Thermal- and Light-driven Metathesis Reactions Between Different Diselenides

doi:10.1007/s40242-021-1149-8

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (2): 516-521.doi: 10.1007/s40242-021-1149-8

Thermal- and Light-driven Metathesis Reactions Between Different Diselenides

KANG Xiaoying¹, YUAN Yuan¹, XU Huaping², CHEN Yulan¹

1. Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin 300354, P. R. China;
2. Key Laboratory of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

收稿日期:2021-03-30 修回日期:2021-04-26 出版日期:2022-04-01 发布日期:2022-05-18
通讯作者: CHEN Yulan E-mail:yulan.chen@tju.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China(Nos.21734006, 21975178).

Thermal- and Light-driven Metathesis Reactions Between Different Diselenides

KANG Xiaoying¹, YUAN Yuan¹, XU Huaping², CHEN Yulan¹

1. Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin 300354, P. R. China;
2. Key Laboratory of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

Received:2021-03-30 Revised:2021-04-26 Online:2022-04-01 Published:2022-05-18
Contact: CHEN Yulan E-mail:yulan.chen@tju.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China(Nos.21734006, 21975178).

摘要/Abstract

摘要： Thermal- and light-driven diselenide metathesis reactions with different types of diselenides are investigated systematically. Their exchange reaction rates and equilibrium conversions are compared in the aspects of the different diselenide structures, activation conditions and solvents. As a result, the metathesis reactions between diselenide small molecules are demonstrated with high dynamic and sensitive features, which can be broadly tuned by varying the electron affinity and aromaticity of the diselenide substituents and external conditions(e.g., solvent, stimulus mode). The current work thus will not only advance our understanding on diselenide metathesis chemistry, but also promote concrete and impactful studies in selenium-containing materials.

关键词: Dynamic covalent bond, Metathesis, Diselenide

Abstract: Thermal- and light-driven diselenide metathesis reactions with different types of diselenides are investigated systematically. Their exchange reaction rates and equilibrium conversions are compared in the aspects of the different diselenide structures, activation conditions and solvents. As a result, the metathesis reactions between diselenide small molecules are demonstrated with high dynamic and sensitive features, which can be broadly tuned by varying the electron affinity and aromaticity of the diselenide substituents and external conditions(e.g., solvent, stimulus mode). The current work thus will not only advance our understanding on diselenide metathesis chemistry, but also promote concrete and impactful studies in selenium-containing materials.

Key words: Dynamic covalent bond, Metathesis, Diselenide

KANG Xiaoying, YUAN Yuan, XU Huaping, CHEN Yulan. Thermal- and Light-driven Metathesis Reactions Between Different Diselenides[J]. 高等学校化学研究, 2022, 38(2): 516-521.

KANG Xiaoying, YUAN Yuan, XU Huaping, CHEN Yulan. Thermal- and Light-driven Metathesis Reactions Between Different Diselenides[J]. Chemical Research in Chinese Universities, 2022, 38(2): 516-521.

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Thermal- and Light-driven Metathesis Reactions Between Different Diselenides

Thermal- and Light-driven Metathesis Reactions Between Different Diselenides

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