Transport Properties of Alkali Fluoride High Temperature Ionic Liquids and Application of Theories of Viscous Flow

doi:10.1007/s40242-015-4467-x

高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (5): 858-864.doi: 10.1007/s40242-015-4467-x

Transport Properties of Alkali Fluoride High Temperature Ionic Liquids and Application of Theories of Viscous Flow

POPESCU Anamaria^1,2, CONSTANTIN Virgil^1,2

1. Laboratory of Molten Salts, "Ilie Murgulescu"Institute of Physical Chemistry, Romanian Academy, Bucharest 060021, Romania;
2. Technology Transfer Center(CTT-ICF), Bucharest 060021, Romania

收稿日期:2014-12-05 修回日期:2015-03-30 出版日期:2015-10-01 发布日期:2015-10-10
通讯作者: CONSTANTIN Virgil, E-mail: virgilconstantin@yahoo.com E-mail:virgilconstantin@yahoo.com

Transport Properties of Alkali Fluoride High Temperature Ionic Liquids and Application of Theories of Viscous Flow

POPESCU Anamaria^1,2, CONSTANTIN Virgil^1,2

1. Laboratory of Molten Salts, "Ilie Murgulescu"Institute of Physical Chemistry, Romanian Academy, Bucharest 060021, Romania;
2. Technology Transfer Center(CTT-ICF), Bucharest 060021, Romania

Received:2014-12-05 Revised:2015-03-30 Online:2015-10-01 Published:2015-10-10
Contact: CONSTANTIN Virgil, E-mail: virgilconstantin@yahoo.com E-mail:virgilconstantin@yahoo.com

摘要/Abstract

摘要：

The transport properties of several alkali fluoride high temperature ionic liquids(LiF, NaF, KF, RbF and CsF) were studied in a range of 980-1400 K and the temperature dependences of the viscosity and density were interpreted, in agreement with the classical equations characterizing the viscous flow(Arrhenius, Batchinski, Eyring and Frenkel). The experimental results reveal the validity of these equations even at high temperatures, suggesting that no significant structural changes of alkali fluorides occurred in the studied temperature range. Our results clearly demonstrate that the mentioned thermo-physical properties can be used as powerful tools in the further investigations of the ionic interactions governing the alkali fluoride molten salts.

关键词: Ionic liquid, Alkali fluoride, Viscosity, Temperature dependence, Correlation, Fluidity

Abstract:

Key words: Ionic liquid, Alkali fluoride, Viscosity, Temperature dependence, Correlation, Fluidity

POPESCU Anamaria, CONSTANTIN Virgil. Transport Properties of Alkali Fluoride High Temperature Ionic Liquids and Application of Theories of Viscous Flow[J]. 高等学校化学研究, 2015, 31(5): 858-864.

POPESCU Anamaria, CONSTANTIN Virgil. Transport Properties of Alkali Fluoride High Temperature Ionic Liquids and Application of Theories of Viscous Flow[J]. Chemical Research in Chinese Universities, 2015, 31(5): 858-864.

参考文献

[1] Brockner W., Tørklep K., Øye H. A., Ber. Bunsenges. Phys. Chem., 1979, 83, 12
[2] Ejima T., Sato Y., Yaegashi S., Kijima T., Takeuchi E., Tamai K., J. Japan Inst. Metals, 1987, 51(4), 328
[3] Popescu A. M., Rev. Roum. Chim., 1999, 44, 765
[4] Zuca St., Rev. Roum. Chim., 1970, 15, 1277
[5] Eds.:Bockris J. O' M., White J. L., Mackenzie J. D., Physicochemical Measurements at High Temperatures, Butterworths, London, 1959
[6] Murgulescu I. G., Zuca St., Z. Phys. Chem.(Leipzig), 1961, 218(5/6), 379
[7] Zuca St., Borcan R., Rev. Roum. Chim., 1984, 29(3), 233
[8] Janz G. J., J. Phys. Chem. Ref. Data, 1988, 17(Supplement 2), 1
[9] Janz G. J., Dampier F. W., Lakshminarayan G. R., Lorenz P. K., Tomkins R. P. T., Molten Salts:Vol. 1, Electrical Conductance, Density, and Viscosity Data, Nat. Stand. Ref. Data Ser., NSRDS-NBS, Washington D. C., 1968, 15, 1
[10] Janz G. J., Gardner G. L., Krebs U., Tomkins R. P. T., J. Phys. Chem. Ref. Data, 1974, 3(1), 1
[11] Malakhov A. N., Pankratov A. L., Eds.:Prigogine I., Rice S.A., John Wiley & Sons Inc., Evolution Times of Probability Distributions and Averages-exact Solutions of the Kramers' Problem in Advances in Chemical Physics, Vol. 121, New York, 2002, 357
[12] Batchinski A. J., Z. Phys. Chem., 1913, 84, 643
[13] Silverman D., Roseveare W. E., J. Am. Chem. Soc., 1932, 54(11), 4460
[14] Glasstone S., Laidler K. J., Eyring H., Theory of Rate Process, McGraw-Hill, New York, 1941
[15] Eds.:Stull D.R., Prophet H., JANAF Thermochemical Tables, Nat. Stand. Ref. Data Ser., NSRDS-NBS 37, Washington D.C., 1971
[16] Malyshev V., Gab A., Popescu A. M., Constantin V., Chem. Res. Chinese Universities, 2013, 29(4), 771
[17] Li Y., Lu J., Xu J. Q., Cui X. B., Sun Y. H., Li K. C., Pan L. Y., Bie H. Y., Chem. Res. Chinese Universities, 2004, 20(6), 681
[18] Du F., Bie X. F., Bian X. F., Hu F., Chen G., Wang C. Z., Wei Y. J., Chem. Res. Chinese Universites, 2013, 29(2), 210
[19] Frenkel J., Kinetic Theory of Liquids, Clarendon Press, Oxford, 1946, 441
[20] Murgulescu I. G., Zuca St., Z. Phys. Chem.(Leipzig), 1963, 222(5/6), 300
[21] Murgulescu I. G., Zuca St., Rev. Roum. Chem., 1965, 10(2), 129

Transport Properties of Alkali Fluoride High Temperature Ionic Liquids and Application of Theories of Viscous Flow

Transport Properties of Alkali Fluoride High Temperature Ionic Liquids and Application of Theories of Viscous Flow

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	XIAO Peiwen, LI Hui, WANG Pingmei, LIU Bolun, JING Wendan, HE Lipeng, WANG Runwei, HAN Xue, ZHANG Zongtao, QIU Shilun, LUO Jianhui. Functionalized Hierarchical ZSM-5 Zeolites for the Viscosity Reduction of Heavy Oil at Low Temperature[J]. 高等学校化学研究, 2022, 38(4): 1083-1088.
[2]	YU Fengli, CHI Yujie, GAO Chong, CHEN Ruirui, XIE Congxia, YU Shitao. Baeyer-Villiger Oxidation of Cyclic Ketones Catalyzed by Amino Acid Ionic Liquids[J]. 高等学校化学研究, 2020, 36(5): 865-869.
[3]	ZHAO Qi, LIANG Xiaoxiao, YOU Yingxue, WANG Yuliang, DU Xinwei, LIU Baijun, HU Wei. Proton Conductivity Improvement Effect of Cellulose on SPEEKK Based PEM[J]. 高等学校化学研究, 2019, 35(5): 916-923.
[4]	ZHAO Xiaohui, QIU Youli, JIANG Long, LI Yu. Analysis of Affinity Energy Between Biphenyl Dioxygenase and Polychlorinated Biphenyls Using Molecular Docking[J]. 高等学校化学研究, 2019, 35(2): 325-332.
[5]	GUAN Lianyue, LUO Qiang, LIANG Na, YU Wei. Determination of Lignans in Schisandra sphenanthera and Schisandra chinensis Using Ionic Liquid-based Ultrasonic-assisted Extraction and High-performance Liquid Chromatography[J]. 高等学校化学研究, 2018, 34(6): 887-892.
[6]	CHEN Siyan, GAO Zhenhai. Structure of a Mixture of Graphene Plates and Ionic Liquid 1-Octyl-3-methylimidazolium Hexafluoroborate[J]. 高等学校化学研究, 2018, 34(4): 598-603.
[7]	XU Chao, YIN Xuhan, ZHANG Chuan, CHEN Hongyue, HUANG He, HU Yi. Improving Catalytic Performance of Burkholderiacepacia Lipase by Chemical Modification with Functional Ionic Liquids[J]. 高等学校化学研究, 2018, 34(2): 279-284.
[8]	WANG Jingyang, ZHANG Meng, XU Xiaodong, FENG Jing, WANG Yanli, ZHANG Milin, HAN Wei, CHEN Yitung, TIAN Guoxin. Synthesis and Characterization of [Cu(N-MeIm)₄(BF₄)₂] in Ionic Liquid[J]. 高等学校化学研究, 2018, 34(1): 8-12.
[9]	Ana Maria POPESCU, Kazimir YANUSHKEVICH, Vasile SOARE, Cristina DONATH, Elena Ionela NEACSU, Virgil CONSTANTIN. Recovery of Metals from Anodic Dissolution Slime of Waste from Electric and Electronic Equipment(WEEE) by Extraction in Ionic Liquids[J]. 高等学校化学研究, 2018, 34(1): 113-118.
[10]	LI Shuang, LI Shuni, ZHAI Quanguo, JIANG Yucheng, HU Mancheng. Phase Behavior of Ionic Liquids-Cesium Carbonate-Water Aqueous Two-phase Systems and Their Extraction of L-Tryptophan[J]. 高等学校化学研究, 2018, 34(1): 127-131.
[11]	BU Luxia, LIU Daying, WEI Zhen, MA Zhanlin. Physicochemical Properties of Bi-containing Ionic Liquid Analogs Based on Choline Chloride[J]. 高等学校化学研究, 2017, 33(6): 929-933.
[12]	TONG Jing, ZHENG Xu, TONG Jian, QU Ye, LIU Lu, LI Hui. Molar Surface Gibbs Energy of the Aqueous Solution of Ionic Liquid[C₄mim] [OAc][J]. 高等学校化学研究, 2017, 33(5): 828-832.
[13]	ZHANG Lifeng, DU Suqing, SONG Qiaolan, LIU Yi, GUO Shouwu. Fluorine-free Ionic Liquid Based on Thiocyanate Anion with Propylene Carbonate as Electrolytes for Supercapacitors:Effects of Concentration and Temperature[J]. 高等学校化学研究, 2017, 33(5): 779-784.
[14]	BIAN Min, TIAN Ling, YAO Cheng. An Improved Method of Simultaneous Determination of Four Bioactive Compounds in Evodiae Fructus Using Ionic Liquids as Mobile Phase Additives in High Performance Liquid Chromatography[J]. 高等学校化学研究, 2017, 33(4): 552-558.
[15]	GAO Shenghan, GAO Ruichang. Antibacterial Cellulose Composite Membranes Prepared in Ionic Liquid via Phase Inversion Method[J]. 高等学校化学研究, 2017, 33(4): 678-683.