Hyper-crosslinked Porous Polymer Based on Bulk Rigid Monomer for Gas and Dye Absorptions

doi:10.1007/s40242-017-6467-5

高等学校化学研究 ›› 2017, Vol. 33 ›› Issue (3): 479-483.doi: 10.1007/s40242-017-6467-5

Hyper-crosslinked Porous Polymer Based on Bulk Rigid Monomer for Gas and Dye Absorptions

SHAN Liang, WANG Li, FAN Yong, SHEN Lanlan, WANG Shengyan, XU Jianing

College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2016-11-23 修回日期:2017-02-10 出版日期:2017-06-01 发布日期:2017-04-05
通讯作者: XU Jianing,E-mail:xujn@jlu.edu.cn E-mail:xujn@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21171065, 21201077).

Hyper-crosslinked Porous Polymer Based on Bulk Rigid Monomer for Gas and Dye Absorptions

SHAN Liang, WANG Li, FAN Yong, SHEN Lanlan, WANG Shengyan, XU Jianing

College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2016-11-23 Revised:2017-02-10 Online:2017-06-01 Published:2017-04-05
Contact: XU Jianing,E-mail:xujn@jlu.edu.cn E-mail:xujn@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21171065, 21201077).

摘要/Abstract

摘要：

Using the rigid 3,3-bis(4-hydroxyphenyl)-2-(4-tritylphenyl)isoindolin-1-one with polar functional groups as a building block and formaldehyde dimethyl acetal(FDA) as crossinglinker, a new hyper-crosslinked polymer (HCP) was synthesized via Friedel-Crafts alkylation reaction promoted by anhydrous FeCl₃. The synthesized HCP is insoluble in boiled water and common organic solvents. Moreover, it shows a good CO₂ capture capacity even if its surface area is not very high, and the absolute CO₂ uptake capacity of it is 3.05 mmol/g. This can be attributed to the introduction of polar hydroxyl and lactam groups into the skeleton of the polymer, which provides effective adsorption sites for CO₂. In addition, the synthesized HCP also exhibits good adsorption capacity for organic dyes in water, especially for crystal violet.

关键词: Hyper-crosslinked polymer, CO₂ adsorption, Dye adsorption

Abstract:

Key words: Hyper-crosslinked polymer, CO₂ adsorption, Dye adsorption

SHAN Liang, WANG Li, FAN Yong, SHEN Lanlan, WANG Shengyan, XU Jianing. Hyper-crosslinked Porous Polymer Based on Bulk Rigid Monomer for Gas and Dye Absorptions[J]. 高等学校化学研究, 2017, 33(3): 479-483.

SHAN Liang, WANG Li, FAN Yong, SHEN Lanlan, WANG Shengyan, XU Jianing. Hyper-crosslinked Porous Polymer Based on Bulk Rigid Monomer for Gas and Dye Absorptions[J]. Chemical Research in Chinese Universities, 2017, 33(3): 479-483.

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Hyper-crosslinked Porous Polymer Based on Bulk Rigid Monomer for Gas and Dye Absorptions

Hyper-crosslinked Porous Polymer Based on Bulk Rigid Monomer for Gas and Dye Absorptions

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