Synthesis of FER Zeolite Using 4-(Aminomethyl) pyridine as Structure-directing Agent

doi:10.1007/s40242-021-1404-z

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (1): 243-249.doi: 10.1007/s40242-021-1404-z

Synthesis of FER Zeolite Using 4-(Aminomethyl) pyridine as Structure-directing Agent

LIANG Jun^1,2, FU Wenhua², LIU Chuang², LI Xiangcheng², WANG Yu², MA Duozheng^1,2, LI Yuekun^1,2, WANG Zhendong², YANG Weimin^1,2

1. School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China;
2. State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Sinopec Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, P. R. China

收稿日期:2021-09-30 修回日期:2021-11-18 出版日期:2022-02-01 发布日期:2022-01-20
通讯作者: YANG Weimin, WANG Zhendong E-mail:yangwm.sshy@sinopec.com；wangzd.sshy@sinopec.com
基金资助:
This work was supported by the National Key R&D Program of China (No.2017YFB0702800) and the National Natural Science Foundation of China (Nos.21972168, 21802168).

Synthesis of FER Zeolite Using 4-(Aminomethyl) pyridine as Structure-directing Agent

LIANG Jun^1,2, FU Wenhua², LIU Chuang², LI Xiangcheng², WANG Yu², MA Duozheng^1,2, LI Yuekun^1,2, WANG Zhendong², YANG Weimin^1,2

1. School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China;
2. State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Sinopec Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, P. R. China

Received:2021-09-30 Revised:2021-11-18 Online:2022-02-01 Published:2022-01-20
Contact: YANG Weimin, WANG Zhendong E-mail:yangwm.sshy@sinopec.com；wangzd.sshy@sinopec.com
Supported by:
This work was supported by the National Key R&D Program of China (No.2017YFB0702800) and the National Natural Science Foundation of China (Nos.21972168, 21802168).

摘要/Abstract

摘要： This paper describes the synthesis of FER zeolite using commercially available 4-(aminomethyl)pyridine as organic structure-directing agent(OSDA). FER zeolites were prepared in mixtures with SiO₂/Al₂O₃ molar ratios in a narrow range and the resultant products possessed a typical flake-shaped morphology. The crystallization of FER zeolite was tracked in order to better understand the formation mechanism and the products obtained at different crystallization time were systematically characterized using multiple techniques. It showed that a majority of Si atoms and nearly all the Al atoms transformed into the solid phase during the hydrothermal synthesis. The rearrangement of inorganic species gave rise to zeolitic 5-membered rings(5-MRs) and 6-membered rings(6-MRs). Consequently, FER zeolite crystals were formed by the consumption of amorphous bulky gel/solid matrix. Tracking the synthesis process of FER can help.

关键词: FER zeolite, 4-(Aminomethyl) pyridine, Crystal growth

Abstract: This paper describes the synthesis of FER zeolite using commercially available 4-(aminomethyl)pyridine as organic structure-directing agent(OSDA). FER zeolites were prepared in mixtures with SiO₂/Al₂O₃ molar ratios in a narrow range and the resultant products possessed a typical flake-shaped morphology. The crystallization of FER zeolite was tracked in order to better understand the formation mechanism and the products obtained at different crystallization time were systematically characterized using multiple techniques. It showed that a majority of Si atoms and nearly all the Al atoms transformed into the solid phase during the hydrothermal synthesis. The rearrangement of inorganic species gave rise to zeolitic 5-membered rings(5-MRs) and 6-membered rings(6-MRs). Consequently, FER zeolite crystals were formed by the consumption of amorphous bulky gel/solid matrix. Tracking the synthesis process of FER can help.

Key words: FER zeolite, 4-(Aminomethyl) pyridine, Crystal growth

LIANG Jun, FU Wenhua, LIU Chuang, LI Xiangcheng, WANG Yu, MA Duozheng, LI Yuekun, WANG Zhendong, YANG Weimin. Synthesis of FER Zeolite Using 4-(Aminomethyl) pyridine as Structure-directing Agent[J]. 高等学校化学研究, 2022, 38(1): 243-249.

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Synthesis of FER Zeolite Using 4-(Aminomethyl) pyridine as Structure-directing Agent

Synthesis of FER Zeolite Using 4-(Aminomethyl) pyridine as Structure-directing Agent

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