Intercalation-assisted Exfoliation Strategy for Two-dimensional Materials Preparation

doi:10.1007/s40242-020-0159-2

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (4): 518-524.doi: 10.1007/s40242-020-0159-2

Intercalation-assisted Exfoliation Strategy for Two-dimensional Materials Preparation

ZHAO Yingcheng, SU Yueqi, GUO Yuqiao, WU Changzheng

Hefei National Laboratory for Physical Sciences at the Microscale, iChEM(Collaborative Innovation Center of Chemistry for Energy Materials), CAS Key Laboratory of Mechanical Behavior and Design of Materials, University of Science and Technology of China, Hefei 230026, P. R. China

收稿日期:2020-05-27 修回日期:2020-07-01 出版日期:2020-08-01 发布日期:2020-07-30
通讯作者: WU Changzheng E-mail:czwu@ustc.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21925110, 21890751, 91745113, 11621063), the Fundamental Research Funds for the Central Universities, China(Nos.WK2060190084, WK2090050043, WK2340000088), the Strategic Priority Research Program of Chinese Academy of Sciences, China(No.XDB36000000), and the Users with Excellence Project of Hefei Science Center, China(No.2018HSC-UE002).

Intercalation-assisted Exfoliation Strategy for Two-dimensional Materials Preparation

ZHAO Yingcheng, SU Yueqi, GUO Yuqiao, WU Changzheng

Hefei National Laboratory for Physical Sciences at the Microscale, iChEM(Collaborative Innovation Center of Chemistry for Energy Materials), CAS Key Laboratory of Mechanical Behavior and Design of Materials, University of Science and Technology of China, Hefei 230026, P. R. China

Received:2020-05-27 Revised:2020-07-01 Online:2020-08-01 Published:2020-07-30
Contact: WU Changzheng E-mail:czwu@ustc.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21925110, 21890751, 91745113, 11621063), the Fundamental Research Funds for the Central Universities, China(Nos.WK2060190084, WK2090050043, WK2340000088), the Strategic Priority Research Program of Chinese Academy of Sciences, China(No.XDB36000000), and the Users with Excellence Project of Hefei Science Center, China(No.2018HSC-UE002).

摘要/Abstract

摘要： Controlled large-quantity synthesis of two-dimensional materials is vital for the research on their physical and chemical characters and potential applications. Utilizing structural features of layered compounds, intercalation of molecules or ions can be applied to the acceleration of liquid-phase exfoliation. In this review, we aim at recent progress on synthesis of two-dimensional materials via intercalation-assisted exfoliation strategy. Works on wet chemical intercalation and electrochemical intercalation, together with product exfoliation afterwards, are summarized. Furthermore, the features and advantages of intercalation-assisted exfoliation strategy for two-dimensional materials synthesis are discussed.

关键词: Two-dimensional material, Liquid-phase exfoliation, Intercalation

Abstract: Controlled large-quantity synthesis of two-dimensional materials is vital for the research on their physical and chemical characters and potential applications. Utilizing structural features of layered compounds, intercalation of molecules or ions can be applied to the acceleration of liquid-phase exfoliation. In this review, we aim at recent progress on synthesis of two-dimensional materials via intercalation-assisted exfoliation strategy. Works on wet chemical intercalation and electrochemical intercalation, together with product exfoliation afterwards, are summarized. Furthermore, the features and advantages of intercalation-assisted exfoliation strategy for two-dimensional materials synthesis are discussed.

Key words: Two-dimensional material, Liquid-phase exfoliation, Intercalation

ZHAO Yingcheng, SU Yueqi, GUO Yuqiao, WU Changzheng. Intercalation-assisted Exfoliation Strategy for Two-dimensional Materials Preparation[J]. 高等学校化学研究, 2020, 36(4): 518-524.

ZHAO Yingcheng, SU Yueqi, GUO Yuqiao, WU Changzheng. Intercalation-assisted Exfoliation Strategy for Two-dimensional Materials Preparation[J]. Chemical Research in Chinese Universities, 2020, 36(4): 518-524.

参考文献 63

[1]	Das Sarma S., Adam S., Hwang E. H., Rossi E., Rev. Mod. Phys., 2011, 83(2), 407
[2]	Mak K. F., Lee C., Hone J., Shan J., Heinz T. F., Phys. Rev. Lett., 2010, 105(13), 136805
[3]	Ithurria S., Tessier M. D., Mahler B., Lobo R., Dubertret B., Efros A., Nat. Mater., 2011, 10(12), 936
[4]	Li L. K., Ye G. J., Tran V., Fei R. X., Chen G. R., Wang H. C., Wang J., Watanabe K., Taniguchi T., Yang L., Chen X. H., Zhang Y. B., Nat. Nanotech., 2015, 10(7), 608
[5]	Novoselov K. S., Geim A. K., Morozov S. V., Jiang D., Katsnelson M. I., Grigorieva I. V., Dubonos S. V., Firsov A. A., Nature, 2005, 438(7065), 197
[6]	Hwang E. H., Adam S., Das Sarma S., Phys. Rev. Lett., 2007, 98(18), 186806
[7]	Rao C. N. R., Sood A. K., Subrahmanyam K. S., Govindaraj A., Angew. Chem. Int. Ed., 2009, 48(42), 7752
[8]	Frindt R., Phys. Rev. Lett., 1972, 28(5), 299
[9]	Novoselov K. S., Geim A. K., Morozov S. V., Jiang D., Zhang Y., Dubonos S. V., Grigorieva I. V., Firsov A. A., Science, 2004, 306(5696), 666
[10]	Huang B., Clark G., Navarro-Moratalla E., Klein D. R., Cheng R., Seyler K. L., Zhong D., Schmidgall E., McGuire M. A., Cobden D. H., Yao W., Xiao D., Jarillo-Herrero P., Xu X. D., Nature, 2017, 546(7657), 270
[11]	Coleman J. N., Lotya M., O'Neill A., Bergin S. D., King P. J., Khan U., Young K., Gaucher A., De S., Smith R. J., Shvets I. V., Arora S. K., Stanton G., Kim H. Y., Lee K., Kim G. T., Duesberg G. S., Hallam T., Boland J. J., Wang J. J., Donegan J. F., Grunlan J. C., Moriarty G., Shmeliov A., Nicholls R. J., Perkins J. M., Grieveson E. M., Theuwissen K., McComb D. W., Nellist P. D., Nicolosi V., Science, 2011, 331(6017), 568
[12]	Smith R. J., King P. J., Lotya M., Wirtz C., Khan U., De S., O'Neill A., Duesberg G. S., Grunlan J. C., Moriarty G., Chen J., Wang J. Z., Minett A. I., Nicolosi V., Coleman J. N., Adv. Mater., 2011, 23(34), 3944
[13]	Zheng J., Zhang H., Dong S. H., Liu Y. P., Nai C. T., Shin H. S., Jeong H. Y., Liu B., Loh K. P., Nat. Commun., 2014, 5, 2995
[14]	Joensen P., Frindt R. F., Morrison S. R., Mater. Res. Bull., 1986, 21(4), 457
[15]	Dresselhaus M. S., Intercalation in Layered Materials, Springer, Boston, 2013
[16]	Feng J., Sun X., Wu C. Z., Peng L. L., Lin C. W., Hu S. L., Yang J. L., Xie Y., J. Am. Chem. Soc., 2011, 133(44), 17832
[17]	Guan G. J., Zhang S. Y., Liu S. H., Cai Y. Q., Low M., Teng C. P., Phang I. Y., Cheng Y., Duei K. L., Srinivasan B. M., Zheng Y. G., Zhang Y. W., Han M. Y., J. Am. Chem. Soc., 2015, 137(19), 6152
[18]	Jeong S., Yoo D., Ahn M., Miro P., Heine T., Cheon J., Nat. Commun., 2015, 6, 5763
[19]	Hummers W. S., Offeman R. E., J. Am. Chem. Soc.,1958, 80(6), 1339
[20]	Chen J., Yao B. W., Li C., Shi G. Q., Carbon, 2013, 64, 225
[21]	Geng X. M., Guo Y. F., Li D. F., Li W. W., Zhu C., Wei X. F., Chen M. L., Gao S., Qiu S. Q., Gong Y. P., Wu L. Q., Long M. S., Sun M. T., Pan G. B., Liu L. W., Sci. Rep., 2013, 3, 1134
[22]	Ding Y. J., Chen Y. P., Zhang X. L., Chen L., Dong Z. H., Jiang H. L., Xu H. X., Zhou H. C., J. Am. Chem. Soc.,2017, 139(27), 9136
[23]	Matte H., Gomathi A., Manna A. K., Late D. J., Datta R., Pati S. K., Rao C. N. R., Angew. Chem. Int. Ed., 2010, 49(24), 4059
[24]	Fan X. B., Xu P. T., Zhou D. K., Sun Y. F., Li Y. G. C., Nguyen M. A. T., Terrones M., Mallouk T. E., Nano Lett., 2015, 15(9), 5956
[25]	Cullen P. L., Cox K. M., Bin Subhan M. K., Picco L., Payton O. D., Buckley D. J., Miller T. S., Hodge S. A., Skipper N. T., Tileli V., Howard C. A., Nat. Chem., 2017, 9(3), 244
[26]	Peng J., Wu J. J., Li X. T., Zhou Y., Yu Z., Guo Y. Q., Wu J. C., Lin Y., Li Z. J., Wu X. J., Wu C. Z., Xie Y., J. Am. Chem. Soc., 2017, 139(26), 9019
[27]	Fan X. B., Xu P. T., Li Y. C., Zhou D. K., Sun Y. F., Nguyen M. A. T., Terrones M., Mallouk T. E., J. Am. Chem. Soc., 2016, 138(15), 5143
[28]	Zeng Z. Y., Yin Z. Y., Huang X., Li H., He Q. Y., Lu G., Boey F., Zhang H., Angew. Chem. Int. Ed., 2011, 50(47), 11093
[29]	Azhagurajan M., Kajita T., Itoh T., Kim Y. G., Itaya K., J. Am. Chem. Soc., 2016, 138(10), 3355
[30]	Duerloo K. A. N., Li Y., Reed E. J., Nat. Commun., 2014, 5, 4214
[31]	Li Y., Duerloo K. A. N., Wauson K., Reed E. J., Nat. Commun., 2016, 7, 10671
[32]	Yu Y. F., Nam G. H., He Q. Y., Wu X. J., Zhang K., Yang Z. Z., Chen J. Z., Ma Q. L., Zhao M. T., Liu Z. Q., Ran F. R., Wang X. Z., Li H., Huang X., Li B., Xiong Q. H., Zhang Q., Liu Z., Gu L., Du Y. H., Huang W., Zhang H., Nat. Chem., 2018, 10(6), 638
[33]	Cao X. H., Tan C. L., Zhang X., Zhao W., Zhang H., Adv. Mater., 2016, 28(29), 6167
[34]	Kang Y. M., Najmaei S., Liu Z., Bao Y. J., Wang Y. M., Zhu X., Halas N. J., Nordlander P., Ajayan P. M., Lou J., Fang Z. Y., Adv. Mater., 2014, 26(37), 6467
[35]	Acerce M., Voiry D., Chhowalla M., Nat. Nanotech., 2015, 10(4), 313
[36]	Peng J., Liu Y. H., Luo X., Wu J. J., Lin Y., Guo Y. Q., Zhao J. Y., Wu X. J., Wu C. Z., Xie Y., Adv. Mater., 2019, 31(19), 1900568
[37]	Nakamura S., Mukai T., Senoh M., Jap. J. Appl. Phys., 1991, 30(12A), L1998
[38]	Koizumi S., Watanabe K., Hasegawa M., Kanda H., Science, 2001, 292(5523), 1899
[39]	Williams J., DiCarlo L., Marcus C., Science, 2007, 317(5838), 638
[40]	Wu J. J., Peng J., Zhou Y., Lin Y., Wen X. L., Wu J. C., Zhao Y. C., Guo Y. Q., Wu C. Z., Xie Y., J. Am. Chem. Soc., 2019, 141(1), 592
[41]	Coker A., Lee T., Das T. P., Phys. Rev. B, 1980, 22(6), 2968
[42]	Zhu Z. L., Cai X. L., Yi S. H., Chen J. L., Dai Y. W., Niu C. Y., Guo Z. X., Xie M. H., Liu F., Cho J. H., Jia Y., Zhang Z. Y., Phys. Rev. Lett., 2017, 119(10), 106101
[43]	Wu B. Z., Liu X. H., Yin J. R., Lee H., Mater. Res. Express, 2017, 4(9), 095902
[44]	Wang Y., Qiu G., Wang R., Huang S., Wang Q., Liu Y., Du Y., Goddard W. A., Kim M. J., Xu X., Ye P. D., Wu W., Nat. Electron., 2018, 1(4), 228
[45]	Gao Z. B., Tao F., Ren J., Nanoscale, 2018, 10(27), 12997
[46]	Wang Q. S., Safdar M., Xu K., Mirza M., Wang Z. X., He J., ACS Nano, 2014, 8(7), 7497
[47]	Liu Y. Y., Wu W. Z., Goddard W. A., J. Am. Chem. Soc., 2018, 140(2), 550
[48]	Peng J., Pan Y., Yu Z., Wu J. J., Wu J. C., Zhou Y., Guo Y. Q., Wu X. J., Wu C. Z., Xie Y., Angew. Chem. Int. Ed., 2018, 57(41), 13533
[49]	Wu J. J., Peng J., Yu Z., Zhou Y., Guo Y. Q., Li Z. J., Lin Y., Ruan K. Q., Wu C. Z., Xie Y., J. Am. Chem. Soc., 2018, 140(1), 493
[50]	Lin C. W., Zhu X. J., Feng J., Wu C. Z., Hu S. L., Peng J., Guo Y. Q., Peng L. L., Zhao J. Y., Huang J. L., Yang J. L., Xie Y., J. Am. Chem. Soc., 2013, 135(13), 5144
[51]	Eda G., Yamaguchi H., Voiry D., Fujita T., Chen M. W., Chhowalla M., Nano Lett., 2011, 11(12), 5111
[52]	Park M. J., Gravelsins S., Son J., van der Zande A. M., Dhirani A., ACS Nano, 2019, 13(6), 6469
[53]	Peng J., Yu Z., Wu J. J., Zhou Y., Guo Y. Q., Li Z. J., Zhao J. Y., Wu C. Z., Xie Y., ACS Nano, 2018, 12(9), 9461
[54]	Zhang Y. Q., Dong N. N., Tao H. C., Yan C., Huang J. W., Liu T. F., Robertson A. W., Texter J., Wang J., Sun Z. Y., Chem. Mater., 2017, 29(15), 6445
[55]	Lotya M., Hernandez Y., King P. J., Smith R. J., Nicolosi V., Karlsson L. S., Blighe F. M., De S., Wang Z. M., McGovern I. T., Duesberg G. S., Coleman J. N., J. Am. Chem. Soc., 2019, 131(10), 3611
[56]	Zhu P. N., Nair S., Peng S. J., Yang S. Y., Ramakrishna S., ACS Appl. Mater. Interfaces, 2012, 4(2), 581
[57]	Smith R. J., King P. J., Lotya M., Wirtz C., Khan U., De S., O'Neill A., Duesberg G. S., Grunlan J. C., Moriarty G., Chen J., Wang J. Z., Minett A. I., Nicolosi V., Coleman J. N., Adv. Mater., 2011, 23(34), 3944
[58]	Su C., Yin Z. Y., Yan Q. B., Wang Z. G., Lin H. T., Sun L., Xu W. S., Yamada T., Ji X., Zettsu N., Teshima K., Warner J. H., Dinca M., Hu J. J., Dong M. D., Su G., Kong J., Li J., Proc. Natl. Acad. Sci. USA, 2019, 116(42), 20844
[59]	Zeng Z. Y., Yin Z. Y., Huang X., Li H., He Q. Y., Lu G., Freddy B., Zhang H., Angew. Chem. Int. Ed., 2011, 50(47), 11093
[60]	Lin Z. Y., Liu, Y., Udayabagya H., Ding M. N., Liu Y. Y., Wang Y. L., Jia C. C., Chen P., Duan X. D., Wang C., Song F., Li M. F., Wan C. Z., Huang Y., Duan X. F., Nature, 2018, 562, 254
[61]	Shi H. H., Li M. M., Nia A. S., Wang M. C., Park S., Zhang Z., Lohe M. R., Yang S., Feng X. L., Adv. Mater., 2020, 32(8), 1907244
[62]	Yu W., Li J., Tun S. H., Wang Z. S., Zhao X. X., Chi X., Fu W., Ibrahim A., Zhou J., Dan J. D., Chen Z. X., Chen Z., Li Z. J., Lu J., Stephen J. P., Feng Y. P., Ding J., Kian P. L., Adv. Mater., 2019, 31(40), 1903779
[63]	Campeon B. D. L., Akada M., Ahmad M. S., Nishikawa Y., Gotoh K., Nishina Y., Carbon, 2020, 158, 356

Intercalation-assisted Exfoliation Strategy for Two-dimensional Materials Preparation

Intercalation-assisted Exfoliation Strategy for Two-dimensional Materials Preparation

可视化

摘要/Abstract

引用本文

使用本文

参考文献 63

相关文章 9

编辑推荐

Metrics

本文评价

[1]	QI Qi, XU Lekai, DU Jiang, YANG Nailiang, WANG Dan. Fabrication and Application of Graphdiyne-based Heterogeneous Compositions: from the View of Interaction[J]. 高等学校化学研究, 2021, 37(6): 1158-1175.
[2]	ZHOU Xinyun, YANG Juehan, ZHONG Mianzeng, XIA Qinglin, LI Bo, DUAN Xidong, WEI Zhongming. Intercalation of Two-dimensional Layered Materials[J]. 高等学校化学研究, 2020, 36(4): 584-596.
[3]	FANG Wensheng, HUANG Lei, ZAMAN Shahid, WANG Zhitong, HAN Youjia, XIA Bao Yu. Recent Progress on Two-dimensional Electrocatalysis[J]. 高等学校化学研究, 2020, 36(4): 611-621.
[4]	YANG Chao, WANG Hao-Fan, XU Qiang. Recent Advances in Two-dimensional Materials for Electrochemical Energy Storage and Conversion[J]. 高等学校化学研究, 2020, 36(1): 10-23.
[5]	GE Shun, ZHAO Ying, SUI Beibei, SHANGGUAN Guoqiang. Studies on the Interaction of Novel Organogermanium Sesquioxides with DNA[J]. 高等学校化学研究, 2015, 31(1): 31-37.
[6]	WEI Ang, WANG Qing-jing, ZHAO Xiao-hui and ZHANG Shu-yong*. Electronic Effect of Carbon Support on Pt Catalyst Supported on Graphite Intercalation Compound[J]. 高等学校化学研究, 2010, 26(3): 465-471.
[7]	YANG Hong-mei, SONG Yi-hu, XU Bo, ZHENG Qiang. Preparation of Exfoliated Low-density Polyethylene/Montmorillonite Nanocomposites Through Melt Extrusion[J]. 高等学校化学研究, 2006, 22(3): 383-387.
[8]	NIU Shu-yan, ZHANG Shu-sheng, SHI Xin, JIAO Kui. Electrochemical Study on the Interaction Betwwen Neutral Red and DNA[J]. 高等学校化学研究, 2005, 21(1): 24-27.
[9]	ZHU Zhi-ping, PENG Wan-pu, ZHOU De-feng, LIU Jing-fu . Synthesis, Characterization and Catalysis of New Pillared Anionic Clays by [GaW₁₁O₃₉M(H₂O)]^7-(M=Mn²⁺,Co²⁺ or Ni²⁺)[J]. 高等学校化学研究, 1998, 14(3): 254-258.