 149(3/4), 275 [24] Seddon K. R., J. Chem. Technol. Biotech., 1997, 68(4), 351 [25] Olivier-Bourbigou H., Magna L., Morvan D., Applied Catalysis A:General, 2010, 373(1/2), 1 [26] Lou L. L., Dong Y. L., Yu K., Jiang S., Song Y., Cao S., Liu S. X.,Journal of Molecular Catalysis A: Chemical, 2010, 333(1/2), 20 [27] Wei J. F., Jiao J., Feng J. J., Lv J., Zhang X. R., Shi X. Y., Chen Z. G.,J. Org. Chem., 2009, 74(16), 6283 [28] Singh V., Ratti R., Kaur S., Journal of Molecular Catalysis A:Chemical, 2011, 334(1/2),13 [29] Karimi B., Enders D., Org. Lett., 2006, 8(6), 1237 [30] Liu Y., Li M., Lu Y., Wu H. H., Gao G. H., Chem. J. Chinese Universities,2007, 28(4), 723 [31] Chauvin Y., Mussmann L., Olivier H., Angew. Chem. Int. Ed. Engl.,1996, 34(23), 2698 [32] Nian B. Y., Xu G., Wu J. P., Yang L. R., Chem. J. Chinese Universities,2007, 28(9), 1677 [33] Sharma S. K., Srivastava V. K., Pandya P. H., Jasra R. V., Catal.Commun., 2005, 6(3), 205 [34] Setty-Fichman M., Blum J., Sasson Y., Eisen M., Tetrahedron Lett.,1994, 35(5), 781 [35] Bujok R., Bieniek M., Masnyk M., Michrowska A., Sarosiek A.,St?powska H., Arlt D., Grela K., J. Org. Chem., 2004, 69(20), 6894

RuCl₃·3H₂O Mediated Olefin Isomerizations in Ionic Liquids: A Highly Recyclable System for Olefin Isomerizations

RuCl₃·3H₂O Mediated Olefin Isomerizations in Ionic Liquids: A Highly Recyclable System for Olefin Isomerizations

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