A Multifunctional Cobalt (II) Metal-Organic Framework with Nanoporous Channels for Gas and Dye Absorption, and Magnetic Performance

doi:10.1007/s40242-022-2263-y

高等学校化学研究 ›› 2023, Vol. 39 ›› Issue (6): 915-920.doi: 10.1007/s40242-022-2263-y

A Multifunctional Cobalt (II) Metal-Organic Framework with Nanoporous Channels for Gas and Dye Absorption, and Magnetic Performance

CAO Weiwei, MA Zhilong, and TIAN Li

Tianjin Key Laboratory of Structure and Performance for Functional Molecules, College of Chemistry, Tianjin Normal University, Tianjin 300387, P.R. China

收稿日期:2022-08-10 出版日期:2023-12-01 发布日期:2023-11-18
通讯作者: TIAN Li E-mail:lilytianli@hotmail.com
基金资助:
This work was supported by the National Natural Science Foundation of China (No.21371133).

A Multifunctional Cobalt (II) Metal-Organic Framework with Nanoporous Channels for Gas and Dye Absorption, and Magnetic Performance

CAO Weiwei, MA Zhilong, and TIAN Li

Tianjin Key Laboratory of Structure and Performance for Functional Molecules, College of Chemistry, Tianjin Normal University, Tianjin 300387, P.R. China

Received:2022-08-10 Online:2023-12-01 Published:2023-11-18
Contact: TIAN Li E-mail:lilytianli@hotmail.com
Supported by:
This work was supported by the National Natural Science Foundation of China (No.21371133).

摘要/Abstract

摘要： Coordination polymer {[Co(BTIA)(H₂O)_0.5]·1.5CH₃OH}_n (Co-1) was synthesized from Co(NO₃)₂·6H₂O and multidentate ligand 4,6-bis-(4H-1,2,4-triazol-1-yl)-isophthalic acid (H2BTIA) under solvothermal conditions. Crystal analysis found that Co-1 was a (4⁴·6²)2(4¹⁶·6¹²) 3D framework with one dimensional channels, which gives it good adsorption performance for greenhouse gas CO2 and anionic dyes CR^2- and TY^-. In particular for the large-size CR^2-, it behaves a very fast removal rate. In addition, magnetic analysis discloses that antiferromagnetic (AF) coupling exists in binuclear cobalt unit.

关键词: Co (II) ion, Metal-organic framework (MOF), Gas adsorption, Dye adsorption, Congo red

Abstract: Coordination polymer {[Co(BTIA)(H₂O)_0.5]·1.5CH₃OH}_n (Co-1) was synthesized from Co(NO₃)₂·6H₂O and multidentate ligand 4,6-bis-(4H-1,2,4-triazol-1-yl)-isophthalic acid (H2BTIA) under solvothermal conditions. Crystal analysis found that Co-1 was a (4⁴·6²)2(4¹⁶·6¹²) 3D framework with one dimensional channels, which gives it good adsorption performance for greenhouse gas CO2 and anionic dyes CR^2- and TY^-. In particular for the large-size CR^2-, it behaves a very fast removal rate. In addition, magnetic analysis discloses that antiferromagnetic (AF) coupling exists in binuclear cobalt unit.

Key words: Co (II) ion, Metal-organic framework (MOF), Gas adsorption, Dye adsorption, Congo red

CAO Weiwei, MA Zhilong, and TIAN Li. A Multifunctional Cobalt (II) Metal-Organic Framework with Nanoporous Channels for Gas and Dye Absorption, and Magnetic Performance[J]. 高等学校化学研究, 2023, 39(6): 915-920.

CAO Weiwei, MA Zhilong, and TIAN Li. A Multifunctional Cobalt (II) Metal-Organic Framework with Nanoporous Channels for Gas and Dye Absorption, and Magnetic Performance[J]. Chemical Research in Chinese Universities, 2023, 39(6): 915-920.

参考文献

[1] Furukawa H., Ko N., Go Y. B., Aratani N., Choi S. B., Choi E., Yazaydin A. O., Snurr R. Q., O'Keeffe M., Kim J., Yaghi O. M., Science, 2010, 329, 424
[2] Li J. R., Sculley J., Zhou H. C., Chem. Rev., 2012, 112, 869
[3] Li B., Wen H. M., Cui Y. J., Zhou W., Qian G. D., Chen B. L., Adv. Mater., 2016, 28, 8819
[4] Feng L., Wang K. Y., Day G. S., Ryder M. R., Zhou H. C., Chem. Rev., 2020, 120, 13087
[5] Wang K. Y., Feng L. G., Yan T. H., Wu S. X., Joseph E. A., Zhou H. C., Angew. Chem. Int. Ed., 2020, 59, 11349
[6] Lian X. Z., Fang Y., Joseph E., Wang Q., Li J. L., Banerjee S., Lollar C., Wang X., Zhou H. C., Chem. Soc. Rev., 2017, 46, 3386
[7] Wu D., Zhang P. F., Yang G. P., Hou L., Zhang W. Y., Han Y. F., Liu P., Wang Y. Y., Coord. Chem. Rev., 2021, 434, 213709
[8] Li L. B., Lin R. B., Krishna R., Li H., Xiang S. C., Wu H., Li J. P., Zhou W., Chen B. L., Science, 2018, 362, 443
[9] Lan T. H., Li L. B., Chen Y., Wang X. Q., Yang J. F., Li J. P., Adv. Mater., 2021, 33, 2100866
[10] Cui W. G., Zhang G. Y., Hu T. L., Bu X. H., Coor. Chem. Rev., 2019, 387, 79
[11] Wang T., Lin E., Peng Y. L., Chen Y., Cheng P., Zhang Z. J., Coord. Chem. Rev., 2020, 423, 213485
[12] Liao P. Q., Huang N. Y., Zhang W. X., Zhang J. P., Chen X. M., Science, 2017, 356, 1193
[13] Yi J. D., Xie R., Xie Z. L., Chai G. L., Liu T. F., Chen R. P., Huang Y. B., Cao R., Angew. Chem. Int. Ed., 2020, 59, 23641
[14] Hou S. L., Dong J., Zhao B., Adv. Mater., 2020, 32, 1806163
[15] Ding M., Flaig R. W., Jiang H. L., Yaghi O. M., Chem. Soc. Rev., 2019, 48, 2783
[16] Peng D., Yin L., Hu P., Li B., Ouyang Z. W., Zhuan G. L., Wang Z. X., Inorg. Chem., 2018, 57, 2577
[17] Liu J. H., Li L. D., Li X. X, Zhao D., Sun Y. Q., Zheng S. T., Chem. Commun., 2019, 55, 7394
[18] Pinkowicz D., Southerland H. I., Avendaño C., Prosvirin A., Sanders C., Wernsdorfer W., Pedersen K. S., Dreiser J., Clérac R., Nehrkorn J., Simeoni G., Schnegg A., Holldack K., Dunbar K. R., J. Am. Chem. Soc., 2015, 137, 14406
[19] Liu X. Q., Feng X. W., Meihaus K. R., Meng X. X., Zhang Y., Li L., Liu J. L., Pedersen K. S., Keller L., Shi W., Zhang Y. Q., Cheng P., Long J. R., Angew. Chem. Int. Ed., 2020, 59, 10610
[20] Ma Y. J., Hu J. X., Han S. D., Pan J., Li J. H., Wang G. M., J. Am. Chem. Soc., 2020, 142, 2682
[21] Sumida K., Rogow D. L., Mason J. A., McDonald T. M., Bloch E. D., Herm Z. R., Bae T. H., Long J. R., Chem. Rev., 2012, 112, 724
[22] Xiang S., He Y., Zhang Z., Wu H., Zhou W., Krishna R., Chen B., Nat. Commun., 2012, 3, 954
[23] Zhang Z. J., Yao Z. Z., Xiang S. C., Chen B. L., Energy Environ. Sci., 2014, 7, 2868
[24] Okesola B. O., Smith D. K., Chem. Soc. Rev., 2016, 45, 4226
[25] Zeng M. H., Yin Z., Tan Y. X., Zhang W. X., He Y. P., Kurmoo M., J. Am. Chem. Soc., 2014, 136, 4680
[26] Zou C., Zhang Z., Xu X., Gong Q., Li J., Wu C. D., J. Am. Chem. Soc., 2012, 134, 87
[27] Jia Y. Y., Ren G. J., Li A. L., Zhang L. Z., Feng R., Zhang Y. H., Bu X. H., Cryst. Growth Des., 2016, 16, 5593
[28] Zhou Y., Yao S., Ma Y. L., Li G. H., Huo Q. S., Liu Y. L., Chem. Commun., 2018, 54, 3006
[29] Yang X. M., Yan C. Y., Li Z. Y., Li X., Yu Q., Sang T. T., Gai Y. L., Zhang Q. F., Xiong K. C., Inorg. Chem., 2021, 60, 5988
[30] Wang X. S., Liang J., Li L., Lin Z. J., Bag P. P., Ga S. Y., Huang Y. B., Cao R., Inorg. Chem., 2015, 55, 2641
[31] Wu M. K., Yi F. Y., Fang Y., Xiao X. W., Wang S. C., Pan L. Q., Zhu S. R., Tao K., Han L., Cryst. Growth Des., 2017, 10, 5458
[32] Rodriguez A., Sakiyama H., Masciocchi N., Galli S., Galez N., Lloret F., Colacio E., Inorg. Chem., 2005, 44, 8399
[33] Li J. P., Li B. J., Pan M. T., Liu B., Cheng J. J., Li R. Y., Gao X. L., Wang S. M., Hou H. W., Liu Z. Y., Cryst. Growth Des., 2017, 17, 2975
[34] Caballero A. B., Rodriguez-Dieguez A., Lezama L., Barea E., Salas J. M., Dalt. Trans., 2011, 40, 5180
[35] Caballero A. B., Rodriguez-Dieguez A., Barea E., Quiros M., Salas J. M., CrystEngComm., 2010, 12, 3038
[36] Chen W. M., Meng X. L., Zhuang G. L., Wang Z., Kurmoo M., Zhao Q. Q., Wang X. P., Shan B. R., Tung C. H., Sun D., J. Mater. Chem. A, 2017, 5, 13079
[37] Wang X. P., Chen W. M., Qi H., Li X. Y., Rajnák C., Feng Z. Y., Kurmoo M., Boča R., Jia C. J., Tung C. H., Sun D., Chem. Eur. J., 2017, 23, 7990
[38] Zhou X. J., Liu L. L., Tai X. S., Zhang H., Chem. Res. Chinese Universities, 2018, 34(5), 723
[39] Park J., Li J. R., Sañudo E. C., Yuan D. Q., Zhou H. C., Chem. Commun., 2012, 48, 883
[40] Liu Z. Y., Zhao H., Song W. C., Wang X. G., Liu Z. Y., Zhao X. J., Yang E. C., J. Mater. Chem. C, 2019, 7, 191
[41] Shi W. J., Li Y. Z., Hu Q. X., Wang G. D., Hou L., Wang Y. Y., J. Solid State Chem., 2020, 283, 121170
[42] Chen K. J., Lin R. B., Liao P. Q., He C. T., Lin J. B., Xue W., Zhang Y. B., Zhang J. P., Chen X. M., Cryst. Growth Des., 2013, 13, 2118
[43] Liu B., Zhao R. L., Yang G. P., Hou L., Wang Y. Y., Shi Q. Z., CrystEngComm, 2013, 15, 2057
[44] Zhai Q. G., Lin Q., Wu T., Zheng S. T., Bu X. H., Feng P. Y., Chem. Mater., 2012, 24, 2624
[45] Ling Y., Yang F. L., Deng M. L., Chen Z. X., Liu X. F., Weng L. H., Zhou Y. M., Dalton Trans., 2012, 41, 4007
[46] Song Y., Fan R. Q., Xing K., Du X., Su T., Wang P., Yang Y. L., Cryst. Growth Des., 2017, 17, 2549
[47] Zhou Y., Yao S., Ma Y. L., Li G. H., Huo Q. S., Liu Y. L., Chem. Commun., 2018, 54, 3006
[48] Rabu P., Rueff J. M., Huang Z. L., Angelov S., Souletie J., Drillon M., Polyhedron, 2021, 20, 1677
[49] Rueff J. M., Masciocchi N., Rabu P., Sironi A., Skoulios A., Chem.―Eur. J., 2002, 8, 1813
[50] Rueff J. M., Masciocchi N., Rabu P., Sironi A., Skoulios A., Eur. J. Inorg. Chem., 2001, 2001, 2843

A Multifunctional Cobalt (II) Metal-Organic Framework with Nanoporous Channels for Gas and Dye Absorption, and Magnetic Performance

A Multifunctional Cobalt (II) Metal-Organic Framework with Nanoporous Channels for Gas and Dye Absorption, and Magnetic Performance

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