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高等学校化学研究 ›› 2021, Vol. 37 ›› Issue (6): 1257-1267.doi: 10.1007/s40242-021-1350-9

• Reviews • 上一篇    下一篇

Study of Graphdiyne-based Magnetic Materials

LI Ru1,2, ZHANG Mingjia1, LI Xiaodong1, MA Xiaodi1, HUANG Changshui1,2   

  1. 1. Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, P. R. China;
    2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, P. R. China
  • 收稿日期:2021-08-31 修回日期:2021-09-30 出版日期:2021-11-23 发布日期:2021-11-23
  • 通讯作者: HUANG Changshui, ZHANG Mingjia E-mail:huangcs@qibebt.ac.cn;zhangmj@qibebt.ac.cn
  • 基金资助:
    This work was supported by the the National Natural Science Foundation of China(Nos.51802324, 51822208, 21771187, 21790050, 21790051), the Frontier Science Research Project of the Chinese Academy of Sciences(No.QYZDBSSW-JSC052), the Taishan Scholars Program of Shandong Province, China(No. tsqn201812111), and the Research Project of Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences(Nos.QIBEBT ZZBS 201809, SEI I202120).

Study of Graphdiyne-based Magnetic Materials

LI Ru1,2, ZHANG Mingjia1, LI Xiaodong1, MA Xiaodi1, HUANG Changshui1,2   

  1. 1. Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, P. R. China;
    2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, P. R. China
  • Received:2021-08-31 Revised:2021-09-30 Online:2021-11-23 Published:2021-11-23
  • Contact: HUANG Changshui, ZHANG Mingjia E-mail:huangcs@qibebt.ac.cn;zhangmj@qibebt.ac.cn
  • Supported by:
    This work was supported by the the National Natural Science Foundation of China(Nos.51802324, 51822208, 21771187, 21790050, 21790051), the Frontier Science Research Project of the Chinese Academy of Sciences(No.QYZDBSSW-JSC052), the Taishan Scholars Program of Shandong Province, China(No. tsqn201812111), and the Research Project of Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences(Nos.QIBEBT ZZBS 201809, SEI I202120).

摘要: Carbon-based magnetic semiconductors are easy to be modified with low cost and low power consumption. While they can demonstrate robust long-range magnetic ordering and show great potential for application after introducing magnetic moments. Graphdiyne(GDY), as an allotrope of carbon, exhibits intrinsic semiconductor properties and paramagnetic properties due to its unique structure and the presence of sp carbon. To improve the magnetic properties of GDY and prepare excellent magnetic semiconductor materials, scientists have done a lot of related research work. The most direct and effective method to introduce magnetism is heteroatom doping. In this review, we have entirely described the latest GDY magnetism introduction methods, effects, and theoretical calculations, etc. Doping methods include post-doping and molecular design doping. The doping elements have covered non-metallic elements(N, H, F, Cl, S), metallic elements(Fe), and functional groups. The magnetic properties of the modified GDY materials were studied by experimental analysis and theoretical calculations. This review provides a sufficient basis and direction for related researches.

关键词: Graphdiyne, Chemical doping, Magnetic property, Ferromagnetism semiconductor, Spintronics

Abstract: Carbon-based magnetic semiconductors are easy to be modified with low cost and low power consumption. While they can demonstrate robust long-range magnetic ordering and show great potential for application after introducing magnetic moments. Graphdiyne(GDY), as an allotrope of carbon, exhibits intrinsic semiconductor properties and paramagnetic properties due to its unique structure and the presence of sp carbon. To improve the magnetic properties of GDY and prepare excellent magnetic semiconductor materials, scientists have done a lot of related research work. The most direct and effective method to introduce magnetism is heteroatom doping. In this review, we have entirely described the latest GDY magnetism introduction methods, effects, and theoretical calculations, etc. Doping methods include post-doping and molecular design doping. The doping elements have covered non-metallic elements(N, H, F, Cl, S), metallic elements(Fe), and functional groups. The magnetic properties of the modified GDY materials were studied by experimental analysis and theoretical calculations. This review provides a sufficient basis and direction for related researches.

Key words: Graphdiyne, Chemical doping, Magnetic property, Ferromagnetism semiconductor, Spintronics