Boron-doped Covalent Triazine Framework for Efficient CO2 Electroreduction

doi:10.1007/s40242-021-1384-z

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (1): 141-146.doi: 10.1007/s40242-021-1384-z

Boron-doped Covalent Triazine Framework for Efficient CO₂ Electroreduction

YI Jundong^2,3, LI Qiuxia^1,4, CHI Shaoyi^1,4, HUANG Yuanbiao^1,4,5, CAO Rong^1,4,5,6

1. College of Chemistry, Fuzhou University, Fuzhou 350108, P. R. China;
2. Institute of New Materials & Industry Technology, Wenzhou University, Wenzhou 325027, P. R. China;
3. School of Chemistry and Materials Science, Collaborative Innovation Center of Chemistry for Energy Materials(iChEM), University of Science and Technology of China, Hefei 230026, P. R. China;
4. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350025, P. R. China;
5. University of the Chinese Academy of Sciences, Beijing 100049, P. R. China;
6. Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, P. R. China

收稿日期:2021-09-24 修回日期:2021-10-22 出版日期:2022-02-01 发布日期:2021-11-15
通讯作者: HUANG Yuanbiao, CAO Rong E-mail:ybhuang@fjirsm.ac.cn；rcao@fjirsm.ac.cn
基金资助:
This work was supported by the National Key Research and Development Program of China(Nos.2018YFA0208600, 2018YFA0704502), the National Natural Science Foundation of China(Nos.21871263, 22071245, 22033008), the Fund of the Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China(No.2021ZZ103), and the Project of the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.Y201850).

Boron-doped Covalent Triazine Framework for Efficient CO₂ Electroreduction

YI Jundong^2,3, LI Qiuxia^1,4, CHI Shaoyi^1,4, HUANG Yuanbiao^1,4,5, CAO Rong^1,4,5,6

1. College of Chemistry, Fuzhou University, Fuzhou 350108, P. R. China;
2. Institute of New Materials & Industry Technology, Wenzhou University, Wenzhou 325027, P. R. China;
3. School of Chemistry and Materials Science, Collaborative Innovation Center of Chemistry for Energy Materials(iChEM), University of Science and Technology of China, Hefei 230026, P. R. China;
4. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350025, P. R. China;
5. University of the Chinese Academy of Sciences, Beijing 100049, P. R. China;
6. Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, P. R. China

Received:2021-09-24 Revised:2021-10-22 Online:2022-02-01 Published:2021-11-15
Contact: HUANG Yuanbiao, CAO Rong E-mail:ybhuang@fjirsm.ac.cn；rcao@fjirsm.ac.cn
Supported by:
This work was supported by the National Key Research and Development Program of China(Nos.2018YFA0208600, 2018YFA0704502), the National Natural Science Foundation of China(Nos.21871263, 22071245, 22033008), the Fund of the Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China(No.2021ZZ103), and the Project of the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.Y201850).

摘要/Abstract

摘要： Converting CO₂ into chemicals with electricity generated by renewable energy is a promising way to achieve the goal of carbon neutrality. Carbon-based materials have the advantages of low cost, wide sources and environmental friendliness. In this work, we prepared a series of boron-doped covalent triazine frameworks and found that boron doping can significantly improve the CO selectivity up to 91.2% in the CO₂ electroreduction reactions(CO₂RR). The effect of different doping ratios on the activity by adjusting the proportion of doped atoms was systematically investigated. This work proves that the doping modification of non-metallic materials is a very effective way to improve their activity, and also lays a foundation for the study of other element doping in the coming future.

关键词: Covalent triazine framework, CO₂ electroreduction, CO, B-doping

Abstract: Converting CO₂ into chemicals with electricity generated by renewable energy is a promising way to achieve the goal of carbon neutrality. Carbon-based materials have the advantages of low cost, wide sources and environmental friendliness. In this work, we prepared a series of boron-doped covalent triazine frameworks and found that boron doping can significantly improve the CO selectivity up to 91.2% in the CO₂ electroreduction reactions(CO₂RR). The effect of different doping ratios on the activity by adjusting the proportion of doped atoms was systematically investigated. This work proves that the doping modification of non-metallic materials is a very effective way to improve their activity, and also lays a foundation for the study of other element doping in the coming future.

Key words: Covalent triazine framework, CO₂ electroreduction, CO, B-doping

YI Jundong, LI Qiuxia, CHI Shaoyi, HUANG Yuanbiao, CAO Rong. Boron-doped Covalent Triazine Framework for Efficient CO₂ Electroreduction[J]. 高等学校化学研究, 2022, 38(1): 141-146.

YI Jundong, LI Qiuxia, CHI Shaoyi, HUANG Yuanbiao, CAO Rong. Boron-doped Covalent Triazine Framework for Efficient CO₂ Electroreduction[J]. Chemical Research in Chinese Universities, 2022, 38(1): 141-146.

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Boron-doped Covalent Triazine Framework for Efficient CO₂ Electroreduction

Boron-doped Covalent Triazine Framework for Efficient CO₂ Electroreduction

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