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高等学校化学研究 ›› 2021, Vol. 37 ›› Issue (6): 1213-1223.doi: 10.1007/s40242-021-1332-y

• Reviews • 上一篇    下一篇

Heteroatom Doped Graphdiyne and Analogues: Synthesis, Structures and Applications

MAN Yixiao, ZHAO Jinyu, LIU Shipeng, PAN Qingyan, ZHAO Yingjie   

  1. College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China
  • 收稿日期:2021-08-24 修回日期:2021-09-22 出版日期:2021-11-23 发布日期:2021-11-23
  • 通讯作者: PAN Qingyan, ZHAO Yingjie E-mail:Qingyanpan@qust.edu.cn;yz@qust.edu.cn
  • 基金资助:
    This work was supported by the Natural Science Foundation of Shandong Province, China(No.ZR2020ZD38).

Heteroatom Doped Graphdiyne and Analogues: Synthesis, Structures and Applications

MAN Yixiao, ZHAO Jinyu, LIU Shipeng, PAN Qingyan, ZHAO Yingjie   

  1. College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China
  • Received:2021-08-24 Revised:2021-09-22 Online:2021-11-23 Published:2021-11-23
  • Contact: PAN Qingyan, ZHAO Yingjie E-mail:Qingyanpan@qust.edu.cn;yz@qust.edu.cn
  • Supported by:
    This work was supported by the Natural Science Foundation of Shandong Province, China(No.ZR2020ZD38).

摘要: As a new carbon allotrope, graphdiyne(GDY) has shown intensive practical application prospects in the energy field, catalysis, gas separation, etc., due to its unique 2D π-conjugated structure, rich sp-hybridized carbon atoms and semiconductor characteristics. Considerable efforts have been made to the development of well-defined GDY materials in recent years. The doping heteroatoms can further tune the structures, semiconductor properties of GDY, and expand the promising applications. This review summarized a comprehensive development of heteroatom doped GDYs, including their synthesis, structures, properties, applications in nanotechnology, as well as the forecast in the future.

关键词: Graphdiyne, Carbon material, 2D material, Hetero-atom doping

Abstract: As a new carbon allotrope, graphdiyne(GDY) has shown intensive practical application prospects in the energy field, catalysis, gas separation, etc., due to its unique 2D π-conjugated structure, rich sp-hybridized carbon atoms and semiconductor characteristics. Considerable efforts have been made to the development of well-defined GDY materials in recent years. The doping heteroatoms can further tune the structures, semiconductor properties of GDY, and expand the promising applications. This review summarized a comprehensive development of heteroatom doped GDYs, including their synthesis, structures, properties, applications in nanotechnology, as well as the forecast in the future.

Key words: Graphdiyne, Carbon material, 2D material, Hetero-atom doping