Functionalized Hierarchical ZSM-5 Zeolites for the Viscosity Reduction of Heavy Oil at Low Temperature

doi:10.1007/s40242-022-1425-2

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (4): 1083-1088.doi: 10.1007/s40242-022-1425-2

Functionalized Hierarchical ZSM-5 Zeolites for the Viscosity Reduction of Heavy Oil at Low Temperature

XIAO Peiwen^1,2, LI Hui³, WANG Pingmei^1,2, LIU Bolun³, JING Wendan³, HE Lipeng^1,2, WANG Runwei³, HAN Xue^1,2, ZHANG Zongtao³, QIU Shilun³, LUO Jianhui^1,2

1. Research Institute of Petroleum Exploration &Development, PetroChina, Beijing 100083, P. R. China;
2. Key Laboratory of Nano Chemistry(KLNC), China National Petroleum Corporation(CNPC), Beijing 100083, P. R. China;
3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2021-10-22 修回日期:2021-11-01 出版日期:2022-08-01 发布日期:2022-07-01
通讯作者: ZHANG Zongtao E-mail:zzhang@jlu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China(No.21771081), the Chang Bai Mountain Scholars Program, China (No.440020031182), the Provincial Major Project, China(No.20180101001JC), and the PetroChina Scientific Research and Technology Development Project, China(Nos.2018A-0907, 2020D-5006-82).

Functionalized Hierarchical ZSM-5 Zeolites for the Viscosity Reduction of Heavy Oil at Low Temperature

XIAO Peiwen^1,2, LI Hui³, WANG Pingmei^1,2, LIU Bolun³, JING Wendan³, HE Lipeng^1,2, WANG Runwei³, HAN Xue^1,2, ZHANG Zongtao³, QIU Shilun³, LUO Jianhui^1,2

1. Research Institute of Petroleum Exploration &Development, PetroChina, Beijing 100083, P. R. China;
2. Key Laboratory of Nano Chemistry(KLNC), China National Petroleum Corporation(CNPC), Beijing 100083, P. R. China;
3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2021-10-22 Revised:2021-11-01 Online:2022-08-01 Published:2022-07-01
Contact: ZHANG Zongtao E-mail:zzhang@jlu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China(No.21771081), the Chang Bai Mountain Scholars Program, China (No.440020031182), the Provincial Major Project, China(No.20180101001JC), and the PetroChina Scientific Research and Technology Development Project, China(Nos.2018A-0907, 2020D-5006-82).

摘要/Abstract

摘要： Herein, we propose a novel approach to reduce the viscosity of heavy oil by functional hierarchical CTMS-ZSM-5-PTMS zeolites. CTMS-ZSM-5-PTMS zeolites synthesized by asymmetric modification and selective alkali etching can reduce the viscosity of heavy oil through adsorbing asphaltenes. This method can reduce the viscosity of heavy oil from hundreds of thousands mPa·s to about ten thousand mPa·s. The work provides an economical and environmentally friendly candidate for heavy oil viscosity reduction under low-temperature conditions.

关键词: Heavy oil, Viscosity, Hierarchical ZSM-5 zeolite

Abstract: Herein, we propose a novel approach to reduce the viscosity of heavy oil by functional hierarchical CTMS-ZSM-5-PTMS zeolites. CTMS-ZSM-5-PTMS zeolites synthesized by asymmetric modification and selective alkali etching can reduce the viscosity of heavy oil through adsorbing asphaltenes. This method can reduce the viscosity of heavy oil from hundreds of thousands mPa·s to about ten thousand mPa·s. The work provides an economical and environmentally friendly candidate for heavy oil viscosity reduction under low-temperature conditions.

Key words: Heavy oil, Viscosity, Hierarchical ZSM-5 zeolite

XIAO Peiwen, LI Hui, WANG Pingmei, LIU Bolun, JING Wendan, HE Lipeng, WANG Runwei, HAN Xue, ZHANG Zongtao, QIU Shilun, LUO Jianhui. Functionalized Hierarchical ZSM-5 Zeolites for the Viscosity Reduction of Heavy Oil at Low Temperature[J]. 高等学校化学研究, 2022, 38(4): 1083-1088.

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Functionalized Hierarchical ZSM-5 Zeolites for the Viscosity Reduction of Heavy Oil at Low Temperature

Functionalized Hierarchical ZSM-5 Zeolites for the Viscosity Reduction of Heavy Oil at Low Temperature

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